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Volumn 48, Issue 3, 2009, Pages 1045-1052

Molecular recognition of redox-switchable bis-crown moieties assembled on a dicobalt complex

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EID: 61449158921     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801708v     Document Type: Article
Times cited : (15)

References (63)
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    • Feringa, B. L, Ed, Wiley-VCH: Weinheim, Germany
    • (a) Molecular Switches; Feringa, B. L., Ed.; Wiley-VCH: Weinheim, Germany, 2001.
    • (2001) Molecular Switches
  • 4
    • 0012317549 scopus 로고    scopus 로고
    • Balzani, V, Venturi, M, Credi, A, Eds, Wiley-VCH: Weinheim, Germany
    • (b) Molecular Devices and Machines; Balzani, V.; Venturi, M.; Credi, A., Eds.; Wiley-VCH: Weinheim, Germany, 2003.
    • (2003) Molecular Devices and Machines
  • 12
    • 0002688596 scopus 로고    scopus 로고
    • Suslick, K. S, Ed, Pergamon: Oxford, U.K
    • Chen, C.-T. Comprehensive Supramolecular Chemistry; Suslick, K. S., Ed.; Pergamon: Oxford, U.K., 1996; Vol. 5, pp 91-140.
    • (1996) Comprehensive Supramolecular Chemistry , vol.5 , pp. 91-140
    • Chen, C.-T.1
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    • 2 ligand: (a) Akine, S.; Taniguchi, T.; Saiki, T.; Nabeshima, T. J. Am. Chem. Soc. 2005, 127, 540-541.
    • 2 ligand: (a) Akine, S.; Taniguchi, T.; Saiki, T.; Nabeshima, T. J. Am. Chem. Soc. 2005, 127, 540-541.
  • 61
    • 61449084768 scopus 로고    scopus 로고
    • redox couples for amine-coordinated dicobalt complex since binding of the potassium ion changed the monodentate 4-aminomethylbenzo-15-crown-5 into bidentate pseudo-diamine
    • The shoulder peak in spectrum b around 0 V versus Ag/AgCl may be ascribed to Co(III)Co(III)/Co(II)CoII, may be increased so that part of complex exists as amine coordinated species
    • The shoulder peak in spectrum b around 0 V versus Ag/AgCl may be ascribed to Co(III)Co(III)/Co(II)Co(II) redox couples for amine-coordinated dicobalt complex since binding of the potassium ion changed the monodentate 4-aminomethylbenzo-15-crown-5 into bidentate pseudo-diamine. The binding constant of diamine to the Co(II)Co(II) complex may be increased so that part of complex exists as amine coordinated species.
    • The binding constant of diamine to the Co(II)Co(II) complex
  • 63
    • 61449149667 scopus 로고    scopus 로고
    • The calculations were carried out using the MacroModel 9.1 software.
    • The calculations were carried out using the MacroModel 9.1 software.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.