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Volumn 130, Issue 46, 2008, Pages 15250-15251

Nitrogenase model complexes [Cp*Fe(μ-SR1) 2(μ-η2-R2N=NH)FeCp*] (R 1 = Me, Et; R2 = Me, Ph; Cp* = η5- C5Me5): Synthesis, structure, and catalytic N-N bond cleavage of hydrazines on diiron centers

Author keywords

[No Author keywords available]

Indexed keywords

HYDRAZINE DERIVATIVE; NITROGENASE; SULFUR;

EID: 56449083772     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805025w     Document Type: Article
Times cited : (106)

References (41)
  • 3
    • 0001219252 scopus 로고    scopus 로고
    • (c) Eady, R. R. Chem. Rev. 1996, 96, 3013.
    • (1996) Chem. Rev , vol.96 , pp. 3013
    • Eady, R.R.1
  • 9
    • 84875478214 scopus 로고    scopus 로고
    • Bio-organometallic Approaches to Nitrogen Fixation Chemistry
    • Tolman, W. B, Ed, Wiley: Weinheim, Germany
    • (a) Peters, J. C.; Mehn, M. P. Bio-organometallic Approaches to Nitrogen Fixation Chemistry. In Activation of Small Molecules; Tolman, W. B., Ed.; Wiley: Weinheim, Germany, 2006; pp 81-119.
    • (2006) Activation of Small Molecules , pp. 81-119
    • Peters, J.C.1    Mehn, M.P.2
  • 10
    • 84902434526 scopus 로고    scopus 로고
    • Nitrogen Fixation
    • McCleverty, J. A, Meyer, T. J, Eds, Elsevier: Oxford
    • (b) Holland, P. L. Nitrogen Fixation. In Comprehensive Coordination Chemistry 11; McCleverty, J. A.; Meyer, T. J., Eds.; Elsevier: Oxford, 2004; Vol. 8, pp 569-599.
    • (2004) Comprehensive Coordination Chemistry 11 , vol.8 , pp. 569-599
    • Holland, P.L.1
  • 29
    • 56449096505 scopus 로고    scopus 로고
    • 2a, 1H NMR (THF-d8, δ 13.19 (br, 1H, NH, disappeared upon treatment with D2O, 7.39 (m, 2H, Ph, 7.29 (m, 3H, Ph, 1.56-1.62 (m, 4H, CH2CH3, 1.52 (s, 15H, Cp*-CH3, 1.26 (s, 15H, Cp*- CH3, 0.98-1.02 (m, 6H, CH2CH3, 2b, 1H NMR (C6D6-d6, δ 13.11 (br, 1H, NH, disappeared upon treatment with D 2O, 7.16 (br, 5H, Ph, 1.43 (br, 30H, Cp*-CH 3, 1.16 (br, 6H, CH3, 2c, 1H NMR (C6D6-d6, δ 12.65 (br, 1H, NH, disappeared upon treatment with D2O, 3.83 (s, 3H, CH3, 1.60 (br, 34H, CH2CH3, Cp*-CH3, 1.03 br, 6H, CH2CH 3
    • 3).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.