Trinuclear nickel complexes with triplesalen ligands: Simultaneous occurrence of mixed valence and valence tautomerism in the oxidized species

Inorganic Chemistry

Volumn 44, Issue 15, 2005, Pages 5467-5482

  Glaser, Thorsten ^a   Heidemeier, Maik ^a   Fröhlich, Roland ^a   Hildebrandt, Peter ^b   Bothe, Eberhart ^c   Bill, Eckhard ^c  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^c MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 23244458072     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050268x     Document Type: Article

References (103)

1. (a) Pfeiffer, P.; Breith, E.; Lübbe, E.; Tsumaki, T. Liebigs Ann. Chem. 1933, 503, 84-130.
2. (b) Pfeiffer, P.; Hesse, T.; Pfitzner, H.; Scholl, W.; Thielert, H. J. Prakt. Chem. 1937, 149, 217-296.
3. (c) Pfeiffer, P.; Christeleit, W.; Hesse, T.; Pfitzner, H.; Thielert, H. J. Prakt. Chem. 1938, 150, 261-316.
4. (d) Holm, R. H.; Everett, G. W.; Chakravorty, A. Prog. Inorg. Chem. 1966, 7, 83-214.
5. (e) Calligaris, M.; Randaccio, L. In Comprehensive Coordination Chemistry; Wilkenson, G., Guillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U. K., 1987; Vol. 2, pp 715-738.
6. (a) Yoon, H.; Burrows, C. J. J. Am. Chem. Soc. 1988, 110, 4087-4089.
7. (b) Yoon, H.; Wagler, T. R.; O'Connor, K. J.; Burrows, C. J. J. Am. Chem. Soc. 1990, 112, 4568-4570.
8. DiMauro, E. F.; Kozlowski, M. C. Organometallics 2002, 21, 1454-1461.
9. (a) Siddall, T. L.; Miyaura, N.; Huffman, J. C.; Kochi, J. K. J. Chem. Soc., Chem. Commun. 1983, 1185-1186.
10. (b) Samsel, E. G.; Srinivasan, K.; Kochi, J. K. J. Am. Chem. Soc. 1985, 107, 7606-7617.
11. Srinivasan, K.; Michaud, P.; Kochi, J. K. J. Am. Chem. Soc. 1986, 108, 2309-2320.
12. Nakajima, K.; Kojima, M.; Fujita, J. Chem. Lett. 1986, 1483-1486.
13. (a) Vincens, V.; Le Borgne, A.; Spassky, N. Makromol. Chem., Rapid Commun. 1989, 10, 623.
14. (b) Atwood, D. A.; Jegier, J. A.; Rutherford, D. J. Am. Chem. Soc. 1995, 117, 7.
15. Srinivasan, K.; Kochi, J. K. Inorg. Chem. 1985, 24, 4671-4679.
16. (a) Zhang, W.; Loebach, J. L.; Wilson, S. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1990, 112, 2801-2803.
17. (b) Irie, R.; Noda, K.; Ito, Y.; Matsumoto, N.; Katsuki, T. Tetrahdron Lett. 1990, 31, 7345-7348.
18. (c) Larrow, J. F.; Jacobsen, E. N.; Gao, Y.; Hong, Y.; Nie, X.; Zepp, C. M. J. Org. Chem. 1994, 59, 1939-1942.
19. (d) Sasaki, H.; Irie, R.; Hamada, T.; Suzuki, K.; Katsuki, T. Tetrahedron 1994, 50, 11827-11838.
20. (e) Martínez, L. E.; Leighton, J. L.; Carsten, D. H.; Jacobsen, E. N. J. Am. Chem. Soc. 1995, 117, 5897-5898.
21. Zhang, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296-2298.
22. (a) Hamada, T.; Fukuda, T.; Imanishi, H.; Katsuki, T. Tetrahedron 1996, 52, 515-530.
23. (b) Ito, Y. N.; Katsuki, T. Bull. Chem. Soc. Jpn. 1999, 72, 603-619.
24. (c) Ryan, K. M.; Bousquet, C.; Gilheany, D. G. Tetrahdron Lett. 1999, 40, 3613-3616.
25. (d) Jacobsen, H.; Cavallo, L. Chem.-Eur. J. 2001, 7, 800-807.
26. (e) El-Bahraoui, J.; Wiest, O.; Feichtinger, D.; Plattner, D. A. Angew. Chem., Int. Ed. 2001, 40, 2073-2076.
27. (f) Cavallo, L.; Jacobsen, H. J. Org. Chem. 2003, 68, 6202-6207.
28. (e) Darensbourg, D. J.; Mackiewicz, R. M.; Rodgers, J. L.; Fang, C. C.; Billodeaux, D. R.; Reibenspies, J. H. Inorg. Chem. 2004, 43, 6024-6034.
29. Cavallo, L.; Jacobsen, H. Eur. J. Inorg. Chem. 2003, 892-902.
30. Bandini, M.; Cozzi, P. G.; Umanchi-Ronchi, A. J. Chem. Soc., Chem. Commun. 2002, 919-927.
