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This was calculated with the Rehm-Weller equation: ΔG PET, E(ox, E(red, E(ex, e 2/εr, with E(ox, 0.12 V, E(red, 0.96 V, γ(ex, 490 nm, and e2/εr, 0.1 eV. See:(a) Rehm, D, Weller, A. Isr. J. Chem. 1970, 8, 259
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59949093812
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1 value is near to the limit of our instrument, the actual value might be even shorter. See: (a) Watanabe, N.; Kihara, N.; Furusho, Y.; Takata, T.; Araki, Y.; Ito, O. Angew. Chem., Int. Ed. 2003, 42, 681.
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1 value is near to the limit of our instrument, the actual value might be even shorter. See: (a) Watanabe, N.; Kihara, N.; Furusho, Y.; Takata, T.; Araki, Y.; Ito, O. Angew. Chem., Int. Ed. 2003, 42, 681.
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