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0027159222
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(a) Chan, M. K.; Kim, J.; Rees, D. C. Science 1993, 260, 792.
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(b) Kim, J.; Woo, D.; Rees, D. C. Biochemistry 1993, 32, 7104.
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Biochemistry
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Molybdenum Enzymes, Cofactors, and Model Systems; Stiefel, E. I., Coucouvanis, D., Newton, W. E., Eds.; American Chemical Society: Washington, DC
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(c) Bolin, J. T.; Campobasso, N.; Muchmore, S. W.; Morgan, T. V.; Mortenson, L. E. In Molybdenum Enzymes, Cofactors, and Model Systems; Stiefel, E. I., Coucouvanis, D., Newton, W. E., Eds.; ACS Symp. Ser. No. 535; American Chemical Society: Washington, DC, 1993; pp 186-195.
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Bolin, J.T.1
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(a) Rod, T. H.; Hammer, B.; Nørskov, J. K. Phys. Rev. Lett. 1999, 82, 4054.
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Rod, T.H.1
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(c) Siegbahn, P. E. M.; Westerberg, J.; Svensson, M.; Crabtree, R. H. J. Phys. Chem. B 1998, 102, 1615.
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33750497852
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(m) Hoffmann, R.; Deng, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1062.
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Hoffmann, R.1
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26
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0001686889
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(a) Anderson, R. A.; Faegri, K., Jr.; Green, J. C.; Haaland, A.; Lappert, M. F.; Leung, W.-P.; Rydpal, K. Inorg. Chem. 1988, 27, 1782.
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Anderson, R.A.1
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Leung, W.-P.6
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27
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0001077548
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(b) Olmstead, M. M.; Power, P. P.; Shoner, S. C. Inorg. Chem. 1991, 30, 2547.
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Olmstead, M.M.1
Power, P.P.2
Shoner, S.C.3
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28
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13044266900
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6c
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6c
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29
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13044259407
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See Supporting Information
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(b) See Supporting Information.
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30
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0344142372
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2, has been crystallographically characterized: Hauptmann, R.; Kliss, R.; Henkel, G. Angew. Chem., Int. Ed. 1999, 38, 377.
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(1999)
Angew. Chem., Int. Ed.
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Hauptmann, R.1
Kliss, R.2
Henkel, G.3
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32
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13044296837
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6-DMSO, 293 K): δ 36.17 (3 H, p-Me), 35.72 (3 H, p-Me), 35.20 (6 H, o-Me), 33.87 (6 H, o-Me), 26.58 (2 H, m-Mes), 25.91 (2 H, m-Mes)
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6-DMSO, 293 K): δ 36.17 (3 H, p-Me), 35.72 (3 H, p-Me), 35.20 (6 H, o-Me), 33.87 (6 H, o-Me), 26.58 (2 H, m-Mes), 25.91 (2 H, m-Mes).
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33
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13044289841
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min/max (deg), unique/observed [I > 2σ(I)] data, R1/wR2 for observed data (%), GooF. (a) 1a-THF: 10.4231(3), 10.9167(5), 12.8489(5); 66.488(2), 69.768(2), 85.210(2); P1̄, 1, 200(2); 4.2/54.7, 5666/4047, 4.64/ 11.52, 1.025
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min/max (deg), unique/observed [I > 2σ(I)] data, R1/wR2 for observed data (%), GooF. (a) 1a-THF: 10.4231(3), 10.9167(5), 12.8489(5); 66.488(2), 69.768(2), 85.210(2); P1̄, 1, 200(2); 4.2/54.7, 5666/4047, 4.64/ 11.52, 1.025.
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34
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13044295224
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6: 15.2729(7), 18.6174(7), 23.6395(10); 105.922(2), 96.730(2), 93.088(2); P1̄, 4, 170(2); 2.3/46.0, 17699/10168, 5.91/9.27, 1.022
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6: 15.2729(7), 18.6174(7), 23.6395(10); 105.922(2), 96.730(2), 93.088(2); P1̄, 4, 170(2); 2.3/46.0, 17699/10168, 5.91/9.27, 1.022.
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35
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13044255585
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μ-Fe, 77.7(1)
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μ-Fe, 77.7(1).
