Coordination chemistry of the cyclo-(P5tBu4) - ion: Monomeric and oligomeric copper(I), silver(I) and goId(I) complexes

Chemistry - A European Journal

Volumn 14, Issue 15, 2008, Pages 4511-4520

  Gómez Ruiz, Santiago ^a   Wolf, Robert ^a   Bauer, Sebastian ^a   Bittig, Henry ^a   Schisler, Andrea ^a   Lönnecke, Peter ^a   Hey Hawkins, Evamarie ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

Author keywords

Copper; Gold P ligands; Phosphorus; Silver

Indexed keywords

SODIUM;

COPPER; GOLD P LIGANDS; PHOSPHORUS; SILVER;

COORDINATION REACTIONS;

COPPER; GOLD; ION; ORGANOMETALLIC COMPOUND; ORGANOPHOSPHORUS COMPOUND; SILVER; SINGLE HETEROCYCLIC RINGS;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY, X-RAY; GOLD; HETEROCYCLIC COMPOUNDS, 1-RING; IONS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; ORGANOPHOSPHORUS COMPOUNDS; SILVER; STEREOISOMERISM;

EID: 53849097359     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800007     Document Type: Article

References (88)

1. a) H. Köhler, A. Michaelis. Ber. Dtsch. Chem. Ges 1877, 10, 807-814;
2. b) M. Baudler, C. Gruner, G. Fürstenberg, B. Kloth, F. Saykowski, U. Özer, Z. Anorg. Allg. Chem. 1978, 446, 169-176;
3. c) M. Baudler, B. Makowka, Z. Anorg. Allg. Chem. 1985, 528, 7-21;
4. d) M. Baudler, K. Glinka, Chem. Rev. 1993, 93, 1623-1667;
5. e) K. B. Dillon, F. Mathey, J. F. Nixon in Phosphorus: The Carbon Copy: From Organophosphorus to Phospha-organic Chemistry, John Wiley and Sons Ltd., Chichester 1998:
6. f) D. A. Pantazis, J. E. McGrady, J. M. Lynam, C. A. Russell, M. Green, Dalton Trans. 2004, 2080-2086;
7. g) E. Urnezius, W. W. Brennessel, C. J. Cramer, J. E. Ellis, P. R. Schleyer, Science 2002, 295, 832-834;
8. h) J. J. Weigand, N. Burford, M. D. Lumsden. A. Decken, Angew. Chem., 2006, 118, 6745-6749;
9. Angew. Chem. Int. Ed., 2006, 45, 6733-6737.
10. 5), was already synthesised in 1877 although its oligomeric nature was not recognised at the time: H. Köhler, A. Michaelis, Ber. Dtsch. Chem. Ges. 1877, 10, 807-814.
11. a) M. Baudler. Pure Appl. Chem. 1980, 52. 755-769;
12. b) M. Baudler, Angew. Chem. 1982, 94, 520-539;
13. Angew. Client. Int. Ed. Engl. 1982, 21, 492-512;
14. c) M. Baudler, Z. Chem. 1984, 24, 352-359;
15. d) M. Baudler, Angew. Chem. 1987, 99, 429-451;
16. Angew. Chem. Int. Ed. Engl. 1987, 26, 419-441;
17. e) M. Baudler, K. Glinka, Chem. Rev. 1993, 93,1623-1667 and references therein.
18. a) K. lssleib, K. Krech. Chem. Ber. 1965, 98, 2545-2550;
19. b) K. Issleib, E. Kruck, Z. Anorg. Allg. Chem. 1965, 339, 274-280;
20. c) K. lssleib, K. Krech, Chem. Ber. 1966, 99, 1310-1315;
21. d) K. lssleib, M. Hoffmann, Chem. Ber. 1966, 99, 1320-1324;
22. e) K. lssleib, Ch. Rockstroh, I. Duchek, E. Fluck, Z Anorg. Allg. Chem. 1968, 360, 77-87;
