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For Stille reactions of stannylcyclopropenes, see ref 6c.
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33745223065
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For the use of similar conditions in the trifluoromethylation of aldehydes, see
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61349160836
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3 is not understood at this time.
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3 is not understood at this time.
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40
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0141785188
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a of ∼30, enabling metalation with strong bases much in the same fashion as terminal alkynes. See: Fattahi, A.; McMarthy, R. E.; Ahmad, M. R.; Kass, S. R. J. Am. Chem. Soc. 2003, 125, 11746-11750.
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a of ∼30, enabling metalation with strong bases much in the same fashion as terminal alkynes. See: Fattahi, A.; McMarthy, R. E.; Ahmad, M. R.; Kass, S. R. J. Am. Chem. Soc. 2003, 125, 11746-11750.
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41
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33646928316
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For a a study of the effect of substituents at the 3-position on the HOMO and LUMO energies of cyclopropenes, see: Diev, V. V.; Kostikov, R. R.; Gleiter, R.; Molchanov, A. P. J. Org. Chem. 2006, 71, 4066-4077.
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For a a study of the effect of substituents at the 3-position on the HOMO and LUMO energies of cyclopropenes, see: Diev, V. V.; Kostikov, R. R.; Gleiter, R.; Molchanov, A. P. J. Org. Chem. 2006, 71, 4066-4077.
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DOI: 10.1002/anie.200802391
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43
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61349115267
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Iodocyclopropene 3 was stable and could be purified by column chromatography without noticeable decomposition.
-
Iodocyclopropene 3 was stable and could be purified by column chromatography without noticeable decomposition.
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-
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45
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15744370734
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For a useful alternative preparation of these types of compounds, see
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For a useful alternative preparation of these types of compounds, see: Chuprakov, S.; Rubin, M.; Gevorgyan, V. J. Am. Chem. Soc. 2005, 127, 3714-3715.
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46
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61349174351
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In the absence of further experiments, speculation about the mechanism of these reactions would be premature at this stage
-
In the absence of further experiments, speculation about the mechanism of these reactions would be premature at this stage.
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