-
1
-
-
33746577674
-
-
Fischer, E. O.; Maasböl, A. Angew. Chem., Int. Ed. Engl. 1964, 3, 580-581.
-
(1964)
Angew. Chem., Int. Ed. Engl
, vol.3
, pp. 580-581
-
-
Fischer, E.O.1
Maasböl, A.2
-
3
-
-
0003464697
-
-
Dötz, K. H, Ed, Wiley: New York
-
(b) Topics in Organometallic Chemistry: Dötz, K. H., Ed.; Wiley: New York, 2004; Vol. 13.
-
(2004)
Topics in Organometallic Chemistry
, vol.13
-
-
-
4
-
-
0000550993
-
-
For η2-α-phospinocarbene complexes see: a
-
2-α-phospinocarbene complexes see: (a) Cotton, F. A.; Falvello, L. R.; Najjar, R. C. Organometallics 1982, 1, 1640-1644.
-
(1982)
Organometallics
, vol.1
, pp. 1640-1644
-
-
Cotton, F.A.1
Falvello, L.R.2
Najjar, R.C.3
-
5
-
-
84985574715
-
-
(b) Fischer, E. O.; Reitmeier, R.; Ackermann, K. Angew. Chem., Int. Ed. Engl. 1983, 22, 411-412.
-
(1983)
Angew. Chem., Int. Ed. Engl
, vol.22
, pp. 411-412
-
-
Fischer, E.O.1
Reitmeier, R.2
Ackermann, K.3
-
9
-
-
0000526573
-
-
(f) Anstice, H. M.; Fielding, H. H.; Gibson, V. C.; Housecroft, C. E.; Kee, T. P. Organometallics 1991, 10, 2183-2191.
-
(1991)
Organometallics
, vol.10
, pp. 2183-2191
-
-
Anstice, H.M.1
Fielding, H.H.2
Gibson, V.C.3
Housecroft, C.E.4
Kee, T.P.5
-
10
-
-
84985657645
-
-
(g) Kreissl, F. R.; Ostermeier, J.; Ogric, C. Chem. Ber. 1995, 128, 289-292.
-
(1995)
Chem. Ber
, vol.128
, pp. 289-292
-
-
Kreissl, F.R.1
Ostermeier, J.2
Ogric, C.3
-
11
-
-
16144366456
-
-
(h) Lehotkay, Th.; Wurst, K.; Jaitner, P.; Kreissl, F. R. J. Organomet. Chem. 1996, 523, 105-110.
-
(1996)
J. Organomet. Chem
, vol.523
, pp. 105-110
-
-
Lehotkay, T.1
Wurst, K.2
Jaitner, P.3
Kreissl, F.R.4
-
12
-
-
0033549726
-
-
(i) Dovesi, S.; Solari, E.; Scopelliti, R.; Floriani, C. Angew. Chem., Int. Ed. 1999, 38, 2388-2391.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 2388-2391
-
-
Dovesi, S.1
Solari, E.2
Scopelliti, R.3
Floriani, C.4
-
13
-
-
1842505617
-
-
(j) Merceron-Saffon, N.; Gornitzka, H.; Baceiredo, A.; Bertrand, G. J. Organomet. Chem. 2004, 689, 1431-1435.
-
(2004)
J. Organomet. Chem
, vol.689
, pp. 1431-1435
-
-
Merceron-Saffon, N.1
Gornitzka, H.2
Baceiredo, A.3
Bertrand, G.4
-
14
-
-
0030197322
-
-
For metallacyclic complexes containing M=C-PRR′ fragments, see: (a) Jamison, G. M.; Saunders, R. S.; Wheeler, D. R.; Alam, T. M.; McClain, M. D.; Loy, D. A. Organometallics 1996, 15, 3244-3246.
-
For metallacyclic complexes containing M=C-PRR′ fragments, see: (a) Jamison, G. M.; Saunders, R. S.; Wheeler, D. R.; Alam, T. M.; McClain, M. D.; Loy, D. A. Organometallics 1996, 15, 3244-3246.
