-
1
-
-
85034928025
-
-
Kiepeis, N. E.; East, A. L. L.; Csàszàr, A. G.; Allen, W. D.; Lee, T. J.; Schwenke, D. W. J. Chem. Phys. 1983, 99, 3865.
-
(1983)
J. Chem. Phys
, vol.99
, pp. 3865
-
-
Kiepeis, N.E.1
East, A.L.L.2
Csàszàr, A.G.3
Allen, W.D.4
Lee, T.J.5
Schwenke, D.W.6
-
2
-
-
0033553138
-
-
Weis, P.; Kemper, P. R.; Bowers, M. T.; Xantheas, S. S. J. Am. Chem. Soc. 1999, 121, 3531.
-
(1999)
J. Am. Chem. Soc
, vol.121
, pp. 3531
-
-
Weis, P.1
Kemper, P.R.2
Bowers, M.T.3
Xantheas, S.S.4
-
8
-
-
12844249938
-
-
Ghosal, S.; Hemminger, J. C.; Bluhm, H.; Mun, B. S.; Hebenstreit, E. L. D.; Ketteler, G.; Olgetree, D. F.; Requejo, F. G.; Salmeron, M. Science 2005, 307, 563.
-
(2005)
Science
, vol.307
, pp. 563
-
-
Ghosal, S.1
Hemminger, J.C.2
Bluhm, H.3
Mun, B.S.4
Hebenstreit, E.L.D.5
Ketteler, G.6
Olgetree, D.F.7
Requejo, F.G.8
Salmeron, M.9
-
9
-
-
33646427186
-
-
Gopalakrishnan, S.; Liu, D.; Allen, H. C.; Kuo, M.; Shultz, M. J. Chem. Rev. 2006, 106, 1155.
-
(2006)
Chem. Rev
, vol.106
, pp. 1155
-
-
Gopalakrishnan, S.1
Liu, D.2
Allen, H.C.3
Kuo, M.4
Shultz, M.J.5
-
14
-
-
37049108170
-
-
Hey, M. J.; Shield, D. W.; Speight, J. M.; Will, M. C. J. Chem. Soc. Faraday Trans. 11981, 77, 123.
-
(1981)
J. Chem. Soc. Faraday Trans
, vol.1
, Issue.77
, pp. 123
-
-
Hey, M.J.1
Shield, D.W.2
Speight, J.M.3
Will, M.C.4
-
16
-
-
0029308703
-
-
Hu, J. H.; Shi, Q.; Davidovits, P.; Worsnop, D. R.; Zahniser, M. S.; Kolb, C. E. J. Phys. Chem. 1995, 99, 8768.
-
(1995)
J. Phys. Chem
, vol.99
, pp. 8768
-
-
Hu, J.H.1
Shi, Q.2
Davidovits, P.3
Worsnop, D.R.4
Zahniser, M.S.5
Kolb, C.E.6
-
17
-
-
0029509564
-
-
George, C.; Behnke, W.; Scheer, V.; Zetzsch, C.; Magi, L.; Ponche, J. L.; Mirabel, P. Geophys. Res. Lett. 1995, 22, 1505.
-
(1995)
Geophys. Res. Lett
, vol.22
, pp. 1505
-
-
George, C.1
Behnke, W.2
Scheer, V.3
Zetzsch, C.4
Magi, L.5
Ponche, J.L.6
Mirabel, P.7
-
20
-
-
33645522601
-
-
Muenter, A. H.; DeZwaan, J. L.; Nathanson, G. M. J. Phys. Chem. B 2006, 110, 4881.
-
(2006)
J. Phys. Chem. B
, vol.110
, pp. 4881
-
-
Muenter, A.H.1
DeZwaan, J.L.2
Nathanson, G.M.3
-
21
-
-
35948971356
-
-
Muenter, A. H.; DeZwaan, J. L.; Nathanson, G. M. J. Phys. Chem. c 2007, 111, 15043.
-
(2007)
J. Phys. Chem. c
, vol.111
, pp. 15043
-
-
Muenter, A.H.1
DeZwaan, J.L.2
Nathanson, G.M.3
-
22
-
-
40549126287
-
-
DeZwaan, J. L.; Brastad, S. M.; Nathanson, G. M. J. Phys. Chem. C 2007, 112, 3008.
-
(2007)
J. Phys. Chem. C
, vol.112
, pp. 3008
-
-
DeZwaan, J.L.1
Brastad, S.M.2
Nathanson, G.M.3
-
23
-
-
0037118398
-
-
Ringeisen, B. R.; Muenter, A. H.; Nathanson, G. M. J. Phys. Chem. B 2002, 106, 4988.
