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Volumn , Issue 1, 2009, Pages 43-52

Synthesis and 13C NMR spectroscopy of model compounds for the microstructure analysis of poly(vinyl glycoside)s

Author keywords

Chiral auxiliaries; Glycosylation; Microstructure; Poly(vinyl alcohol); Stereochemical effect

Indexed keywords


EID: 58649124755     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200800798     Document Type: Article
Times cited : (4)

References (35)
  • 8
    • 58649123036 scopus 로고    scopus 로고
    • manuscript in preparation
    • J. Yuan, H. Frauenrath, 2008, manuscript in preparation.
    • (2008)
    • Yuan, J.1    Frauenrath, H.2
  • 17
    • 58649111176 scopus 로고    scopus 로고
    • The two enantiomerically pure rac diastereomers 1c(2R,4R) and 1c(2S,4S) themselves were commercially available.
    • The two enantiomerically pure rac diastereomers 1c(2R,4R) and 1c(2S,4S) themselves were commercially available.
  • 24
    • 58649087331 scopus 로고    scopus 로고
    • The angles have been named and defined according to the IU-PAC recommendations, see: J. Mol. Biol. 1970, 52, 1. Thus, Π, 0° if C1-H1 and O-C7 are syn periplanar, and Π >0° for a clockwise rotation of O-C7 viewed from C1 to O; likewise, ψ, 0° if C1-O and C7-H7 are syn periplanar, and ψ > 0° for a clockwise rotation of C7-H7 viewed from O to C7
    • The angles have been named and defined according to the IU-PAC recommendations, see: J. Mol. Biol. 1970, 52, 1. Thus, Π = 0° if C1-H1 and O-C7 are syn periplanar, and Π >0° for a clockwise rotation of O-C7 viewed from C1 to O; likewise, ψ = 0° if C1-O and C7-H7 are syn periplanar, and ψ > 0° for a clockwise rotation of C7-H7 viewed from O to C7.
  • 35
    • 58649088152 scopus 로고    scopus 로고
    • The absolute configurations (S) and (R) have been assigned according to the Cahn-Ingold-Prelog rules. For simple linear, branched, or cyclic alkyl residues compounds the priorities assigned to the substituents according to these rules may be regarded as a rough measure of their steric demand.
    • The absolute configurations (S) and (R) have been assigned according to the Cahn-Ingold-Prelog rules. For simple linear, branched, or cyclic alkyl residues compounds the priorities assigned to the substituents according to these rules may be regarded as a rough measure of their steric demand.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.