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The presence of an equilibrium between [RuH(PMe3) 5, and [RuH(NH3)(PMe3) 4, in THF was reported in the following paper
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For an unequivocal exclusion of the hydrido mechanism shown in Scheme 3, a model study using an alkoxo-ruthenium may provide pertinent information. However, our attempts to isolate a stable isopropoxoruthenium complex met no success hampering further mechanistic clarification.
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For an unequivocal exclusion of the hydrido mechanism shown in Scheme 3, a model study using an alkoxo-ruthenium may provide pertinent information. However, our attempts to isolate a stable isopropoxoruthenium complex met no success hampering further mechanistic clarification.
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