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Volumn 44, Issue 28, 2005, Pages 4352-4355

Copper(II) and zinc(II) complexes can fix atmospheric carbon dioxide

Author keywords

Carbon dioxide fixation; Copper; Networks; NMR spectroscopy; Zinc

Indexed keywords

AMINES; CARBON DIOXIDE; COPPER COMPOUNDS; CRYSTALLOGRAPHY; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; ZINC COMPOUNDS;

EID: 22744449808     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500587     Document Type: Article
Times cited : (135)

References (34)
  • 1
    • 1542304635 scopus 로고    scopus 로고
    • For recent reviews, see: a) G. Parkin, Chem. Rev. 2004, 104, 699-767;
    • (2004) Chem. Rev. , vol.104 , pp. 699-767
    • Parkin, G.1
  • 9
    • 22744446339 scopus 로고    scopus 로고
    • For some examples of carbonato-metal and bicarbonato-metal complexes, see: a) A. N. Acharya, A. Das, A. C. Dash, Adv. Inorg. Chem. 2004, 55, 127-199;
    • (2004) Adv. Inorg. Chem. , vol.55 , pp. 127-199
    • Acharya, A.N.1    Das, A.2    Dash, A.C.3
  • 19
    • 4444275259 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 2334-2375;
    • (2004) Angew. Chem. Int. Ed. , vol.43 , pp. 2334-2375
  • 21
    • 22744446945 scopus 로고    scopus 로고
    • note
    • 2 gave R1 = 0.057 (I > 2σ(I)), wR2 = 0.1650 (all data) using 3910 observed reflections.
  • 22
    • 0002592430 scopus 로고    scopus 로고
    • For examples of di-, tri-, and tetranuclear zinc(II) carbonate complexes, see: a) F. Meyer, P. Rutsch, Chem. Commun. 1998, 1037-1038;
    • (1998) Chem. Commun. , pp. 1037-1038
    • Meyer, F.1    Rutsch, P.2
  • 28
    • 22744456922 scopus 로고    scopus 로고
    • note
    • 2 gave R1 = 0.085 (I > 2σ(I)), wR2 = 0.236 (all data) using 4238 observed reflections.
  • 31
    • 22744450867 scopus 로고    scopus 로고
    • 1H NMR spectra
    • 1H NMR spectra.
  • 32
    • 22744438761 scopus 로고    scopus 로고
    • note
    • X-ray structural analysis confirmed that the recrystallization product of 2 from aqueous acetonitrile solution is 1b.
  • 34
    • 22744440132 scopus 로고    scopus 로고
    • note
    • 2O (M = Cu, Zn) was treated with ligand L under the same conditions as for the preparation of complexes 1a and 1b, the IR spectra of the reaction products showed no carbonate-related vibrations, which means that no carbon dioxide has been absorbed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.