Inducing spin crossover in metallo-supramolecular polyelectrolytes through an amphiphilic phase transition

Journal of the American Chemical Society

Volumn 127, Issue 9, 2005, Pages 3110-3114

  Bodenthin, Yves ^a   Pietsch, Ullrich ^a   Möhwald, Helmuth ^b   Kurth, Dirk G ^b,c  

^a UNIVERSITY OF POTSDAM   (Germany)

^b MAX PLANCK INSTITUTE OF COLLOIDS AND INTERFACES   (Germany)

^c NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

LIQUID CRYSTALS; MAGNETIC PROPERTIES; NANOSTRUCTURED MATERIALS; PHASE TRANSITIONS; STRAIN; SUPRAMOLECULAR CHEMISTRY; THIN FILMS;

COORDINATION GEOMETRY; CRYSTAL FIELDS; MAGNETIC ARCHITECTURE; TRANSITION METAL IONS;

POLYELECTROLYTES;

ALKANEDIOL DERIVATIVE; ALKYL GROUP; AMPHOPHILE; IRON DERIVATIVE; METAL ION; POLYELECTROLYTE; PYRIDINE DERIVATIVE; TRANSITION ELEMENT;

ARTICLE; CRYSTAL STRUCTURE; FILM; GEOMETRY; LANGMUIR BLODGETT FILM; MAGNETISM; PHASE TRANSITION; SUPRAMOLECULAR CHEMISTRY; X RAY ANALYSIS;

EID: 14844363878     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0447210     Document Type: Article

References (45)

1. Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH: Weinheim, Germany, 1995. Lehn, J.-M. Science 2002, 295, 2400. Lehn, J.-M. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 4763-4768. Whitesides, G. M.; Grzybowski, B. Science 2002, 295, 2418.
2. Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH: Weinheim, Germany, 1995. Lehn, J.-M. Science 2002, 295, 2400. Lehn, J.-M. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 4763-4768. Whitesides, G. M.; Grzybowski, B. Science 2002, 295, 2418.
3. Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH: Weinheim, Germany, 1995. Lehn, J.-M. Science 2002, 295, 2400. Lehn, J.-M. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 4763-4768. Whitesides, G. M.; Grzybowski, B. Science 2002, 295, 2418.
4. Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH: Weinheim, Germany, 1995. Lehn, J.-M. Science 2002, 295, 2400. Lehn, J.-M. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 4763-4768. Whitesides, G. M.; Grzybowski, B. Science 2002, 295, 2418.
5. Holliday, B. J.; Mirkin, C. A. Angew. Chem. 2001, 113, 2076-2098.
6. Decurtins, S.; Gütlich, P.; Kohler, C. P.; Spiering, H.; Hauser, A. Chem. Phys. Lett. 1984, 105, 1.
7. Decurtins, S.; Gütlich, P.; Hasselbach, K. M.; Hauser, A.; Spiering, H. Inorg. Chem. 1985, 24, 2174.
8. Renz, F.; Oshio, H.; Ksenofontov, V.; Waldeck, M.; Spiering, H.; Gütlich, P. Angew. Chem., Int. Ed. 2000, 39, 3699.
9. Gu, Z. Z.; Sato, O.; Iyoda, T.; Hashimoto, K.; Fujishima, A. J. Phys. Chem. 1996, 100, 18289.
10. Sato, O.; Iyota, A.; Fujishima, A.; Hashimoto, K. Science 1996, 272, 704.
11. Attia, A. S.; Jung, O. S.; Pierpont, C. G. Inorg. Chim. Acta 1994, 226, 91.
12. Boillot, M.-L.; Roux, C.; Audiere, J.-P.; Dausse, A.; Zarembowitch J. Inorg. Chem. 1996, 35, 3975.
13. Kahn, O.; Martinez, C. J. Science 1998, 279, 44.
14. Gütlich, P.; Garcia, Y.; van Koningsbruggen, P. J.; Renz, F. Photo-Magnetism of Transition Metal Compounds. In Introduction to Physical Techniques in Molecular Magnetism: Structrural and Macroscopic Techniques; Palacio, F., Ressouche, E., Schweizer, J., Eds.; University Press: Zaragoza, Spanien, 2001.
15. Galyametdinov, Y.; Ksenofontov, V.; Prosvirin, A.; Ovchinnikov, I.; Ivanova, G.; Gütlich, P.; Haase, W. Angew. Chem., Int. Ed. 2001, 40, 4269. Soyer, H.; Dupart, E.; Gómez-García, C. J.; Mingotaud, C.; Delhaès, P. Adv. Mater. 1999, 11, 382.
16. Galyametdinov, Y.; Ksenofontov, V.; Prosvirin, A.; Ovchinnikov, I.; Ivanova, G.; Gütlich, P.; Haase, W. Angew. Chem., Int. Ed. 2001, 40, 4269. Soyer, H.; Dupart, E.; Gómez-García, C. J.; Mingotaud, C.; Delhaès, P. Adv. Mater. 1999, 11, 382.
17. Constable, E. C.; Baum, G.; Bill, E.; Dyson, R.; van Eldik, R.; Fenske, D.; Kaderli, S.; Morris, D.; Neubrand, A.; Neuburger, M.; Smith, D. R.; Wieghardt, K.; Zehnder, M.; Zuberbuhler, A. D. Chem. Eur. J. 1999, 5, 498-508.
18. Schütte, M.; Kurth, D. G.; Linford, M. R.; Cölfen, H.; Möhwald, H. Angew. Chem. 1998, 110, 3058-3061; Angew. Chem., Int. Ed. 1998, 37, 2891-2893.
19. Schütte, M.; Kurth, D. G.; Linford, M. R.; Cölfen, H.; Möhwald, H. Angew. Chem. 1998, 110, 3058-3061; Angew. Chem., Int. Ed. 1998, 37, 2891-2893.
20. Kurth, D. G.; Lehmann, P.; Schütte, M. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 5704-5707.
21. Kurth, D. G.; Meister, A.; Thünemann, A. F.; Förster, G. Langmuir 2003, 19, 4055.
22. Lehmann, P.; Kurth, D. G.; Brezesinski, G.; Symietz, C. Chem. Eur. J. 2001, 7, 1646-1651.
23. Kern, W. Semicond. Int. 1984, 94.
24. Parrat, L. G. Phys. Rev. 1954, 95, 359.
25. Erko, A.; Packe, I.; Gudat, W.; Abrosimov, N.; Firsov, A. Proc. SPIE-Int. Soc. Opt. Eng. 2000, 4145, 122-128.
26. Michalowicz, A.; Vlaic, G. J. Synchrotron Radiat. 1998, 5, 1317-1320.
27. Kharchenko, A.; Englisch, U.; Geue, Th.; Grenzer, J.; Pietsch, U.; Siebrecht, R. Neutron News 2000, 11, 4.