31. (a) Hansen, K. B.; Leighton, J. L.; Jacobsen, E. N. J. Am. Chem. Soc. 1996, 118, 10924-10925.
32. (b) Darensbourg, D. J.; Yarbrough, J. C. J. Am. Chem. Soc. 2002, 124, 6335-6342.
33. (c) Darensbourg, D. J.; Mackiewicz, R. M.; Phelps, A. L.; Billodeaux, D. R. Acc. Chem. Res. 2004, 37, 836-844.
34. (a) Sträter, N.; Lipscomb, W. N.; Klabunde, T.; Krebs, B. Angew. Chem., Int. Ed. Engl. 1996, 35, 2024-2055.
35. (b) Averill, B. A. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Ltd.: Oxford, U. K., 2004; Vol. 8, pp 641-676.
36. Konsler, R. G.; Karl, J.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 10780-10781.
37. Jacobsen, E. N. Acc. Chem. Res. 2000, 33, 421-431.
38. Glaser, T.; Heidemeier, M.; Lügger, T. J. Chem. Soc., Dalton Trans. 2003, 2381-2383.
39. (a) Long, J. R. In Chemistry of Nanostructured Materials; Yang, P., Ed.; World Scientific: Hong Kong, 2003; pp 291-315.
40. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141-143.
41. (c) Sessoli, R.; Tsai, H. L.; Schake, A. R.; Wang, S. Y.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804-1816.
42. (d) Gatteschi, D.; Caneschi, A.; Pardi, L.; Sessoli, R. Science 1994, 265, 1054-1058.
43. (e) Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268-297.
44. (f) Gatteschi, D.; Sorace, L. J. Solid State Chem. 2001, 159, 253-261.
45. (g) Delfs, C.; Gatteschi, D.; Pardi, L.; Sessoli, R.; Wieghardt, K.; Hanke, D. Inorg. Chem. 1993, 32, 3099-3103.
46. Ung, V. A.; Thompson, A.; Bardwell, D. A.; Gatteschi, D.; Jeffery, J. C.; McCleverty, J. A.; Totti, F.; Ward, M. D. Inorg. Chem. 1997, 36, 3447-3454.
47. Glaser, T.; Gerenkamp, M.; Fröhlich, R. Angew. Chem., Int. Ed. 2002, 41, 3823-3825.
48. Glaser, T.; Heidemeier, M. Unpublished results.
49. Kennedy, B. J.; Murray, K. S. Inorg. Chem. 1985, 24, 1552-1557.
50. (a) Mitra, S. Prog. Inorg. Chem. 1977, 22, 309-408.
51. (b) Bencini, A.; Ciofini, I.; Uytterhoeven, M. G. Inorg. Chim. Acta 1998, 274, 90-101.
52. (a) Campbell, K. A.; Lashley, M. R.; Wyatt, J. K.; Nantz, M. H.; Britt, R. D. J. Am. Chem. Soc. 2001, 123, 5710-5719.
53. (b) Krzystek, J.; Telser, J. J. Magn. Reson. 2003, 162, 454-465.
54. Glaser, T.; Heidemeier, M.; Grimme, S.; Bill, E. Inorg. Chem. 2004, 43, 5192-5194.
55. SMART; Bruker AXS: Madison, Wisconsin, 2000.
56. COLLECT; Nonius B. V.: Delft, The Netherlands, 1998.
57. Otwinowski, Z.; Minor, W. Methods Enzymol. 1997, 276, 307-326.
58. (a) Blessing, R. H. Acta Crystallogr., Sect. A 1995, A51, 33-37.
59. (b) Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421-426.
60. Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, A46, 467-473.
61. Sheldrick, G. M. SHELXL-97; Universität Göttingen: Göttingen, Germany, 1997.
62. Brandenburg, K. DIAMOND; Universität Bonn: Bonn, Germany, 1997.
63. Hernández-Molina, R.; Mederos, A. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Ltd.: Oxford, U. K., 2004; Vol. 1, pp 411-446.
64. (a) Lopez, J.; Liang, S.; Bu, X. R. Tetrahedron Lett. 1998, 39, 4199-4202.
65. (b) Janssen, K. B. M.; Laquierra, I.; Dehaen, W.; Parton, R. F.; Vankelecom, I. F. J.; Jacobs, P. A. Tetrahedron: Asymmetry 1997, 8, 3481-3487.
66. (a) Atkins, R.; Brewer, G.; Kokot, E.; Mockler, G. M.; Sinn, E. Inorg. Chem. 1985, 24, 127-134.
67. (b) Fernandey Garcia, M. I.; Fondo, M.; Garcia Deibe, A. M.; Fernandez Fernandez, M. B.; Gonzalez, A. M. Z. Anorg. Allg. Chem. 2000, 626, 1985-1991.
68. (c) Costes, J.-P.; Dahan, F.; Dupuis, A.; Laurant, J.-P. J. Chem. Soc., Dalton Trans. 1998, 1307-1314.
