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Volumn 46, Issue 7, 2007, Pages 1075-1078

Heterogeneous asymmetric catalysis with homochiral metal-organic frameworks: Network-structure-dependent catalytic activity

Author keywords

Asymmetric catalysis; Chirality; Functional materials; Heterogeneous catalysis; Metal organic frameworks

Indexed keywords

ALDEHYDES; AROMATIC COMPOUNDS; CATALYST ACTIVITY; ENANTIOSELECTIVITY; MOLECULAR STRUCTURE; REACTION KINETICS;

EID: 34250698001     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200602099     Document Type: Article
Times cited : (492)

References (41)
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    • 34250724119 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2000, 39, 2081;
    • (2000) Chem. Int. Ed , vol.39 , pp. 2081
    • Angew1
  • 33
    • 34250759065 scopus 로고    scopus 로고
    • Crystal-structure determinations of 1 and 2 were performed on a Siemens SMART CCD. The data were collected using graphite-monochromatic MoKα radiation (λ, 0.71073 Å) at 173 K. The data sets were corrected by using the SADABS program.[15] The structures were solved by direct methods and refined by the full-matrix least-squares method with the SHELXTL-97 program package.[16] Crystallographic data for 1: tetragonal, space group P4122, a, 20.305(1, c, 49.641(4) Å, V, 20466(2) Å3, Z, 4, ρ calcd, 0.993 g cm-3, μ(MoKα, 0.469 mm-1. Least-squares refinements based on 16912 reflections with I > 2σ(I) and 866 parameters led to convergence, with a final R1, 0.0639, wR2, 0.1798, Flack parameter, 0.003, and GOF, 1.190. Crystallographic data for 2: tetragonal, space group P4
    • -1. Least-squares refinements based on 2254 reflections with I > 2σ(I) and 201 parameters led to convergence, with a final R1 = 0.1240, wR2 = 0.3090, Flack parameter = 0.06(14), and GOF = 1.111. CCDC-609008 (1) and -261745 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.