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1H NMR spectra with known compounds (2a, 2d, 2f, 2g, 3d and 3h) or by MS identification of characteristic fragments of type 5 for regioisomer 2 (2b and 2e) and of type 6 for regioisomer 3 (3b, 3e and 3f).
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2 at room temp. gave an aldehyde of type 9 quantitatively.
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2 at room temp. gave an aldehyde of type 9 quantitatively.
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34
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60849108517
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The ee values were measured by HPLC analysis using CHIRALCEL ODH as the chiral stationary phase (see Exp. Sect.).
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