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Volumn 106, Issue 19, 2002, Pages 4999-5010

Collisions of DCl with liquid glycerol: Evidence for rapid, near-interfacial D → H exchange and desorption

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR BEAM SCATTERING;

EID: 0037118399     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp013959x     Document Type: Article
Times cited : (33)

References (59)
  • 21
    • 0001498808 scopus 로고
    • for simulations of the state of HCl in concentrated solutions
    • See also Laasonen, K.; Klein, M.L. J. Am. Chem. Soc. 1994, 116, 11620 for simulations of the state of HCl in concentrated solutions.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 11620
    • Laasonen, K.1    Klein, M.L.2
  • 30
    • 0004023095 scopus 로고
    • Reinhold Publishing Corporation: New York
    • Miner, C.S. Glycerol; Reinhold Publishing Corporation: New York, 1953.
    • (1953) Glycerol
    • Miner, C.S.1
  • 31
    • 0004273538 scopus 로고
    • CRC Press: Cleveland
    • Newman, A.A. Glycerol; CRC Press: Cleveland, 1968.
    • (1968) Glycerol
    • Newman, A.A.1
  • 33
    • 0004283386 scopus 로고
    • Marcel Dekker: New York
    • ± decreases steadily from 1 for pure glycerol to 0.46 for 0.26 M NaOH. See Hiemenz, P.C. Principles of Colloid and Surface Chemistry, 2nd ed.; Marcel Dekker: New York, 1986; p 395 and Aktins, P. Physical Chemistry, 6th ed.; Oxford University Press: New York, 1998; p 249.
    • (1986) Principles of Colloid and Surface Chemistry, 2nd ed. , pp. 395
    • Hiemenz, P.C.1
  • 34
    • 0003516749 scopus 로고    scopus 로고
    • Oxford University Press: New York
    • ± decreases steadily from 1 for pure glycerol to 0.46 for 0.26 M NaOH. See Hiemenz, P.C. Principles of Colloid and Surface Chemistry, 2nd ed.; Marcel Dekker: New York, 1986; p 395 and Aktins, P. Physical Chemistry, 6th ed.; Oxford University Press: New York, 1998; p 249.
    • (1998) Physical Chemistry, 6th ed. , pp. 249
    • Aktins, P.1
  • 35
    • 0011231222 scopus 로고    scopus 로고
    • note
    • des(t) = [c(x = 0, t)/c*] at different values of τ.
  • 36
    • 0011181468 scopus 로고    scopus 로고
    • note
    • th(DCl).
  • 39
    • 0011201584 scopus 로고    scopus 로고
    • note
    • 1/2 is less than 3 Å, which is smaller than one glycerol molecule.
  • 42
    • 0011181797 scopus 로고    scopus 로고
    • note
    • -1 at 294 K, where η = 1300 cP, and is estimated in the preceding paper to be 10 times smaller at 273 K, where η = 12 100 cP.
  • 43
    • 0011171493 scopus 로고    scopus 로고
    • note
    • HCl(273 K) is computed to be 0.12 ± 0.02.
  • 49
    • 0011231223 scopus 로고    scopus 로고
    • note
    • - in the preceding paper.
  • 50
    • 0011178824 scopus 로고    scopus 로고
    • See ref 40 of the preceding paper
    • See ref 40 of the preceding paper.
  • 56
    • 0011218652 scopus 로고    scopus 로고
    • note
    • pulse).
  • 58
    • 0011240696 scopus 로고    scopus 로고
    • note
    • Recent results by Li et al. (ref 22) show that the mass accommodation coefficients in ethylene glycol at 303 K are 0.37 for HCl (intermediate between the water and glycerol values) and 0.96 for HBr (close to the glycerol value).
  • 59
    • 0011179259 scopus 로고    scopus 로고
    • note
    • -1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.