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Volumn 46, Issue 4, 2007, Pages 1048-1050

Room-temperature spin crossover observed for [(TPyA)Fe II(DBQ2-)FeIITPyA]2+ [TPyA = tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]

Author keywords

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Indexed keywords


EID: 33947147332     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic062400e     Document Type: Article
Times cited : (54)

References (25)
  • 6
    • 33947142600 scopus 로고    scopus 로고
    • In Spin Crossover in Transition Metal Compounds I; Gütlich, P., Goodwin, H. A., Eds.; Topics in Current Chemistry 233; Springer: New York, 2004.
    • (a) In Spin Crossover in Transition Metal Compounds I; Gütlich, P., Goodwin, H. A., Eds.; Topics in Current Chemistry Vol. 233; Springer: New York, 2004.
  • 12
    • 33947139349 scopus 로고    scopus 로고
    • In Spin Crossover in Transition Metal Compounds II; Gütlich, P., Goodwin, H. A., Eds.; Topics in Current Chemistry 234; Springer: New York, 2004.
    • (a) In Spin Crossover in Transition Metal Compounds II; Gütlich, P., Goodwin, H. A., Eds.; Topics in Current Chemistry Vol. 234; Springer: New York, 2004.
  • 17
    • 33947138880 scopus 로고    scopus 로고
    • Characterization of moisture-sensitive 1. Absorption spectrum (MeOH, λmax, nm (εM, L mol-1 cm-1, 250 (3.7 × 104, 330 (3.6 × 10 4, 428 (sh, 1.1 × 104, 752 (3.8 × 10 3, IR (KBr, νCH 3078 (w, 2951 (m, 1605 (s, 1573 (w, 1502 (vs, 1485 (sh, vs, 1442 (vs, 1335 (s, 1160 (m, 1055 (multiple, br, 905 (m, 763 (s, 655 (m, 521 (m) cm-1. Anal. Calcd for C 50H54B2F8Fe2N 8O4: C, 53.80; H, 4.88; N, 10.04. Found: C, 54.11; H, 5.04; N, 10.19
    • 4: C, 53.80; H, 4.88; N, 10.04. Found: C, 54.11; H, 5.04; N, 10.19.
  • 18
    • 33947103277 scopus 로고    scopus 로고
    • Crystal and structure refinement parameters for 1. At 208(2) K, C50H54B2F8Fe2N 8O4, fw, 1116.33 g mol-1, monoclinic, space group P21/c, a, 15.245(2) Å, b, 18.481(3) Å, c, 19.241(3) Å, β, 107.588(2)°, V, 5167.4(14)Å3, Z, 4, dcalcd, 1.435 g cm-3, μ(Mo Kα, 0.643 mm-1, R1, 0.0864, wR2, 0.2438. At 298(2) K, monoclinic, space group P21/c, a, 15.398(2) Å, b, 18.553(2) Å, c, 19.548(2) Å, β, 107.824(2)°, V, 5316.4(9) Å3, Z, 4, dcalcd, 1.395 g cm-3, μ(Mo Kα, 0.625 mm-1, R1, 0.0598, wR2, 0.1782. Data were collected on a Bruker SMART automatic diffractometer using graphite-monochromated Mo Kα
    • -1, R1 = 0.0598, wR2 = 0.1782. Data were collected on a Bruker SMART automatic diffractometer using graphite-monochromated Mo Kα (λ = 0.71073 Å) radiation. The structure was solved by direct methods and refined by full-matrix least-squares refinement using the SHELKL97 programs.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.