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Crystal-structure determinations of 1 and 2 were performed on a Siemens SMART CCD. The data were collected using graphite-monochromatic MoKα radiation (λ, 0.71073 Å) at 173 K. The data sets were corrected by using the SADABS program.[15] The structures were solved by direct methods and refined by the full-matrix least-squares method with the SHELXTL-97 program package.[16] Crystallographic data for 1: tetragonal, space group P4122, a, 20.305(1, c, 49.641(4) Å, V, 20466(2) Å3, Z, 4, ρ calcd, 0.993 g cm-3, μ(MoKα, 0.469 mm-1. Least-squares refinements based on 16912 reflections with I > 2σ(I) and 866 parameters led to convergence, with a final R1, 0.0639, wR2, 0.1798, Flack parameter, 0.003, and GOF, 1.190. Crystallographic data for 2: tetragonal, space group P4
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