Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis(oxazolinyl)phenyl-rhodium complex

Synlett

Volumn , Issue 12, 2004, Pages 2099-2102

  Tsuchiya, Yasunori ^a   Uchimura, Hirofumi ^a   Kobayashi, Kazuki ^a   Nishiyama, Hisao ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

Asymmetric catalysis; Bisoxazoline; Hydrosilylation; Rhodium; Styrene

Indexed keywords

ALKENE; BENZENE DERIVATIVE; BIS(OXAZOLINYL)PHENYLRHODIUM COMPLEX; RHODIUM COMPLEX; SILANE DERIVATIVE; STYRENE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; ASYMMETRIC ADDITION; ASYMMETRIC HYDROSILYLATION; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; HYDROSILYLATION;

EID: 5644228965     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-831312     Document Type: Article

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34. 4 (0.02 mmol) in THF (1 mL) was stirred for 1 h. Then the solvent was removed under reduced pressure to give the corresponding cationic complex as solids followed by addition of solvent, alkene, and the silane.
35. We did not observe formation of simple reduction products of alkenes or vinylsilanes derived from 'silylrhodation-β-hydride elimination' in most cases.