-
-
-
-
15
-
-
0000361508
-
-
(b) Scheer, M.; Kramkowski, P.; Schuster, K. Organometallics 1999, 18, 2874-2883.
-
(1999)
Organometallics
, vol.18
, pp. 2874-2883
-
-
Scheer, M.1
Kramkowski, P.2
Schuster, K.3
-
16
-
-
0000563058
-
-
(c) Burrows, A. D.; Carr, N.; Green, M.; Lynam, J. M.; Mahon, M. F.; Murray, M.; Kiran, B.; Nguyen, M. T.; Jones, C. Organometallics 2002, 21, 3076-3078.
-
(2002)
Organometallics
, vol.21
, pp. 3076-3078
-
-
Burrows, A.D.1
Carr, N.2
Green, M.3
Lynam, J.M.4
Mahon, M.F.5
Murray, M.6
Kiran, B.7
Nguyen, M.T.8
Jones, C.9
-
18
-
-
0037048714
-
-
(a) Despagnet, E.; Miqueu, K.; Gornitzka, H.; Dyer, P. W.; Bourissou, D.; Bertrand, G. J. Am. Chem. Soc. 2002, 124, 11834-11835.
-
(2002)
J. Am. Chem. Soc
, vol.124
, pp. 11834-11835
-
-
Despagnet, E.1
Miqueu, K.2
Gornitzka, H.3
Dyer, P.W.4
Bourissou, D.5
Bertrand, G.6
-
19
-
-
55249084581
-
-
Despagnet, E. Ph.D. Thesis, Université Paul Sabatier, Toulouse, France, 2002 (national no. 2002TOU30073).
-
(b) Despagnet, E. Ph.D. Thesis, Université Paul Sabatier, Toulouse, France, 2002 (national no. 2002TOU30073).
-
-
-
-
21
-
-
4243133500
-
-
(b) Kreissl, F. R.; Stückler, P.; Meineke, E. W. Chem. Ber. 1977, 110, 3040-3045.
-
(1977)
Chem. Ber
, vol.110
, pp. 3040-3045
-
-
Kreissl, F.R.1
Stückler, P.2
Meineke, E.W.3
-
22
-
-
0031571448
-
-
(c) Filippou, A. C.; Wtissner, D.; Kociok-Köhn, G.; Hinz, I. J. Organomet. Chem. 1997, 541, 333-343.
-
(1997)
J. Organomet. Chem
, vol.541
, pp. 333-343
-
-
Filippou, A.C.1
Wtissner, D.2
Kociok-Köhn, G.3
Hinz, I.4
-
23
-
-
10144228427
-
-
(d) Romero, P. E.; Piers, W. E.; McDonald, R. Angew. Chem., Int. Ed. 2004, 43, 6161-6165.
-
(2004)
Angew. Chem., Int. Ed
, vol.43
, pp. 6161-6165
-
-
Romero, P.E.1
Piers, W.E.2
McDonald, R.3
-
24
-
-
0004289282
-
-
VCH: Weinheim, Germany
-
(a) Kreissl, F. R. Carbyne Complexes; VCH: Weinheim, Germany, 1988; p 117.
-
(1988)
Carbyne Complexes
, pp. 117
-
-
Kreissl, F.R.1
-
25
-
-
0000421150
-
-
(b) McGeary, M. J.; Tonker, T. L.; Templeton, J. L. Organometallics 1985, 4, 2102-2106.
-
(1985)
Organometallics
, vol.4
, pp. 2102-2106
-
-
McGeary, M.J.1
Tonker, T.L.2
Templeton, J.L.3
-
26
-
-
0001146554
-
-
(a) Terry, M. R.; Mercado, L. A.; Kelley, C.; Geoffroy, G. L.; Lugan, N.; Nombel, P.; Mathieu, R.; Haggerty, B. S.; Owens-Waltermire, B. E.; Rheingold, A. L. Organometallics 1994, 13, 843-865.
