A two-state reactivity model explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme oxoiron(IV) complexes

Angewandte Chemie - International Edition

Volumn 48, Issue 7, 2009, Pages 1291-1295

  Klinker, Eric J ^b   Shaik, Sason ^a   Hirao, Hajime ^b   Que Jr , Lawrence ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^b University of Minnesota   (United States)

Author keywords

Bioinorganic chemistry; Iron; Isotope effects; Isotopic labeling; Two state reactivity

Indexed keywords

BIOCHEMISTRY; BOND STRENGTH (MATERIALS); CARRIER MOBILITY; CHEMICAL BONDS; LABELING; STRENGTH OF MATERIALS;

BIOINORGANIC CHEMISTRY; IRON; ISOTOPE EFFECTS; ISOTOPIC LABELING; TWO-STATE REACTIVITY;

ISOTOPES;

HYDROCARBON; IRON; ISOTOPE; OXYGEN;

ARTICLE; CATALYSIS; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; ISOTOPE LABELING; KINETICS; METABOLISM; OXIDATION REDUCTION REACTION;

CATALYSIS; HYDROCARBONS; IRON; ISOTOPE LABELING; ISOTOPES; KINETICS; MODELS, CHEMICAL; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXYGEN;

EID: 60149107980     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200804029     Document Type: Article

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