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The two enantiomerically pure rac diastereomers 1c(2R,4R) and 1c(2S,4S) themselves were commercially available.
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The two enantiomerically pure rac diastereomers 1c(2R,4R) and 1c(2S,4S) themselves were commercially available.
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The angles have been named and defined according to the IU-PAC recommendations, see: J. Mol. Biol. 1970, 52, 1. Thus, Π, 0° if C1-H1 and O-C7 are syn periplanar, and Π >0° for a clockwise rotation of O-C7 viewed from C1 to O; likewise, ψ, 0° if C1-O and C7-H7 are syn periplanar, and ψ > 0° for a clockwise rotation of C7-H7 viewed from O to C7
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The angles have been named and defined according to the IU-PAC recommendations, see: J. Mol. Biol. 1970, 52, 1. Thus, Π = 0° if C1-H1 and O-C7 are syn periplanar, and Π >0° for a clockwise rotation of O-C7 viewed from C1 to O; likewise, ψ = 0° if C1-O and C7-H7 are syn periplanar, and ψ > 0° for a clockwise rotation of C7-H7 viewed from O to C7.
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35
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58649088152
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The absolute configurations (S) and (R) have been assigned according to the Cahn-Ingold-Prelog rules. For simple linear, branched, or cyclic alkyl residues compounds the priorities assigned to the substituents according to these rules may be regarded as a rough measure of their steric demand.
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The absolute configurations (S) and (R) have been assigned according to the Cahn-Ingold-Prelog rules. For simple linear, branched, or cyclic alkyl residues compounds the priorities assigned to the substituents according to these rules may be regarded as a rough measure of their steric demand.
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