-
(1994)
Organometallics
, vol.13
, pp. 843-865
-
-
Terry, M.R.1
Mercado, L.A.2
Kelley, C.3
Geoffroy, G.L.4
Lugan, N.5
Nombel, P.6
Mathieu, R.7
Haggerty, B.S.8
Owens-Waltermire, B.E.9
Rheingold, A.L.10
-
28
-
-
55249085976
-
-
7b
-
7b
-
-
-
-
29
-
-
55249124903
-
-
Selected NMR data for 4b: 31P NMR (CD 2Cl2) δ 25.5 (dt, 1JPH, 545.7 Hz, 3JPH, 14 Hz) ppm; 13C{1H} NMR (CD2Cl2) δ 325.2 d, 1JPC, 24.5 Hz, Mn=C, ppm
-
PC = 24.5 Hz, Mn=C)) ppm.
-
-
-
-
30
-
-
0001511425
-
-
For explicit intramolecular insertion of CO across the M=C bond see: (a) Mitsudo, T.; Watanabe, H.; Sasaki, T.; Takegami, Y.; Watanabe, Y.; Kafuku, K.; Nakatsu, K. Organometallics 1989, 8, 368-378.
-
For explicit intramolecular insertion of CO across the M=C bond see: (a) Mitsudo, T.; Watanabe, H.; Sasaki, T.; Takegami, Y.; Watanabe, Y.; Kafuku, K.; Nakatsu, K. Organometallics 1989, 8, 368-378.
-
-
-
-
31
-
-
0034738042
-
-
(b) Grotjahn, D. B.; Bikzhanova, G. A.; Collins, L. S. B.; Concolino, T.; Lam, K.-C.; Rheingold, A. L. J. Am. Chem. Soc. 2000, 122, 5222-5223.
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 5222-5223
-
-
Grotjahn, D.B.1
Bikzhanova, G.A.2
Collins, L.S.B.3
Concolino, T.4
Lam, K.-C.5
Rheingold, A.L.6
-
32
-
-
55249124205
-
-
Selected spectroscopic data for 6c: 1H NMR (300.1 MHz, C6D5CD3, 298 K) δ 6.99 (t, 3JHH, 6.6 Hz, 2H, m-H (Ph, 6.81 (t, 3JHH, 6.6 Hz, 1H, p-H (Ph, 6.80 (d, 1JPH, 260.4 Hz, 1H, PHMes, 6.69 (s, 2H, m-H (Mes, 6.61 (d, 3JHH, 7.3 Hz, 2H, o-H (Ph, 4.49 (s, 5H, C5H5, 2.52 (s, 6H, o-CH3 (Mes, 2.04 (s, 3H, p-CH3 (Mes, ppm; 31P NMR (121.5 MHz, C6D5CD3, 298 K) δ 18.9 (d, 1JPH, 260.4 Hz) ppm; 13C{1H) NMR (125.8 MHz, C6D5CD3, 240 K) δ358.2 (d, 1JPC, 75.5 Hz, Mn=C-P, 233.0 (br s, Mn-CO, 118.2-142.9 (Ph and Mes, 90.5 (s, C5H5, 24.1 (br s, o-CH 3, 20.9 s, p-CH3
-
-1.
-
-
-
-
33
-
-
55249087346
-
-
-3. CCDC-692689 contains full crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre at www.ccdc.cam.ac.uk/data_request/cif.
-
-3. CCDC-692689 contains full crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre at www.ccdc.cam.ac.uk/data_request/cif.
-
-
-
-
34
-
-
55249098040
-
-
-1.
-
-1.
-
-
-
-
35
-
-
55249118081
-
-
-1.
-
-1.
