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Volumn 44, Issue 23, 2005, Pages 8521-8530

Autoxidation-product-initiated dioxygenases: Vanadium-based, record catalytic lifetime catechol dioxygenase catalysis

Author keywords

[No Author keywords available]

Indexed keywords

CATECHOL 1,2 DIOXYGENASE; HYDROGEN PEROXIDE; VANADIUM;

EID: 28344432002     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050717t     Document Type: Article
Times cited : (26)

References (58)
  • 5
    • 28344440118 scopus 로고    scopus 로고
    • note
    • 2 are correct, however.
  • 13
    • 28344443095 scopus 로고    scopus 로고
    • note
    • We define an "autoxidation-product-initiated reaction" as one where an ROOH or other product of an (typically unintended) autoxidation initiates and facilitates an otherwise slow reaction.
  • 18
    • 28344455121 scopus 로고    scopus 로고
    • note
    • 6
  • 22
    • 0001289976 scopus 로고
    • 3-catalyzed DTBC oxygenation in which benzoquinone disappears in the early stages according to GLC analysis: Matsumoto, M.; Kuroda, K. J. Am. Chem. Soc. 1982, 104, 1433-1434.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 1433-1434
    • Matsumoto, M.1    Kuroda, K.2
  • 27
    • 0000835432 scopus 로고
    • and ref 11 therein
    • 8- into monomeric Nb-peroxy species useful in subsequent syntheses: Finke, R. G.; Droege, M. W. J. Am. Chem. Soc. 1984, 106, 7274 and ref 11 therein.
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 7274
    • Finke, R.G.1    Droege, M.W.2
  • 36
    • 28344434528 scopus 로고    scopus 로고
    • note
    • 2 and V-based polyoxoanions involve V-fragments of the polyoxoanions as the true catalysts, rather than intact polyoxoanion catalysis.
  • 37
    • 33847090283 scopus 로고
    • Original work using the pseudoelementary step concept: (a) Field, R. J.; Noyes, R. M. Acc. Chem. Res. 1977, 10, 214-221.
    • (1977) Acc. Chem. Res. , vol.10 , pp. 214-221
    • Field, R.J.1    Noyes, R.M.2
  • 42
    • 33845378053 scopus 로고
    • (c) Professor Grove's aerobic olefin epoxidation dioxygenase: Groves, J. T.; Quinn, R. J. Am. Chem. Soc. 1985, 107, 5790-5792. This classic system has not been commercialized due, it is our understanding, to its low catalytic turnover frequencies (ca. 1 turnover/h), irreversible inactivation to Ru(III), product inhibition, and eventual oxidative inactivation of the porphyrin-based catalyst system. It is a remarkable system nevertheless.
    • (1985) J. Am. Chem. Soc. , vol.107 , pp. 5790-5792
    • Groves, J.T.1    Quinn, R.2
  • 43
  • 47
    • 0002833984 scopus 로고
    • 2 is formed and then is crucial in helping to create a new (dioxygenase) catalyst. See: Chen, J. D.; Sheldon, R. A. J. Catal. 1995, 153, 1-8.
    • (1995) J. Catal. , vol.153 , pp. 1-8
    • Chen, J.D.1    Sheldon, R.A.2
  • 56
    • 0347721772 scopus 로고    scopus 로고
    • and references therein to the extensive prior literature of autoxidation
    • Weiner, H.; Trovarelli, A.; Finke, R. G. J. Mol. Catal. A: Chem. 2001, 191, 217-252 and references therein to the extensive prior literature of autoxidation.
    • (2001) J. Mol. Catal. A: Chem. , vol.191 , pp. 217-252
    • Weiner, H.1    Trovarelli, A.2    Finke, R.G.3
  • 58
    • 26644474112 scopus 로고    scopus 로고
    • Kinetic and Mechanistic Studies of Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases
    • published online Sept 17
    • Yin, C.-X.; Finke, R. G. Kinetic and Mechanistic Studies of Vanadium-Based, Extended Catalytic Lifetime Catechol Dioxygenases. J. Am. Chem. Soc., published online Sept 17, http://dx.doi.org/10.1021/ja052998+.
    • J. Am. Chem. Soc.
    • Yin, C.-X.1    Finke, R.G.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.