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Crystal data for 1: C16H8Cl5N 2O3V, M, 504.43, triclinic, space group Pl, a, 8.1177(19) Å, 9.394(2) b= 13.531(3) Å, α, 96.038(4)°, β, 92.073(4)°, γ, 115.399(4)°, V, 923.1(4) Å3, Z, 2, rho;calcd, 1.815 g cm-3, F(000, 500, μ(Mo Kα, 1.282 mn-1, T, 293(2) K, 4565 unique reflections [R(int, 0.0453, R (on F, 0.0915, Rw (on F2, 0.2149 (based on all data, Crystal data for 2: C26H 16Cl4N4O6V2, M, 504.43, triclinic, space group PĪ, a, 6.873(2) Å,b, 8.512(3) Å, c, 13.076(4) Å, α, 98.602(6)°, β, 95.049(6)°, γ, 105.828(6)°, V, 720.9(4) Å
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