23. f) K. lssleib, K. Krech, J. Prakt. Chem. 1969, 311, 463-471;
24. g) M. Baudler, D. Koch, E. Tolls, K. M. Diederich, B. Kloth, Z. Anorg. Allg. Chem. 1976, 420, 146-154;
25. h) P. R. Hoffmann, K. G. Caulton, J. Am. Chem. Soc. 1975, 97, 6370-6374;
26. i) M. Baudler, D. Koch, Z. Anorg. Allg. Chem. 1976, 425, 227-235.
27. a) A. Schmidpeter, G. Burget, Phosphorus Sulfur Relat. Elem. 1985, 22, 323-336;
28. b) G. Fritz, K. Stoll, Z. Anorg. Allg. Chem. 1986, 538, 78-112;
29. c) G. Fritz. R. Biastoch, K. Stoll, T. Vaahs, D. Hanke, H. W. Schneider, Phosphorus Sulfur Relat. Elem. 1987, 30, 385-388.
30. A. Schisler, P. Lönnecke, U. Huniar. R. Ahlrich, E. Hey-Hawkins, Angew. Chem. 2001, 113, 4345-4348;
31. Angew. Chem. Int. Ed. Angew. Chem. Int. Ed. Engl. 2001, 40, 4217-4219.
32. S. Gómez-Ruiz, A. Schisler, P. Lönnecke, E. Hey-Hawkins, Chem. Eur. J. 2007, 28, 7974-7982.
33. A. Schisler, P. Lönnecke, E. Hey-Hawkins, lnorg. Chem. 2005, 44, 461-464.
34. A. Schisler, P. Lönnecke, Th. Gelbrich, E. Hey-Hawkins, Dalton Trans. 2004, 2895-2898.
35. a) A. Schisler, Dissertation. Universität Leipzig. 2003;
36. b) J. Geier, Dissertation, ETH Zürich, 2004;
37. c) R. Wolf, Dissertation, Universität Leipzig, 2005;
38. d) J. Geier, H. Rüegger, M. Wörle, H. Grützmacher, Angew. Chem. 2003, 115, 4081-4085;
39. Angew. Chem. Int. Ed. 2003, 42, 3951-3954;
40. e) R. Wolf, A. Schisler, P. Lönnecke, C. Jones, E. Hey-Hawkins, Eur. J. Inorg. Chem. 2004, 3277-3286;
41. f) J. Geier, J. Harmer, H. Grützmacher, Angew. Chem. 2004, 116, 4185-4189,
42. Angew. Chem. Int. Ed. 2004, 43, 4093-4097;
43. g) M. Kaupp, A. Patrakov, R. Reviakine, O. L. Malkina, Chem. Eur. J. 2005, 11, 2773-2782;
44. h) R. Wolf, E. Hey-Hawkins, Z. Anorg. Allg. Chem. 2006, 632, 727-734;
45. i) D. Stein, A. Dransfeld, M. Flock, H. Rüegger, H. Grützmacher Eur. J. lnorg. Chem. 2006, 4157-4167;
46. j) S. Gómez-Ruiz, E. Hey-Hawkins, Dalton Trans. 2007, 5678-5683;
47. k) S. Gómez-Ruiz, R. Wolf, E. Hey-Hawkins, Dalton Trans. 2008 DOI:10.1039/b718727k.
48. R. Wolf, E. Hey-Hawkins, Angew. Chem. 2005, 117, 6398-6401;
49. Angew. Chem. Int. Ed. 2005, 44, 6241-6244.
50. See for example: a) B. Hoge, Ch. Thösen, T. Herrmann. A. Vij, lnorg. Chem. 2004. 43, 1659-1666;
51. b) H. W. Lerner, G. Margraf, L. Kaufmann, J. W. Bats, M. Bolle, M. Wagner, Eur. J. Inorg. Chem. 2005, 1932-1939;
52. c) T. Greiser, E. Weiss, Chem. Ber. 1978, 111, 516-522;
53. d) G. van Koten, J. G. Noltes, A. L. Spek, J. Organomet. Chem. 1978, 159, 441-463;
54. e) A. H. Cowley, D. M. Giolando, R. A. Jones, C. M. Nunn, J. M. Power, J. Chem. Soc. Chem. Commun. 1988, 208-209;
55. f) T. A. Annan, R. Kumar, D. G. Tuck, J. Chem. Soc. Chem. Commun. 1988, 446-447;
56. g) D. J. Brauer, G. Hessler, P. C. Knüppel, O. Stelzer, Inorg. Chem. 1990, 29, 2370-2375;
