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in press
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Min, K. S.; DiPasquale, A.; Golen, J. A.; Rheingold, A. L.; Miller, J. S. J. Am. Chem. Soc. 2007, 129, in press.
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Characterization of moisture-sensitive 1. Absorption spectrum (MeOH, λmax, nm (εM, L mol-1 cm-1, 250 (3.7 × 104, 330 (3.6 × 10 4, 428 (sh, 1.1 × 104, 752 (3.8 × 10 3, IR (KBr, νCH 3078 (w, 2951 (m, 1605 (s, 1573 (w, 1502 (vs, 1485 (sh, vs, 1442 (vs, 1335 (s, 1160 (m, 1055 (multiple, br, 905 (m, 763 (s, 655 (m, 521 (m) cm-1. Anal. Calcd for C 50H54B2F8Fe2N 8O4: C, 53.80; H, 4.88; N, 10.04. Found: C, 54.11; H, 5.04; N, 10.19
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4: C, 53.80; H, 4.88; N, 10.04. Found: C, 54.11; H, 5.04; N, 10.19.
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Crystal and structure refinement parameters for 1. At 208(2) K, C50H54B2F8Fe2N 8O4, fw, 1116.33 g mol-1, monoclinic, space group P21/c, a, 15.245(2) Å, b, 18.481(3) Å, c, 19.241(3) Å, β, 107.588(2)°, V, 5167.4(14)Å3, Z, 4, dcalcd, 1.435 g cm-3, μ(Mo Kα, 0.643 mm-1, R1, 0.0864, wR2, 0.2438. At 298(2) K, monoclinic, space group P21/c, a, 15.398(2) Å, b, 18.553(2) Å, c, 19.548(2) Å, β, 107.824(2)°, V, 5316.4(9) Å3, Z, 4, dcalcd, 1.395 g cm-3, μ(Mo Kα, 0.625 mm-1, R1, 0.0598, wR2, 0.1782. Data were collected on a Bruker SMART automatic diffractometer using graphite-monochromated Mo Kα
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-1, R1 = 0.0598, wR2 = 0.1782. Data were collected on a Bruker SMART automatic diffractometer using graphite-monochromated Mo Kα (λ = 0.71073 Å) radiation. The structure was solved by direct methods and refined by full-matrix least-squares refinement using the SHELKL97 programs.
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