-
-
-
-
36
-
-
55249090797
-
-
Chemical shifts of carbene Cα atoms in L 2ClRh=C(Ar)P(NiPr2)2 (δ 114.4 ppm, L2, CO)2; δ 120.6 ppm, L2, η4-nbd)6a are very upfield compared to shifts for the structurally similar (η4-cod)ClRh=C(OEt)R (δ 291.1 ppm)16b and, η4-cod)(CO)Rh=C(OEt)R, δ 281.2-297.4 ppm).16c Also, the Rh-Cα bond distance in (η4-nbd)ClRh=C(Ar)P(NiPr2) 2 (2.097 Å6a) is longer than the regular Rh=C bond (for example d(Rh-Cα, 1.994 Å in, η4- cod)(CO)Rh=C(OEt)CH=CHC6H4OMe], 16c) and the P-Cα bond (1.637 Å) is significantly shorter than a single bond (dP-C, 1.80-1.82 Å
-
α bond (1.637 Å) is significantly shorter than a single bond (d(P-C) = 1.80-1.82 Å).
-
-
-
-
37
-
-
0035817673
-
-
(b) Göttker-Schnetmann, I.; Aumann, R.; Bergander, K. Organometallics 2001, 20, 3574-3581.
-
(2001)
Organometallics
, vol.20
, pp. 3574-3581
-
-
Göttker-Schnetmann, I.1
Aumann, R.2
Bergander, K.3
-
38
-
-
0347717614
-
-
(c) Barluenga, J.; Vicente, R.; Lopez, L. A.; Rubio, E.; Tomas, M.; Alvarez-Rua, C. J. Am. Chem. Soc. 2004, 126, 470-471.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 470-471
-
-
Barluenga, J.1
Vicente, R.2
Lopez, L.A.3
Rubio, E.4
Tomas, M.5
Alvarez-Rua, C.6
-
39
-
-
55249102315
-
-
Selected spectroscopic data for 5c: 31P NMR (THF-d 8, 298 K, δ-44.0 (d, 1JPH, 403.8 Hz) ppm; 13C{1H} NMR (C6D5CD 3, 233 K) δ 239.9 (d, 2JPC= 19 Hz, P-C=C=O, 230.4 (d, 2JPC, 27.5 Hz, Mn-CO, 28.2 (d, 1JPC, 31.5 Hz, P-C=C=O) ppm; IR (THF) 1932 (s, v CO, 1725 (m br, vC=C=O) cm-1
-
-1.
-
-
-
-
40
-
-
55249098259
-
-
-1.
-
-1.
-
-
-
-
41
-
-
37049092356
-
-
Selected data for 7c: -31P NMR (C6D6. 298 K) δ 281.6 (br s) ppm; 13C{1H} NMR (C 6D6, 298 K) δ166.9 (d, 1JPC, 47 Hz, P=C) ppm. Selected data for 7d: 31P NMR (C6D 6, 298 K) δ 278.8 (br s) ppm; 13C{1H} NMR (C6D6, 298 K) δ 161.2 (d, 1J PC, 54.5 Hz, P=C, These data are very similar to those of (η1-P(Mes)=CPh2) transition-metal complexes: Eshtiagh-Hosseini, H, Kroto, H. W, Nixon, J. F, Maah, M. J, Taylor, M. J. J. Chem. Soc, Chem. Commun. 1981, 199-200
-
2) transition-metal complexes: Eshtiagh-Hosseini, H.; Kroto, H. W.; Nixon, J. F.; Maah, M. J.; Taylor, M. J. J. Chem. Soc., Chem. Commun. 1981, 199-200.
-
-
-
-
44
-
-
0000258814
-
-
The occurrence of three-band patterns in such anionic complexes is ascribed to an interaction of lithium cations with the oxygen atom of a CO group: (a) Ulmer, S. W, Scarstad, P. M, Burlitch, J. M, Hughes, R. E. J. Am. Chem. Soc. 1973, 95, 4469-4471
-
The occurrence of three-band patterns in such anionic complexes is ascribed to an interaction of lithium cations with the oxygen atom of a CO group: (a) Ulmer, S. W.; Scarstad, P. M.; Burlitch, J. M.; Hughes, R. E. J. Am. Chem. Soc. 1973, 95, 4469-4471.