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36
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13044278706
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12mean Fe-N, 1.89(1); mean Fe-S, 2.37(3); mean Fe⋯Fe, 3.687(2); mean S-Fe-S, 78(2); mean Fe-S-Fe, 102(1)
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12mean Fe-N, 1.89(1); mean Fe-S, 2.37(3); mean Fe⋯Fe, 3.687(2); mean S-Fe-S, 78(2); mean Fe-S-Fe, 102(1).
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38
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0000704556
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Hauptmann, R.; Kliss, R.; Schneider, J.; Henkel, G. Z. Anorg. Allg. Chem. 1998, 624, 1927.
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Z. Anorg. Allg. Chem.
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Hauptmann, R.1
Kliss, R.2
Schneider, J.3
Henkel, G.4
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39
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33751127094
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Ellison, J. J.; Senge, K. R.; Power, P. P. Angew. Chem., Int. Ed. Engl. 1994, 33, 1178.
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Angew. Chem., Int. Ed. Engl.
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Ellison, J.J.1
Senge, K.R.2
Power, P.P.3
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13044268262
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6, 293 K): δ 13.54 (8 H, m-Ph), 11.77 (8 H m-Mes), 5.49 (24 H, o-Me), 5.02 (12 H, p-Me), 0.59 (8 H, o-Ph), -1.06 (4 H, p-Ph). Anion-mode laser desorption ionization mass spectrum (LDI-TOF MS): m/z 1192.4 (theoretical 1192.8)
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6, 293 K): δ 13.54 (8 H, m-Ph), 11.77 (8 H m-Mes), 5.49 (24 H, o-Me), 5.02 (12 H, p-Me), 0.59 (8 H, o-Ph), -1.06 (4 H, p-Ph). Anion-mode laser desorption ionization mass spectrum (LDI-TOF MS): m/z 1192.4 (theoretical 1192.8).
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41
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13044291181
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e = 2
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e = 2.
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42
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0003171844
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4: Gall, R. S.; Connelly, N. G.; Dahl, L. F. J. Am. Chem. Soc. 1974, 96, 4017.
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J. Am. Chem. Soc.
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Gall, R.S.1
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Dahl, L.F.3
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0030498682
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4: Decker, A.; Fenske, D.; Maczek, K. Angew. Chem., Int. Ed. Engl. 1996, 35, 2863.
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Decker, A.1
Fenske, D.2
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44
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0001427165
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(a) Gall, R. S.; Chu, C. T.-W.; Dahl, L. F. J. Am. Chem. Soc. 1974, 96, 4019.
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Gall, R.S.1
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45
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0041200022
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(b) Chu, C. T.-W.; Gall, R. S.; Dahl, L. F. J. Am. Chem. Soc. 1982, 104, 737.
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Chu, C.T.-W.1
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46
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13044274707
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2 face), 2.496(1); N-Fe-N, 98.0(2); Fe-N-Fe, 81.6(1)
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2 face), 2.496(1); N-Fe-N, 98.0(2); Fe-N-Fe, 81.6(1).
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47
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0033575069
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Metal-mediated N-N/N=N bond activation is a topic of current interest; for some recent examples, see: (a) Peters, R. G.; Warner, B. P.; Burns, C. J. J. Am. Chem. Soc. 1999, 121, 5585.
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0032545026
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Kaplan, A.W.1
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Ball, G.E.3
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Bergman, R.G.5
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Maseras, F.1
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0000642314
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(a) Wucherer, E. J.; Tasi, M.; Hansert, B.; Powell, A. K.; Garland, M.-T.; Halet, J.-F.; Saillard, J.-Y.; Vahrenkamp, H. Inorg. Chem. 1989, 28, 3564.
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Wucherer, E.J.1
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Garland, M.-T.5
Halet, J.-F.6
Saillard, J.-Y.7
Vahrenkamp, H.8
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0006239113
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and references therein
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(c) Kabir, S. E.; Ruf, M.; Vahrenkamp, H. J. Organomet. Chem. 1998, 571, 91 and references therein.
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Kabir, S.E.1
Ruf, M.2
Vahrenkamp, H.3
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