28. Bodenthin, Y.; Pietsch, U. Bessy Anu. Rep. 2001, 239.
29. Bodenthin, Y.; Grenzer, J.; Lauter, R.; Pietsch, U.; Lehmann, P.; Kurth, D. G.; Möhwald, H. J. Synchrotron Radiat. 2002, 9, 206-209. Bodenthin, Y.; Pietsch, U.; Grenzer, J.; Gene, Th.; Möhwald, H.; Kurth, D. G. J. Phys. Chem. B, in press.
30. Bodenthin, Y.; Grenzer, J.; Lauter, R.; Pietsch, U.; Lehmann, P.; Kurth, D. G.; Möhwald, H. J. Synchrotron Radiat. 2002, 9, 206-209. Bodenthin, Y.; Pietsch, U.; Grenzer, J.; Gene, Th.; Möhwald, H.; Kurth, D. G. J. Phys. Chem. B, in press.
31. Als-Nielsen, J.; McMorrow, D. Elements of Modern X-ray Physics; John Wiley and Sons Ltd.: New York, 2001.
32. The average bond length in bis-terpyridine complexes of Fe(II) is 1.89 Å for the central and 1.98 Å for the terminal positions or 1.94 Å on average. See: (a) Baker, A. T.; Goodwin, H. A. Aust. J. Chem. 1985, 38, 207. (b) Laine, P.; Gourdon, A.; Launay, J.-P. Inorg. Chem. 1995, 34, 5156. (c) Constable, E. C.; Davies, J. E.; Phillips, D.; Raithby, P. R. Polyhedron 1998, 17, 3989.
33. The average bond length in bis-terpyridine complexes of Fe(II) is 1.89 Å for the central and 1.98 Å for the terminal positions or 1.94 Å on average. See: (a) Baker, A. T.; Goodwin, H. A. Aust. J. Chem. 1985, 38, 207. (b) Laine, P.; Gourdon, A.; Launay, J.-P. Inorg. Chem. 1995, 34, 5156. (c) Constable, E. C.; Davies, J. E.; Phillips, D.; Raithby, P. R. Polyhedron 1998, 17, 3989.
34. The average bond length in bis-terpyridine complexes of Fe(II) is 1.89 Å for the central and 1.98 Å for the terminal positions or 1.94 Å on average. See: (a) Baker, A. T.; Goodwin, H. A. Aust. J. Chem. 1985, 38, 207. (b) Laine, P.; Gourdon, A.; Launay, J.-P. Inorg. Chem. 1995, 34, 5156. (c) Constable, E. C.; Davies, J. E.; Phillips, D.; Raithby, P. R. Polyhedron 1998, 17, 3989.
35. Yokoyama, T.; Murakami, Y.; Kiguchi, M.; Komatsu, T.; Kojima, N.; Phys. Rev. B 1998, 58, 14238. Michailowicz, A.; Moscovici, J.; Charton, J.; Sandid. F.; Benamrane, F.; Garcia, Y. J. Synchrotron Radiat. 2001, 8, 701.
36. Yokoyama, T.; Murakami, Y.; Kiguchi, M.; Komatsu, T.; Kojima, N.; Phys. Rev. B 1998, 58, 14238. Michailowicz, A.; Moscovici, J.; Charton, J.; Sandid. F.; Benamrane, F.; Garcia, Y. J. Synchrotron Radiat. 2001, 8, 701.
37. Siebrecht, R.; Schreyer, A.; Englisch, U.; Pietsch, U.; Zabel, H. Physica B 1998, 241-243, 169-171.
38. Zabel, H.; Siebrecht, R.; Schreyer, A. Physica B 2000, 276-278, 17-21. Kharchenko, A.; Englisch, U.; Geue, T.; Grenzer, J.; Pietsch, U.; Siebrecht, R. Neutron News 2000, 11, 29-32.
39. Zabel, H.; Siebrecht, R.; Schreyer, A. Physica B 2000, 276-278, 17-21. Kharchenko, A.; Englisch, U.; Geue, T.; Grenzer, J.; Pietsch, U.; Siebrecht, R. Neutron News 2000, 11, 29-32.
40. Chen, C. T.; Idzerda, Y. U.; Lin, H.-J.; Smith, N. V.; Meigs, G.; Chaban, E.; Ho, G. H.; Pellegrin, E.; Sette, F. Phys. Rev. Lett. 1995, 75, 152.
41. Mertins, H.-Ch.; Abrahamsohn, D.; Gaupp, A.; Schäfers, F.; Gudat, W.; Zaharko, O.; Grimmer, H.; Oppeneer, P. M. Phys. Rev. B 2002, 66, 184404.
42. Kune, J.; Oppeneer, P. M.; Merlins, H.-Ch.; Schäfers, F.; Gaupp, A.; Gudat, W.; Novak, P. J. Magn. Magn. Mater. 2002, 240, 454-456.
43. Meister, A.; Förster, G.; Thünemann, A.; Kurth, D. G. ChemPhysChem 2003, 4, 1095-1100. Kurth, D. G.; Severin, N.; Rabe, J. P. Angew. Chem. 2002, 41, 3833-3835; Angew. Chem., Int. Ed. 2002, 114, 3681-3683.
44. Meister, A.; Förster, G.; Thünemann, A.; Kurth, D. G. ChemPhysChem 2003, 4, 1095-1100. Kurth, D. G.; Severin, N.; Rabe, J. P. Angew. Chem. 2002, 41, 3833-3835; Angew. Chem., Int. Ed. 2002, 114, 3681-3683.
45. Meister, A.; Förster, G.; Thünemann, A.; Kurth, D. G. ChemPhysChem 2003, 4, 1095-1100. Kurth, D. G.; Severin, N.; Rabe, J. P. Angew. Chem. 2002, 41, 3833-3835; Angew. Chem., Int. Ed. 2002, 114, 3681-3683.