57. h) D. J. Brauer, P. C. Knüppel, O. Stelzer, Phosphorus Sulfur Silicon Relat. Elem. 1990, 49, 449-452;
58. i) T. A. Annan, R. Kumar, D. G. Tuck, J. Chem. Soc. Dalton Trans. 1991, 11-18;
59. j) A. Eichhöfer, D. Fenske, W. Holstein, Angew. Chem. 1993, 105, 257-261;
60. Angew. Chem. Int. Ed. Engl. 1993, 32. 242-245;
61. k) M. Faulhaber, M. Driess, K. Merz, Chem. Commun. 1998, 1887-1888;
62. I) C. Meyer, H. Grützmacher, Angew. Chem. 1997, 109, 2576-2578;
63. Angew. Chem. Int. Ed. Engl. 1997, 36, 2471-2473.
64. D.M. Stefanescu, H. F. Yuen, D.S. Glueck, J. A. Golen, A. L. Rheingold, Angew. Chem. 2003, 115, 1076-1078;
65. Angew. Chem. Int. Ed. 2003, 42, 1046-1048.
66. a) W. Hölderich, G. Fritz, Z. Anorg, Allg. Chem. 1979, 457, 127-142;
67. b) M. Baudler, Angew. Chem. 1987, 99, 429-451;
68. Angew. Chem. Int. Ed. Eng. 1987, 26. 419-441.
69. The low solubility of 5, 6, 8 and 9 may act as a driving force for their formation by shifting the equilibrium towards these oligomeric complexes.
70. 1H} NMR spectra of the reaction mixtures showed always four broad signals at δ= 67, 28, 12 and -94 ppm (ratio 2:2:2:1) suggesting the formation of the mononuclear silver(I) complex.
71. a) T. S. Teets, D. V. Partyka, A.J. Esswein, J. B. Updegraff, M. Zeller, A. D. Hunter, T. G. Gray, lnorg. Chem. 2007, 46, 6218-6220;
72. b) M. C. Gimeno, A. Laguna, Chem. Rev. 1997, 97, 511-522;
73. c) R. M. Dávila, R. J. Staples, A. Elduque, M. M. Harlass, L. Kyle, J. P. Fackler, lnorg. Chem. 1994, 33, 5940-5945;
74. d) Z. Li, Z. -H. Loh, K. F. Mok, T. S. A. Hor, lnorg. Chem. 2000, 39, 5299-5305.
75. K. Marat, SPINWORKS, version 2000 05 10, University of Manitoba
76. a) M. Schmidt, Dissertation, 1996, Kaiserslautern:
77. b) O. J. Scherer, T. Brück, G. Wolmershäuser, Chem. Ber. 1989, 122, 2049-2054.
78. R. Blom, A. Haaland, J. Mol. Struct. 1985, 128, 21-27.
79. E. J. Fernández, M. C. Gimeno, P. G. Jones, A. Laguna, M. Laguna, J. M. López de Luzuriaga. Angew. Chem., 1994, 106, 96-98;
80. Angew. Chem. Int. Ed. Eng. 1994, 33. 87-88.
81. H. Schmidbaur, T. Pollok, G. Reber, G. Müller, Chem. Ber. 1988, 121, 1345-1348.
82. Th. Kräuter, B. Neumüller, Polyhedron. 1996, 15, 2851-2857.
83. G. A. Bowmaker, P. J. Harvey, P. C. Healy, B. W. Skelton, A. H. White, J. Chem. Soc. Dalton Trans. 1996, 2449-2457.
84. P. G. Jones, G. M. Sheldrick, J. A. Muir, M. M. Muir, L. B. Pulgar, J. Chem. Soc. Dalton Trans. 1982, 2123-2125.
85. G. M. Sheldrick, SADABS, Program for Empirical Absorption Correction. Göttingen, 1998.
86. SCALE3 ABSPACK: Empirical absorption correction. CrysAlis-Software package, Oxford Diffraction Ltd. 2006.
87. G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, Göttingen, 1997.
88. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen, 1997.