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Volumn 47, Issue 23, 2008, Pages 10921-10934

Metal-to-metal electron-transfer emission in cyanide-bridged chromium-ruthenium complexes: Effects of configurational mixing between ligand field and charge transfer excited states

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EID: 57949095554     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8011266     Document Type: Article
Times cited : (20)

References (78)
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    • Supporting information, see the paragraph at the end of this paper
    • Supporting information, see the paragraph at the end of this paper.
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    • This envelope is constructed as a best fit to the part of the [Ru(NH 3)4bpy]2+ difference spectrum that cannot be attributed to vibronic contributions from bpy ligand distortions.50
    • 50
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    • The envelope of reorganizational contributions that arise from distortions in internal bpy vibrational modes has been estimated from Huang-Rhys parameters that are based on the [Os(bpy)3]2+ rR spectrum,33 attenuated as necessary to allow for the effects of excited state-ground state configurational mixing as described elsewhere. 48 Similar correlations reported previously46,48,50 were based on the net amplitudes of the vibronic sidebands in the medium frequency regime, these amplitudes contain appreciable and varying contributions from 2nd order contributions in the low frequency vibrational modes48 and the resulting correlation lines are somewhat different
    • 48 and the resulting correlation lines are somewhat different.
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    • -1.
    • -1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.