Mechanism of copper(I)-catalyzed cyclopropanation: A DFT study calibrated with copper(I) alkene complexes

Journal of Organometallic Chemistry

Volumn 684, Issue 1-2, 2003, Pages 124-143

  Straub, Bernd F ^a,b   Gruber, Irene ^a   Rominger, Frank ^a   Hofmann, Peter ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b UNIVERSITY OF MUNICH   (Germany)

Author keywords

Carbene ligands; Copper; Copper carbenes; Cyclopropanation; Density functional calculations; Homogeneous catalysis; N ligands

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; CARBENOID; COPPER COMPLEX; COPPER DERIVATIVE; COPPER IMINOPHOSPHANAMIDE; CYCLOBUTANE DERIVATIVE; CYCLOPROPANE DERIVATIVE; ETHYLENE; LIGAND; METAL; UNCLASSIFIED DRUG;

ARTICLE; ARTIFACT; CALCULATION; CALIBRATION; CATALYSIS; CHEMICAL STRUCTURE; COMPUTER ANALYSIS; CONTROLLED STUDY; CYCLOPROPANATION; DENSITY; DISSOCIATION; ELECTRONICS; LIGAND BINDING; MOLECULAR STABILITY; PHASE TRANSITION; RELIABILITY; SOLVATION;

EID: 0142057101     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(03)00520-5     Document Type: Article

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