-
(2002)
J. Phys. Chem. B
, vol.106
, pp. 4988
-
-
Ringeisen, B.R.1
Muenter, A.H.2
Nathanson, G.M.3
-
25
-
-
36449007395
-
-
Benjamin, I.; Wilson, M. A.; Pohorille, A. J. Chem. Phys. 1994, 100, 6500.
-
(1994)
J. Chem. Phys
, vol.100
, pp. 6500
-
-
Benjamin, I.1
Wilson, M.A.2
Pohorille, A.3
-
26
-
-
0001139285
-
-
Baldelli, S.; Schnitzer, C.; Shultz, M. J.; Campbell, D. J. J. Phys. Chem. B 1997, 101, 4607.
-
(1997)
J. Phys. Chem. B
, vol.101
, pp. 4607
-
-
Baldelli, S.1
Schnitzer, C.2
Shultz, M.J.3
Campbell, D.J.4
-
29
-
-
34447557006
-
-
Cwiklik, L.; Andersson, G.; Dan, L. X.; Jungwirth, P. Chem Phys Chem 2007, 8, 1457.
-
(2007)
Chem Phys Chem
, vol.8
, pp. 1457
-
-
Cwiklik, L.1
Andersson, G.2
Dan, L.X.3
Jungwirth, P.4
-
31
-
-
0034249758
-
-
K+F~ ion pairs may also be more surface-active than F- alone because of their lower effective charge, although computer simulations show fewer Na+Cl- pairs at the surface than in bulk water. See Jungwirth, P, Tobias, D. J. J. Phys. Chem B 2000, 104, 7702 In addition, ion pairing between F- and K+ may also reduce the reactivity of F, but our studies indicate that CaI 2 is more effective than NaI in catalyzing interfacial D → H exchange and DCl desorption at high concentrations, even though Ca2+ and I- are more likely to be paired than Na+ and I, See ref 22
-
-. See ref 22.
-
-
-
-
32
-
-
23844527449
-
-
Andersson, G.; Krebs, T.; Morgner, H. Phys. Chem. Chem. Phys. 2005, 7, 2948.
-
(2005)
Phys. Chem. Chem. Phys
, vol.7
, pp. 2948
-
-
Andersson, G.1
Krebs, T.2
Morgner, H.3
-
33
-
-
34047273600
-
-
Andersson, G.; Morgner, H.; Cwiklik, L.; Jungwirth, P. J. Phys. Chem. C 2007, 111, 4379.
-
(2007)
J. Phys. Chem. C
, vol.111
, pp. 4379
-
-
Andersson, G.1
Morgner, H.2
Cwiklik, L.3
Jungwirth, P.4
-
34
-
-
0037118399
-
-
Ringeisen, B. R.; Muenter, A. H.; Nathanson, G. M. J. Phys. Chem. B 2002, 106, 4999.
-
(2002)
J. Phys. Chem. B
, vol.106
, pp. 4999
-
-
Ringeisen, B.R.1
Muenter, A.H.2
Nathanson, G.M.3
-
35
-
-
85178702377
-
-
Gly, is estimated from trends in Rondonini, S.; Longhi, P.; Mussini, P. R.; Mussini, T. Pure Appl. Chem. 1987, 59, 1693.
-
Gly, is estimated from trends in Rondonini, S.; Longhi, P.; Mussini, P. R.; Mussini, T. Pure Appl. Chem. 1987, 59, 1693.
-
-
-
-
36
-
-
0000305672
-
-
Commenga, H. K.; Schulze, F. W.; Thuerl, W. J. Chem. Eng. Data 1977, 22, 131.
-
(1977)
J. Chem. Eng. Data
, vol.22
, pp. 131
-
-
Commenga, H.K.1
Schulze, F.W.2
Thuerl, W.3
-
39
-
-
0042643164
-
-
Arshadi, M.; Yamdagni, R.; Kebarle, P. J. Phys. Chem. 1970, 74, 1475.
-
(1970)
J. Phys. Chem
, vol.74
, pp. 1475
-
-
Arshadi, M.1
Yamdagni, R.2
Kebarle, P.3
-
40
-
-
0004047722
-
-
3rd ed, McGraw-Hill: New York
-
Pitzer, K. S. Thermodynamics, 3rd ed.; McGraw-Hill: New York, 1995.
-
(1995)
S. Thermodynamics
-
-
Pitzer, K.1
-
42
-
-
24944441707
-
-
Lawrence, J. R.; Glass, S. V.; Nathanson, G. M. J. Phys. Chem. A 2005, 109, 7449.
