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Note that, although highly ordered molecular layers of flat aromatic structures were observed on HOPG surface, mostly by scanning tunneling microscopy (see, for example, a) S.-S. Li, H.-J. Yan, L.-J. Wan, H.-B. Yang, B. H. Northop, P. J. Stang, J. Am. Chem. Soc. 2007, 129, 9268-9269;
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Note that, although highly ordered molecular layers of flat aromatic structures were observed on HOPG surface, mostly by scanning tunneling microscopy (see, for example, a) S.-S. Li, H.-J. Yan, L.-J. Wan, H.-B. Yang, B. H. Northop, P. J. Stang, J. Am. Chem. Soc. 2007, 129, 9268-9269;
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for non-planar π-systems, particularly without long alkyl chains such as the present trimeric metallocycle 2, such assembly on surfaces is rarely reported
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Angew. Chem. Int. Ed. 2008, 47, 2964-2968), for non-planar π-systems, particularly without long alkyl chains such as the present trimeric metallocycle 2, such assembly on surfaces is rarely reported.
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44
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57349118643
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In contrast to metallocycle 2, for the free ligand i only adlayers without any ordered structure are observed (see Supporting Information, Figure S5).
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In contrast to metallocycle 2, for the free ligand i only adlayers without any ordered structure are observed (see Supporting Information, Figure S5).
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