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Volumn 121, Issue 46, 1999, Pages 10838-10839

Reductive cleavage of the N-N bond: Synthesis of imidoiron(III) cubanes [6]

Author keywords

[No Author keywords available]

Indexed keywords

CUBANE DERIVATIVE; IRON; NITROGEN; NITROGENASE; SULFUR;

EID: 0033601066     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9919783     Document Type: Letter
Times cited : (51)

References (54)
  • 1
    • 7744224797 scopus 로고    scopus 로고
    • For a recent series of comprehensive reviews, see: (a) Howard, J. B.; Rees, D. C. Chem. Rev. 1996, 96, 2965.
    • (1996) Chem. Rev. , vol.96 , pp. 2965
    • Howard, J.B.1    Rees, D.C.2
  • 6
    • 0000777214 scopus 로고
    • Molybdenum Enzymes, Cofactors, and Model Systems; Stiefel, E. I., Coucouvanis, D., Newton, W. E., Eds.; American Chemical Society: Washington, DC
    • (c) Bolin, J. T.; Campobasso, N.; Muchmore, S. W.; Morgan, T. V.; Mortenson, L. E. In Molybdenum Enzymes, Cofactors, and Model Systems; Stiefel, E. I., Coucouvanis, D., Newton, W. E., Eds.; ACS Symp. Ser. No. 535; American Chemical Society: Washington, DC, 1993; pp 186-195.
    • (1993) ACS Symp. Ser. No. 535 , pp. 186-195
    • Bolin, J.T.1    Campobasso, N.2    Muchmore, S.W.3    Morgan, T.V.4    Mortenson, L.E.5
  • 28
    • 13044266900 scopus 로고    scopus 로고
    • 6c
    • 6c
  • 29
    • 13044259407 scopus 로고    scopus 로고
    • See Supporting Information
    • (b) See Supporting Information.
  • 32
    • 13044296837 scopus 로고    scopus 로고
    • 6-DMSO, 293 K): δ 36.17 (3 H, p-Me), 35.72 (3 H, p-Me), 35.20 (6 H, o-Me), 33.87 (6 H, o-Me), 26.58 (2 H, m-Mes), 25.91 (2 H, m-Mes)
    • 6-DMSO, 293 K): δ 36.17 (3 H, p-Me), 35.72 (3 H, p-Me), 35.20 (6 H, o-Me), 33.87 (6 H, o-Me), 26.58 (2 H, m-Mes), 25.91 (2 H, m-Mes).
  • 33
    • 13044289841 scopus 로고    scopus 로고
    • min/max (deg), unique/observed [I > 2σ(I)] data, R1/wR2 for observed data (%), GooF. (a) 1a-THF: 10.4231(3), 10.9167(5), 12.8489(5); 66.488(2), 69.768(2), 85.210(2); P1̄, 1, 200(2); 4.2/54.7, 5666/4047, 4.64/ 11.52, 1.025
    • min/max (deg), unique/observed [I > 2σ(I)] data, R1/wR2 for observed data (%), GooF. (a) 1a-THF: 10.4231(3), 10.9167(5), 12.8489(5); 66.488(2), 69.768(2), 85.210(2); P1̄, 1, 200(2); 4.2/54.7, 5666/4047, 4.64/ 11.52, 1.025.
  • 34
    • 13044295224 scopus 로고    scopus 로고
    • 6: 15.2729(7), 18.6174(7), 23.6395(10); 105.922(2), 96.730(2), 93.088(2); P1̄, 4, 170(2); 2.3/46.0, 17699/10168, 5.91/9.27, 1.022
    • 6: 15.2729(7), 18.6174(7), 23.6395(10); 105.922(2), 96.730(2), 93.088(2); P1̄, 4, 170(2); 2.3/46.0, 17699/10168, 5.91/9.27, 1.022.
  • 35
    • 13044255585 scopus 로고    scopus 로고
    • μ-Fe, 77.7(1)
    • μ-Fe, 77.7(1).
  • 36
    • 13044278706 scopus 로고    scopus 로고
    • 12mean Fe-N, 1.89(1); mean Fe-S, 2.37(3); mean Fe⋯Fe, 3.687(2); mean S-Fe-S, 78(2); mean Fe-S-Fe, 102(1)
    • 12mean Fe-N, 1.89(1); mean Fe-S, 2.37(3); mean Fe⋯Fe, 3.687(2); mean S-Fe-S, 78(2); mean Fe-S-Fe, 102(1).
  • 40
    • 13044268262 scopus 로고    scopus 로고
    • 6, 293 K): δ 13.54 (8 H, m-Ph), 11.77 (8 H m-Mes), 5.49 (24 H, o-Me), 5.02 (12 H, p-Me), 0.59 (8 H, o-Ph), -1.06 (4 H, p-Ph). Anion-mode laser desorption ionization mass spectrum (LDI-TOF MS): m/z 1192.4 (theoretical 1192.8)
    • 6, 293 K): δ 13.54 (8 H, m-Ph), 11.77 (8 H m-Mes), 5.49 (24 H, o-Me), 5.02 (12 H, p-Me), 0.59 (8 H, o-Ph), -1.06 (4 H, p-Ph). Anion-mode laser desorption ionization mass spectrum (LDI-TOF MS): m/z 1192.4 (theoretical 1192.8).
  • 41
    • 13044291181 scopus 로고    scopus 로고
    • e = 2
    • e = 2.
  • 46
    • 13044274707 scopus 로고    scopus 로고
    • 2 face), 2.496(1); N-Fe-N, 98.0(2); Fe-N-Fe, 81.6(1)
    • 2 face), 2.496(1); N-Fe-N, 98.0(2); Fe-N-Fe, 81.6(1).
  • 47
    • 0033575069 scopus 로고    scopus 로고
    • Metal-mediated N-N/N=N bond activation is a topic of current interest; for some recent examples, see: (a) Peters, R. G.; Warner, B. P.; Burns, C. J. J. Am. Chem. Soc. 1999, 121, 5585.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 5585
    • Peters, R.G.1    Warner, B.P.2    Burns, C.J.3
  • 54
    • 13044278705 scopus 로고    scopus 로고
    • 3e
    • 3e


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.