-
-
-
-
46
-
-
0000963497
-
-
(c) Darensbourg, M. J.; Darensbourg, D. J.; Burns, D.; Drew, D. A. J. Am. Chem. Soc. 1976, 98, 3127-3136.
-
(1976)
J. Am. Chem. Soc
, vol.98
, pp. 3127-3136
-
-
Darensbourg, M.J.1
Darensbourg, D.J.2
Burns, D.3
Drew, D.A.4
-
47
-
-
44449112791
-
-
(d) Sentets, S.; Serres, R.; Ortin, Y.; Lugan, N.; Lavigne, G. Organometallics 2008, 27, 2078-2091.
-
(2008)
Organometallics
, vol.27
, pp. 2078-2091
-
-
Sentets, S.1
Serres, R.2
Ortin, Y.3
Lugan, N.4
Lavigne, G.5
-
48
-
-
0347304486
-
-
Kato, T.; Polishchuk, O.; Gornitzka, H.; Baceiredo, A.; Bertrand, G. J. Organomet. Chem. 2000, 613, 33-36.
-
(2000)
J. Organomet. Chem
, vol.613
, pp. 33-36
-
-
Kato, T.1
Polishchuk, O.2
Gornitzka, H.3
Baceiredo, A.4
Bertrand, G.5
-
52
-
-
0011428686
-
-
(a) Sheridan, J. B.; Johnson, J. R.; Handwerker, B. M.; Geoffroy, G. L. Organometallics 1988, 7, 2404-2411.
-
(1988)
Organometallics
, vol.7
, pp. 2404-2411
-
-
Sheridan, J.B.1
Johnson, J.R.2
Handwerker, B.M.3
Geoffroy, G.L.4
-
53
-
-
11644261773
-
-
(b) Bassner, S. L.; Sheridan, J. B.; Kelley, C.; Geoffroy, G. L. Organometallics 1989, 8, 2121-2126.
-
(1989)
Organometallics
, vol.8
, pp. 2121-2126
-
-
Bassner, S.L.1
Sheridan, J.B.2
Kelley, C.3
Geoffroy, G.L.4
-
54
-
-
0001597233
-
-
(a) Magnuson, R. H.; Meirowitz, R.; Zulu, S.; Giering, W. P. J. Am. Chem. Soc. 1982, 104, 5790-5791.
-
(1982)
J. Am. Chem. Soc
, vol.104
, pp. 5790-5791
-
-
Magnuson, R.H.1
Meirowitz, R.2
Zulu, S.3
Giering, W.P.4
-
57
-
-
0010701189
-
-
(b) Reger, D. L.; Mintz, E.; Lebioda, L. J. Am. Chem. Soc. 1986, 108, 1940-1949.
-
(1986)
J. Am. Chem. Soc
, vol.108
, pp. 1940-1949
-
-
Reger, D.L.1
Mintz, E.2
Lebioda, L.3
-
58
-
-
0000143301
-
-
(c) Reger, D. L.; Klaeren, S. A.; Babin, J. E.; Adams, R. D. Organometallics 1988, 7. 181-189.
-
(1988)
Organometallics
, vol.7
, pp. 181-189
-
-
Reger, D.L.1
Klaeren, S.A.2
Babin, J.E.3
Adams, R.D.4
-
59
-
-
55249118755
-
-
The mixture of ketene (5c or 5d) and phosphaalkene (7c or 7d) complexes was observed during the reaction course, giving finally 7c or 7d in more than 97% E selectivity.
-
The mixture of ketene (5c or 5d) and phosphaalkene (7c or 7d) complexes was observed during the reaction course, giving finally 7c or 7d in more than 97% E selectivity.
-
-
-
|