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0001668294
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The N-C-N type ligand-coordinated Pd complexes prepared by the transmetalation of stannane silane derivatives were reported by van Koten; see: Steenwinkel, P.; Jastrzebski, J. T. B. H.; Deelman, B.-D.; Grove, D. M.; Kooijman, H.; Veldman, N.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. Organometallics 1997, 16, 5486.
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0000057254
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2O is located at the equatorial position; see: van der Zeijden, A. A. H.; van Koten, G.; Luijk, R.; Vrieze, K.; Slob, C.; Krabbendam, H.; Spek, A. L. Inorg. Chem. 1988, 27, 1014.
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(a) Nishiyama, H.; Horihata, M.; Hirai, T.; Wakamatsu, S.; Itoh, K. Organometallics 1991, 10, 2706.
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65
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0000391681
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3N]; see: (b) Haarman, H. F.; Ernsting, J. M.; Kranenburg, M.; Kooijman, H.; Veldman, N.; Spek, A. L.; van Leeuwen, P. W. N. M.; Vrieze, K. Organometallics 1997, 16, 887.
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66
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0011485267
-
-
note
-
Selected bond distances (Å) and angles (deg) for 5e: Rh(1)-Cl(1) = 2.325(3), Rh(1)-Cl(2) = 2.331(3), Rh(1)-O(3) = 2.291(5), Rh-(1)-N(1) = 2.075(6), Rh(1)-N(2) = 2.082(6), Rh(1)-C(1) = 1.921(7); Cl(1)-Rh(1)-Cl(2) = 175.10(9), Cl(1)-Rh(1)-O(3) = 89.8(3), Cl(1)-Rh(1)-N(1) = 92.3(2), Cl(1)-Rh(1)-N(2) = 86.9(2), Cl(1)-Rh(1)-C(1) = 89.7(4) O(3)-Rh(1)-C(1) = 179.3(5), N(1)-Rh(1)-N(2) = 158.7(2).
-
-
-
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67
-
-
0001269493
-
-
2 oxidizes the N-C-N ligand-coordinated Ni(II) and Pt(II) complexes to Ni(III) and Pt(IV); see: Grove, D. M.; van Koten, G.; Zoet, R.; Murrall, N. W.; Welch, A. J. J. Am. Chem. Soc. 1983, 105, 1379.
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(b) Terheijden, J.; van Koten, G.; de Booys, J. L. Organometallics 1983, 2, 1882.
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69
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0000139463
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Other examples of the recoverable chiral complexes are as follows. Ru complex for the cyclopropanation: (a) Nishiyama, H.; Itoh, Y.; Matsumoto, H.; Park, S.-B.; Itoh, K. J. Am. Chem. Soc. 1994, 116, 2223.
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0033519296
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Ru complex for the Diels-Alder reaction: (c) Kündig, E. P.; Saudan, C. M.; Bernardinelli, G. Angew. Chem., Int. Ed. Engl. 1999, 38, 1220.
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Kündig, E.P.1
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72
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0011391519
-
-
note
-
The absolute configuration of anti-7 was determined by the retention time of the chiral HPLC analysis.
-
-
-
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73
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0001697761
-
-
The absolute configuration of syn-7 was determined by the retention time of the chiral HPLC analysis using the authentic sample, which was prepared by Roush's method (57% ee, IS, 1R); see: Roush, W. R.; Ando, K.; Powers, D. B.; Palkowits, A. D.; Halterman, R. L. J. Am. Chem. Soc. 1990, 112, 6339.
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0016092754
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(c) Childs, R. F.; Mulholland, D. L.; Nixon, A. Can. J. Chem. 1982, 60, 801.
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Childs, R.F.1
Mulholland, D.L.2
Nixon, A.3
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77
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0011393326
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note
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Selected bond distances (Å) and angles (deg) for 8: Rh(1)-Cl-(1) = 2.341(4), Rh(1)-Cl(2) = 2.338(4), Rh(1)-O(3) = 2.27(1), Rh(1)-N(1) = 2.06(1), Rh(1)-N(2) = 2.12(1), Rh(1)-C(1) = 1.93(2); Cl(1)-Rh(1)-Cl(2) = 177.9(2), Cl(1)-Rh(1)-O(3) = 91.9(3), Cl(1)-Rh(1)-N(1) = 87.9(4), Cl(1)-Rh(1)-N(2) = 91.2(3), Cl(1)-Rh(1)-C(1) = 92.2(5), O(3)-Rh(1)-C(1) = 173.9(6), N(1)-Rh(1)-N(2) = 160.0(5), Rh-(1)-O(3)-C(15)= 137(1).
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-
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78
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0025280370
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For Lewis acid carbonyl complexation, see: (a) Shambayati, S.; Crowe, W. E.; Schreiber, S. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 256.
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, vol.29
, pp. 256
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Shambayati, S.1
Crowe, W.E.2
Schreiber, S.L.3
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79
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0000964801
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Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, U.K.
