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Volumn 14, Issue 29, 2008, Pages 8904-8915

Ruthenium(II) pyridylamine complexes with diimine ligands showing reversible photochemical and thermal structural change

Author keywords

Ligand effects; N ligands; Photochromism; Reaction mechanisms; Ruthenium

Indexed keywords

ABSORPTION; ACETONITRILE; AMINES; CHEMICAL REACTIONS; DISSOCIATION; HEATING; LIGANDS; LIGHT ABSORPTION; LUMINESCENCE OF ORGANIC SOLIDS; ORGANIC COMPOUNDS; ORGANIC SOLVENTS; PHOTOCHEMICAL REACTIONS; RUTHENIUM; RUTHENIUM COMPOUNDS; SOLVENTS;

EID: 55049129799     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800827     Document Type: Article
Times cited : (30)

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    • In the preliminary communication,[19] we proposed a wrong structure tor 4, but we could clarify the structures of dissociation products in this study
    • [19] we proposed a wrong structure tor 4, but we could clarify the structures of dissociation products in this study.
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    • In the course of photoirradiation of a [D6]DMSO solution of 1 at 453 nm, we observed formation of two photoproducts showing σh symmetry in the 1H NMR spectrum (see Figure S6, Supporting Information, These two species exhibited one peak cluster in the ESIMS spectrum at m/ z 777.1, assignable to, Ru(bpy, D6]DMSO, TPA, PF6, M-PF6, see Figure S7, Supporting Information, This may be derived from photoisomerization of the Ru-coordinated DMSO molecule between the S-bound and O-bound forms: a) M. K. Smith, J. A. Gibson, C. G. Young, J. A. Broomhead, P. C. Junk, F. R. Keene, Eur. J. Inorg. Chem. 2000, 1365-1370;
    • -] (see Figure S7, Supporting Information). This may be derived from photoisomerization of the Ru-coordinated DMSO molecule between the S-bound and O-bound forms: a) M. K. Smith, J. A. Gibson, C. G. Young, J. A. Broomhead, P. C. Junk, F. R. Keene, Eur. J. Inorg. Chem. 2000, 1365-1370;
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    • In this case, the cryslallographic analysis resulted in relatively high R values due to the poor quality of the crystal. However, the result is adequate to describe the geometry of 7.
    • In this case, the cryslallographic analysis resulted in relatively high R values due to the poor quality of the crystal. However, the result is adequate to describe the geometry of 7.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.