Toward general access to the Aspidosperma-type terpenoid indole alkaloids: Synthesis of the key 3,3-disubstituted piperidones through enantioselective intramolecular Heck-type reaction of chloroformamides

Chemical and Pharmaceutical Bulletin

Volumn 56, Issue 11, 2008, Pages 1567-1574

  Yasui, Yoshizumi ^a   Takeda, Hiroshi ^a   Takemoto, Yoshiji ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Enantioselective reaction; Terpenoid indole alkaloid; Total synthesis

Indexed keywords

CHLORINE DERIVATIVE; CHLOROFORMAMIDE DERIVATIVE; EPIVINBURNINE; FORMAMIDE DERIVATIVE; INDOLE ALKALOID; PALLADIUM; PIPERIDONE DERIVATIVE; POTASSIUM DERIVATIVE; SILVER DERIVATIVE; TERPENOID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASPIDOSPERMA; BIOTRANSFORMATION; CATALYST; ENANTIOSELECTIVITY; HECK REACTION; NONHUMAN; QUANTUM YIELD; REACTION ANALYSIS; REACTION TIME; SYNTHESIS;

ALKALOIDS; ASPIDOSPERMA; CATALYSIS; CHROMATOGRAPHY, THIN LAYER; FORMAMIDES; INDICATORS AND REAGENTS; INDOLES; PALLADIUM; PHOSPHATES; PIPERIDONES; POTASSIUM COMPOUNDS; SILVER COMPOUNDS; STEREOISOMERISM; TERPENES;

EID: 55749088765     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.56.1567     Document Type: Article

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