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(b) Shambayati, S.; Schreiber, S. L. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, U.K., 1991; Vol. 1, p 283.
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, vol.1
, pp. 283
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Shambayati, S.1
Schreiber, S.L.2
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81
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0011437774
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note
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Setected bond distances (Å) and angles (deg) for 9: Rh(1)-Cl-(1) = 2.334(4), Rh(1)-Cl(2) = 2.340(4), Rh(1)-N(1) = 2.08(1), Rh(1)-N(2) = 2.12(1), Rh(1)-N(3) = 2.24(1), Rh(1)-C(1) = 1.87(1); Cl(1)-Rh-(1)-Cl(2) = 179.1(1), Cl(1)-Rh(1)-N(1) = 92.1(4), Cl(1)-Rh(1)-N(2) = 87.3(3), Cl(1)-Rh(1)-N(3) = 90.8(4), Cl(1)-Rh(1)-C(1) = 89.1(4), N(3)-Rh(1)-C(1) = 177.5(5), N(1)-Rh(1)-N(2) = 161.0(5).
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82
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0011440512
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-
note
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Selected bond distances (Å) and angles (deg) for 10: Rh(1)-C(1) = 1.941(7), Rh(1)-C(19) = 2.106(7), Rh(1)-N(1) = 2.053(5), Rh-(1)-N(2) = 2,055(5), C(19)-N(3) = 1.145(9); N(1)-Rh(1)-N(2) = 157.3(2), Rh(1)-C(19)-N(3) = 170.2(7).
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83
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33847085986
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(a) Yamamoto, Y.; Yatagai, H.; Naruta, Y.; Maruyama, K. J. Am. Chem. Soc. 1980, 102, 7107.
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Yamamoto, Y.1
Yatagai, H.2
Naruta, Y.3
Maruyama, K.4
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84
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0000416437
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(b) Yamamoto, Y.; Yatagai, H.; Ishihara, Y.; Maeda, N.; Maruyama, K. Tetrahedron 1984, 40, 2239.
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Yamamoto, Y.1
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Maeda, N.4
Maruyama, K.5
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86
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33751158182
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(d) Keck, G. E.; Savin, K. A.; Cressman, E. N. K.; Abbott, D. E. J. Org. Chem. 1994, 59, 7889.
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Keck, G.E.1
Savin, K.A.2
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Abbott, D.E.4
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89
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0002615295
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note
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Other examples of anti-selective allylation of aldehydes with γ-substituted (E)-allyltins without chelation or transmetalation were reported. One of the anti-selective allylations was only preceded by the use of aryl-substituted allyltins. The authors explained that these observations were due to a chairlike cyclic transition state; see: (a) Koreeda, M.; Tanaka, Y. Chem. Lett. 1982, 1299.
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Koreeda, M.1
Tanaka, Y.2
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91
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0029920186
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Another case was the use of the γ-substituted (E)-allyltins with a bulky substituent such as the tert-butyl or trialkylsilyl group at the β-position. This reaction was assumed to proceed via the inverse antiperiplanar acyclic transition state as in our case; see: (c) Nishigaichi, Y.; Ishida, N.; Nishida, M.; Takuwa, A. Tetrahedron Lett. 1996, 37, 3701.
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Nishigaichi, Y.1
Ishida, N.2
Nishida, M.3
Takuwa, A.4
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93
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0003441987
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Yamamoto, H., Ed.; OUP: Oxford, U.K.; Chapter 13
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(b) Nishiyama, H.; Motoyama, Y. In Lewis Acid Reagents: A Practical Approach; Yamamoto, H., Ed.; OUP: Oxford, U.K., 1999; Chapter 13.
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Nishiyama, H.1
Motoyama, Y.2
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0003441992
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Yamamoto, H., Ed.; Wiley-VCH: Weinheim, Germany; Chapter 14
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(c) Kündig, E. P.; Saudan, C. M. In Lewis Acids in Organic Synthesis; Yamamoto, H., Ed.; Wiley-VCH: Weinheim, Germany, 2000; Vol. 2, Chapter 14.
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Kündig, E.P.1
Saudan, C.M.2
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96
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Matarasso-Tchiroukhine, E.; Cadiot, P. J. Organomet. Chem. 1976, 121, 155, 169.
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The DIRDIF program system
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Technical Report of Crystallography Laboratory; University of Nijmegen, Nijmegen, The Netherlands
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DIRDIF92: Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; Garcia-Granda, S.; Gould, R. O.; Smits, J. M. M.; Smykalla, C. The DIRDIF Program System; Technical Report of the Crystallography Laboratory; University of Nijmegen, Nijmegen, The Netherlands, 1992.
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Beurskens, P.T.1
Admiraal, G.2
Beurskens, G.3
Bosman, W.P.4
Garcia-Granda, S.5
Gould, R.O.6
Smits, J.M.M.7
Smykalla, C.8
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100
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Molecular Structure Corp., The Woodlands, TX
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teXane: Crystal Structure Analysis Package; Molecular Structure Corp., The Woodlands, TX, 1985 and 1992.
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