69. Böttcher, A.; Elias, H.; Eisenmann, B.; Hilms, E.; Huer, A.; Kniep, R.; Röhr, C. Z. Naturforsch., B: Chem. Sci. 1994, 49, 1089-1100.
70. (a) Shkol'nikova, L. M.; Yumal, E. M.; Shugarn, E. A. Zh. Strukt. Khim. 1970, 11, 886.
71. (b) Manfredotti, A. G.; Guastini, C. Acta Crystallogr., Sect. C 1983, 39, 863.
72. Ottenwaelder, X.; Ruiz-Garcia, R.; Blondin, G.; Carasco, R.; Cano, J.; Lexa, D.; Journaux, Y.; Aukauloo, A. J. Chem. Soc., Chem. Commun. 2004, 504-505.
73. Santos, I. C.; Vilas-Boas, M.; Piedale, M. F. M.; Freire, C.; Duarte, M. T.; de Castro, B. Polyhedron 2000, 19, 655.
74. Azevedo, F.; de Carrondo, M. A. A. F.; de Castro, B.; Convery, M.; Domingues, D.; Freire, C.; Duarte, M. T.; Nielson, K.; Santos, I. C. Inorg. Chim. Acta 1994, 219, 43-54.
75. Szlyk, E.; Wojtczak, A.; Larsen, E.; Surdykowski, A.; Neumann, J. Inorg. Chim. Acta 1999, 293, 239.
76. (a) Wojtczak, A.; Szlyk, E.; Jaskolski, M.; Larsen, E. Acta Chem. Scand. 1997, 51, 274.
77. (b) de Castro, B.; Freire, C.; Duarte, M. T.; Minas da Piedade, M. F.; Santos, I. C. Acta Crystallogr., Sect. C 2001, 57, 370.
78. Bosnich, B. J. Am. Chem. Soc. 1968, 90, 627-632.
79. Crawford, S. M. Spectrochim. Acta 1963, 19, 255-270.
80. Di Bella, S.; Fragala, I.; Ledoux, I.; Diaz-Garcia, M. A.; Marks, T. J. J. Am. Chem. Soc. 1997, 119, 9550-9557.
81. (a) Ballhausen, C. J.; Liehr, A. D. J. Am. Chem. Soc. 1959, 81, 538-542.
82. (b) Holm, R. H. J. Am. Chem. Soc. 1960, 82, 5632-5636.
83. (c) Maki, G. J. Chem. Phys. 1958, 29, 1129-1138.
84. Shimazaki, Y.; Tani, F.; Fukui, K.; Naruta, Y.; Yamauchi, O. J. Am. Chem. Soc. 2003, 125, 10512-10513.
85. Freire, C.; de Castro, B. J. Chem. Soc., Dalton Trans. 1998, 1491-1497.
86. + is observed during the temperature cycle with a signal of the decomposition product around g = 2.1.
87. Glaser, T.; Hedman, B.; Hodgson, K. O.; Solomon, E. I. Acc. Chem. Res. 2000, 33, 859-868.
88. (a) Kapturkiewicz, A.; Behr, B. Inorg. Chim. Acta 1983, 69, 247-251.
89. (b) Opallo, M.; Behr, B.; Kapturkiewicz, A. J. Electroanal. Chem. 1985, 162, 427-432.
90. (c) Goldsby, K. A.; Blaho, J. K.; Hoferkamp, L. A. Polyhedron 1989, 8, 113-115.
91. (d) Böttcher, A.; Elias, H.; Jäger, E.-G.; Langfelderova, H.; Mazur, M.; Müller, L.; Paulus, H.; Pelikan, P.; Rudolph, M.; Valko, M. Inorg. Chem. 1993, 32, 4131-4138.
92. (e) Leung, W.-H.; Chan, E. Y. Y.; Chow, W. K. F.; Williams, I. D.; Peng, S.-M. J. Chem. Soc., Dalton Trans. 1996, 1229-1236.
93. (f) Vilas-Boas, M.; Freire, C.; de Castro, B.; Christensen, P. A.; Hillmann, A. R. Inorg. Chem. 1997, 36, 4919-4929.
94. Buchanan, R. M.; Pierpont, C. G. J. Am. Chem. Soc. 1980, 102, 4951-4957.
95. (a) Dei, A.; Gatteschi, D.; Sangregorio, C.; Sorace, L. Acc. Chem. Res. 2004, 37, 827-835.
96. (b) Shultz, D. A. In Magnetism: Molecules to Materials; Miller, J.-S., Drillon, M., Eds.; Wiley-VCH: Weinheim, Germany, 2001; Vol. II, pp 281-306.
97. Adams, D. M.; Dei, A.; Rheingold, A. L.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 8221-8229.
98. (a) Pierpont, C. G.; Lange, C. W. Prog. Inorg. Chem. 1994, 41, 331-442.
99. (b) Pierpont, C. G. Coord. Chem. Rev. 2001, 216, 99-125.
100. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
101. (a) Hashihayata, T.; Ito, Y.; Katsuki, T. Synlett 1996, 1079-1081.
102. (b) Hashihayata, T.; Ito, Y.; Katsuki, T. Tetrahedron 1997, 53, 9541-9552.
103. (c) Miura, K.; Katsuki, T. Synlett 1999, 783-785.