An unexpected ruthenium complex and its unique behavior as catalyst in dynamic kinetic resolution of secondary alcohols

Chemical Communications

Volumn , Issue 42, 2008, Pages 5333-5335

  Chen, Qihui ^a   Yuan, Chengye ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; RUTHENIUM COMPLEX;

ARTICLE; CATALYST; RACEMIZATION; SYNTHESIS;

EID: 55349101994     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b811627j     Document Type: Article

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32. When 4 Å molecular sieve was added to the reaction, the yield was increased dramatically up to 16% in general. It is indirect experimental evidence showing that water molecules were formed in this reaction
33. Catalyst can be recovered with 90% yield after racemization and the recovered catalyst can be used with same activity