Facile generation of lithiocarbyne complexes: [M(≡CLi)(CO) 2{HB(pzMe2)3}] (M = Mo, W; pz = pyrazol-1-yl)

Organometallics

Volumn 27, Issue 20, 2008, Pages 5177-5179

  Cordiner, Richard L ^a   Hill, Anthony F ^a   Wagler, Jörg ^a,b  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; HYSTERESIS MOTORS; IRON COMPOUNDS; MOLYBDENUM; TELLURIUM COMPOUNDS; TUNGSTEN COMPOUNDS;

CARBYNE; ELECTROPHILES; FUNCTIONALIZED;

MOLYBDENUM COMPOUNDS;

EID: 55249089037     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800733m     Document Type: Article

References (28)

1. (a) Enriquez, A. J.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 2001, 123, 4992.
2. (b) Jamison, G. M.; White, P. S.; Harris, D. L.; Templeton, J. L. In Transition Metal Carbyne Complexes; Kreissl, F. R., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1992; Proceedings of the NATO Advanced Research Workshop on Transition Metal Carbyne Complexes, Wildbad Kreuth, Germany., p 201.
3. (c) Jamison, G. M.; Bruce, A. E.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 1991, 113, 5057.
4. (a) Peters, J. C.; Odom, A. L.; Cummins, C. C. Chem. Commun. 1997, 1995.
5. (b) Greco, J. C.; Peters, J. C.; Baker, T. A.; Davis, W. M.; Cummins, C. C.; Wu, G. J. Am. Chem. Soc. 2001, 123, 5003.
6. Carlson, R. G.; Gile, M. A.; Heppert, J. A.; Mason, M. H.; Powell, D. R.; Vander Velde, D.; Vilain, J. M. J. Am. Chem. Soc. 2002, 124, 1580.
7. (a) Hejl, A.; Trnka, T. M.; Day, M. W.; Grubbs, R. H. Chem. Commun. 2002, 2524.
8. (b) Romero, P. E.; Piers, W. R.; McDonald, R. Angew. Chem., Int. Ed. 2004, 43, 6161.
9. (c) Caskey, S. R.; Stewart, M. H.; Kivela, J. E.; Scotsman, J. R.; Johnson, M. J. A.; Kampf, J. W. J. Am. Chem. Soc. 2005, 127, 16750.
10. (d) Macnaughtan, M. L.; Johnson, M. J. A.; Kampf, J. W. J. Am. Chem. Soc. 2007, 129, 7708.
11. (e) Stewart, M. H.; Johnson, M. J. A.; Kampf, J. W. Organometallics 2007, 26, 5102.
12. (f) Gary, J. B.; Buda, C.; Johnson, M. J. A.; Dunietz, B. D. Organometallics 2008, 27, 814.
13. Caldwell, L. M. Adv. Organomet. Chem. 2008, 57, 1.
14. Leroux, F.; Schlosser, M.; Zohar, E.; Marek, I. In Chemistry of Organolithium Compounds; Rappoport, Z., Marek, I., Eds.; Wiley: Chichester, U.K., 2004; Vol. 1, p 435.
15. Lalor, F. J.; Desmond, T. J.; Cotter, G. M.; Shanahan, C. A.; Ferguson, G.; Parvez, M.; Ruhl, B. J. Chem. Soc., Dalton Trans. 1995, 1709.
16. 7
17. Brower, D. C.; Stoll, M.; Templeton, J. L. Organometallics 1989, 8, 2786.
18. Woodworth. B. E.; Templeton, J. L. J. Am. Chem. Soc. 1996, 118, 7418.
19. General procedure for the generation and electrophilic quenching of la: to a precooled (dry ice/propanone) solution of 4a (0.20 g, 0.37 mmol) in anhydrous THF (10 mL) was added a solution of "BuLi (0.15 mL, Aldrich, 2.50 M in hexane, 0.37 mmol). The mixture was stirred for 30 min, treated with the requisite electrophile (0.37 mmol), and then warmed to 0°C and stirred until the completion of the reaction, as indicated by in situ IR spectroscopy. The volatiles were removed under reduced pressure, and the desired product was isolated by extraction with dichloromethane. filtration through diatomaceous earth, dilution with hexane, concentration, and cooling. The products were generally obtained in spectropscopically pure form; however, if necessary, further purification could be effected by column chromatography on silica gel with an increasing dichloromethane/ hexane gradient as eluent.
20. 3), see: (a) Ahn, S.; Mayr, A. J. Am. Chem. Soc. 1996, 118, 7408.
21. (b) Filippou, A. C.; Hofmann, P.; Kiprof, P.; Schmidt, H. R.; Wagner, C. J. Organomet. Chem. 1993, 459, 233.
22. (c) Anderson, S.; Cook, D. J.; Hill, A. F.; Malget, J. M.; White, A. J. P.; Williams, D. J. Organometallics 2004, 23, 2552.
23. Cordiner, R. L.; Hill, A. F.; Wagler, J. Organometallics 2008, 27, 4532.
24. Chaona, S.; Lalor, F. J.; Desmond, T. J. Synth. Methods Organomet. Chem. 1997, 7, 189.
25. Etienne, M.; White, P. S.; Templeton, J. L. J. Am. Chem. Soc. 1991, 113, 2324.
26. Desmond, T.; Lalor, F. J.; Ferguson, G.; Parvez, M. J. Chem. Soc., Chem. Commun. 1984, 75.
27. max = 60°), 325 parameters, CCDC 693015.
28. Caldwell, L. M.; Hill, A. F.; Rae, A. D.; Willis, A. C. Organometallics 2008, 27, 341.