-
(2005)
J. Phys. Chem. A
, vol.109
, pp. 7449
-
-
Lawrence, J.R.1
Glass, S.V.2
Nathanson, G.M.3
-
43
-
-
0000391511
-
-
The residence time τhalf can be extracted from the postchopper spectra by measuring the ratio ITD(texp, ITD(texp, where J is the integrated signal intensity at two exposure times texp and texp, For a solution in which F- is in excess, ITD(texp, τ/texp, erfc((texp/τ)1/2) exp(texp/τ, 2(texp/τ)1/2-1, r is the time in which the outgoing HF flux reaches 57% of the incoming DCl flux, and τhalf, 0.6τ is the analogous 50% time. See also Appendix I of Shi, Q, Davidovits, P, Jayne, J. T, Worsnop, D. W, Kolb, C. E. J. Phys. Chem. A 1999, 103, 8812
-
half = 0.6τ is the analogous 50% time. See also Appendix I of Shi, Q.; Davidovits, P.; Jayne, J. T.; Worsnop, D. W.; Kolb, C. E. J. Phys. Chem. A 1999, 103, 8812.
-
-
-
-
44
-
-
54249109285
-
-
-1.
-
-1.
-
-
-
-
45
-
-
54249129228
-
-
-1 are obtained from calculations in ref 23 assuming that the viscosities of pure glycerol and the 0.5 M KF solutions are equal. The coefficients should drop by half in 2.5 M KP-glycerol, which is approximately twice as viscous as pure glycerol.
-
-1 are obtained from calculations in ref 23 assuming that the viscosities of pure glycerol and the 0.5 M KF solutions are equal. The coefficients should drop by half in 2.5 M KP-glycerol, which is approximately twice as viscous as pure glycerol.
-
-
-
-
46
-
-
36448996163
-
-
For recent studies of ion-water interactions, see also Park, S.; Feyer, M. D. Proc. Nat. Aca. Sci 2007, 104, 16731
-
(a) For recent studies of ion-water interactions, see also Park, S.; Feyer, M. D. Proc. Nat. Aca. Sci 2007, 104, 16731
-
-
-
-
47
-
-
36148935198
-
-
and. (b) Smith, J. D.; Saykally, R. J.; Geissler, P. L. J. Am. Chem. Soc. 2007, 129, 13847.
-
and. (b) Smith, J. D.; Saykally, R. J.; Geissler, P. L. J. Am. Chem. Soc. 2007, 129, 13847.
-
-
-
-
48
-
-
0020793837
-
-
Hertz, H. G.; Versmold, H.; Yoon, C. Ber. Bunsenges. Phys. Chem. 1983, 87, 577.
-
(1983)
Ber. Bunsenges. Phys. Chem
, vol.87
, pp. 577
-
-
Hertz, H.G.1
Versmold, H.2
Yoon, C.3
-
50
-
-
33746489313
-
-
Laasonen, K.; Larrucea, J.; Sillapää, A. J. Chem. Phys. C 2006, 110, 12699.
-
(2006)
J. Chem. Phys. C
, vol.110
, pp. 12699
-
-
Laasonen, K.1
Larrucea, J.2
Sillapää, A.3
-
52
-
-
54249142066
-
-
The 103 s-1 estimate for the HF dissociation rate constant kf and a diffusion-limited recombination rate of kr, 4πRD, 3 × 108 M-1 s -1 for R, 10 Å and D, 5 × 10-7 cm2 s-1 yields a dissociation constant for HF in glycerol of Kacid, kf/kr ≈ 3 × 10-6, or approximately 100 times smaller than in water. The constant KGly ≈10-15.5 further yields a base dissociation constant of ∼1 × 10-10, which predicts a GlyO- concentration of ∼2 × 10-5 M in the 2 M KF solution. This value is close to the lower limit of the estimate of 10-4±1 using pH paper, as stated in the Experimental Procedure section
-
-4±1 using pH paper, as stated in the Experimental Procedure section.
-
-
-
-
53
-
-
0345393771
-
-
a, M.; Jungwirth, P.; Tobias, D. J.; Gerber, R. B. J. Phys. Chem. B 2003, 107, 12690.
-
(2003)
J. Phys. Chem. B
, vol.107
, pp. 12690
-
-
RoeselovARTINFSTARTaARTINFEND, M.1
Jungwirth, P.2
Tobias, D.J.3
Gerber, R.B.4
-
58
-
-
54249098177
-
-
Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; Wiley: New York, 1999; Appendix 4.
-
Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; Wiley: New York, 1999; Appendix 4.
-
-
-
|