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Volumn 27, Issue 17, 2008, Pages 4532-4540

Reactions of [Mo(≡CBr)(CO)2{HB(pzMe2) 3}] (pz = pyrazol-1-yl) with amines: Synthesis of amino, pyridinium, and thiolato carbyne complexes

Author keywords

[No Author keywords available]

Indexed keywords

BITS; CHLORINE COMPOUNDS; MOLYBDENUM;

EID: 52649146957     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8004756     Document Type: Article
Times cited : (25)

References (102)
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    • For reviews of the chemistry of alkylidyne complexes: (a) Kim, H.-S.; Angelici, R. J. Adv. Organomet. Chem. 1987, 27, 51.
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    • Kim, H.-S.1    Angelici, R.2
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    • (c) Mayr, A.; Ahn, S. Adv. Trans. Metal Coord. Chem. 1996, 1, 1.
  • 4
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    • Transition Metal Carbyne Complexes
    • Kreissl, F. R, Ed, Kluwer: Dordrecht
    • (d) Transition Metal Carbyne Complexes; Kreissl, F. R., Ed.; NATO ASI Series C392; Kluwer: Dordrecht, 1992.
    • (1992) NATO ASI Series , Issue.C392
  • 6
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    • A review dealing with aminocarbyne complexes derived from electrophilic attack at coordinated isonitriles has also appeared
    • (f) Caldwell, L. M. Adv. Organomet. Chem. 2008, 56, 1. A review dealing with aminocarbyne complexes derived from electrophilic attack at coordinated isonitriles has also appeared:
    • (2008) Adv. Organomet. Chem , vol.56 , pp. 1
    • Caldwell, L.M.1
  • 18
    • 52649096832 scopus 로고    scopus 로고
    • Direct oxide abstraction was originally demonstrated by Fischer in the synthesis of the benzylidyne complex [W≡CPhBr(CO)4 using Br2PPh3 and the aminomethylidyne complex [W(≡CNEt2)Cl(CO)4] using thionyl chloride as the oxide-abstracting agent.7 Subsequent refinement by Mayr established the effectiveness of (CF3CO)2O and oxalyl halides, 8 which we9 and Filippou10 have applied to aminomethylidyne syntheses
    • 10 have applied to aminomethylidyne syntheses.
  • 24
    • 52649179251 scopus 로고
    • Transition Metal Carbynes
    • Kreissl, F. R, Ed
    • (c) Hill, A. F. Transition Metal Carbynes; Kreissl, F. R., Ed.; NATO ASI Series; 1992; Vol. 392, p 239.
    • (1992) NATO ASI Series , vol.392 , pp. 239
    • Hill, A.F.1
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    • Cambridge Crystallographic Data Centre. Conquest, November 2007 release/update.
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    • 4)]: (a) Green, M.; Howard, J. A. K.; James, A. P.; Jelfs, A. N.; de, M.; Nunn, C. M.; Stone, F. G. A. J. Chem. Soc., Chem. Commun. 1984, 1623.
    • 4)]: (a) Green, M.; Howard, J. A. K.; James, A. P.; Jelfs, A. N.; de, M.; Nunn, C. M.; Stone, F. G. A. J. Chem. Soc., Chem. Commun. 1984, 1623.
  • 71
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    • A situation where the slight nondegeneracy of benzylidyne acceptor orbitals assumes considerable importance is in the field of electro-optical applications: Da Re, R. E, Hopkins, M. D. Coord. Chem. Rev. 2005, 249, 1396
    • A situation where the slight nondegeneracy of benzylidyne acceptor orbitals assumes considerable importance is in the field of electro-optical applications: Da Re, R. E.; Hopkins, M. D. Coord. Chem. Rev. 2005, 249, 1396.
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    • (a) Fritsch, P. Ann. 1894, 279, 319.
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    • Fritsch, P.1
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    • (b) Buttenberg, W. P. Ann. 1894, 279, 327.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.