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note
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The appearance of a 1-rhoda(II)-1,3,5-hexatriene species, obtained from a o-dialkynyl-substituted diazoacetophenone and catalytic rhodium(II) octanoate and subsequent π-cyclization to a cyclopentadiene, was postulated by: (a) Padwa, A.; Kassir, J. M.; Xu, S. L. J. Org. Chem. 1997, 62, 1642-1652.
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For a general review of (related) rhodium(II)-mediated cyclizations involving carbene rhodium complexes obtained from diazo compounds see: (b) Padwa, A. J. Organomet. Chem. 2000; 610, 88-101.
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0031774005
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Similar results have been independently reported by: Barluenga, J.; Aznar, F.; Barluenga, S.; Fernández, M.; Martín, A.; García-Granda, S.; Piñera-Nicoláas, A. Chem. Eur. J. 1998, 4 (11), 2280-2298.
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0011439041
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note
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Compounds 14b-d were obtained in 82-86% yields, whereas compounds 14a was obtained in 48% yield together with a second isomer in 33% yield. For a detailed discussion see ref 1.
-
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57
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0011396222
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note
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2O)/MeOH an more active catalyst but due to formation of HCl only applicable on acid resistant systems: see ref 9.
-
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58
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0000399376
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note
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Carbene rhodium complexes of the type Rh=C(OR)C are not reported to our knowledge; those of the type Rh=C(OM)C are scarcely reported: (a) Erker, G.; Lecht, R.; Tsay, Y.-H.; Krüger, C. Chem. Ber. 1987, 120, 1763-1765.
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2 see: (a) Cardin, D. J.; Doyle, M. J.; Lappert, M. F. J. Chem. Soc., Chem. Commun. 1972, 927-928.
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0000632288
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2 have been developed by the Werner group: (d) Schwab, P.; Mahr, N.; Wolf, J.; Werner, H. Angew. Chem. 1993, 105, 1498-1500;
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0011490298
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note
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For a detailed discussion of chemical exchange phenomena in compounds 14 see ref 1.
-
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-
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73
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37049132144
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note
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For a discussion of the rotation parameters of the Rh=C bond in N-heterocyclic carbene rhodium complexes see: Doyle, M. J.; Lappert, M. F. J. Chem. Soc., Chem. Commun. 1974, 679-680.
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0011396078
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note
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13C chemical shift of the Rh=C bond. X-ray data are provided in refs 18b-f.
-
-
-
-
75
-
-
0011488503
-
-
note
-
+. In fact the zwitterionic character of tungstaoctatraenes 14 due to the electron-withdrawing CO ligands should be higher than that of compound 16c.
-
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76
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0002938890
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(a) Enders, D.; Gielen, H.; Runsink, J.; Breuer, K.; Boehm, K. Eur. J. Inorg. Chem. 1998, 913-919.
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(b) References 18b-f
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(b) References 18b-f.
-
-
-
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78
-
-
0011490299
-
-
note
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The mass spectrometer LAZARUS III DE was provided by Dr. H. Luftmann, Organisch-Chemisches Institut der Universität Münster. Data sets were collected with LeCroy DSO 9450A instrumentation.
-
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80
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0000921410
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