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This envelope is constructed as a best fit to the part of the [Ru(NH 3)4bpy]2+ difference spectrum that cannot be attributed to vibronic contributions from bpy ligand distortions.50
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The envelope of reorganizational contributions that arise from distortions in internal bpy vibrational modes has been estimated from Huang-Rhys parameters that are based on the [Os(bpy)3]2+ rR spectrum,33 attenuated as necessary to allow for the effects of excited state-ground state configurational mixing as described elsewhere. 48 Similar correlations reported previously46,48,50 were based on the net amplitudes of the vibronic sidebands in the medium frequency regime, these amplitudes contain appreciable and varying contributions from 2nd order contributions in the low frequency vibrational modes48 and the resulting correlation lines are somewhat different
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