Synthesis, reactivity, and theoretical studies of the η2(4e)-bonded phosphaalkyne complex [CpMo{P(OMe)3}2{η2(4e)-P≡CBut }][B(C6F5)4] and the molybdenum-mediated cyclocotrimerization of alkyne and phosphaalkyne ligands

Organometallics

Volumn 21, Issue 15, 2002, Pages 3076-3078

  Burrows, Andrew D ^a   Carr, Nicholas ^a   Green, Michael ^a,b   Lynam, Jason M ^a,b   Mahon, Mary F ^a   Murray, Martin ^b   Kiran, Boggavarapu ^c   Nguyen, Minh T ^c   Jones, Cameron ^d  

^a University of Bath Claverton Down   (United Kingdom)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

^c UNIVERSITY OF LEUVEN   (Belgium)

^d CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

LIGANDS;

ORGANOMETALLICS;

EID: 0000563058     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020169g     Document Type: Article

References (17)

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5. (a) Allen, S. R.; Beevor, R. G.; Green, M.; Norman, N. C.; Orpen, A. G.; Williams, I. D. J. Chem. Soc., Dallon Trans. 1985, 435.
6. (b) Allen, S. R.; Beevor, R. G.; Green, M.; Orpen, A. G.; Paddick, K. E.; Williams, I. D. J. Chem. Soc., Dalton Trans. 1987, 591.
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13. - anion is interacting with one of the phosphorus centers, this species undergoing reversible dissociation in solution.
14. Creve, S.; Nguyen, M. T.; Vanquickenborne, L. G. Eur. J. Inorg. Chem. 1999, 31281.
15. 3, Z = 4, R indices (I > 2σ(I)) R1 = 0.05H and wR2 = 0.1251.
16. Böhm, D.; Knoch, S.; Kummer, U.; Schmidt, U.; Zenneck, U. Angew. Chem., Int. Ed. Engl. 1995, 34, 198.
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