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4544354251
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lecture presented by R. Wolf at ALKCHEM-3, Würzburg, Germany, 30.09
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R. Wolf, E. Hey-Hawkins, "Alkali Metal Salts of Catenated Oligophosphanes-Corresponding Structures in the Solid State and in Solution?", lecture presented by R. Wolf at ALKCHEM-3, Würzburg, Germany, 30.09.2003.
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Wolf, R.1
Hey-Hawkins, E.2
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19
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4544247904
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note
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3, Z = 2.
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20
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0009891668
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4,7,13,16,21,24-Hexaoxa-1,10-dizabicyclo[8.8.8]hexacosane: B. Dietrich, J.-M. Lehn, J.-P. Sauvage, J. Blanzat, Tetrahedron 1973, 29, 1629.
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Dietrich, B.1
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37049108599
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Cetinkaya, B.1
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37049075852
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c) M. Culcasi, G. Gronchi, J. Escudié, C. Cuoret, L. Pujol, P. Tordo, J. Am. Chem. Soc. 1986, 108, 3130;
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4544222900
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4544312254
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2[13b]) with potassium in THF according to: K. Issleib, K. Krech, Chem. Ber. 1965, 98, 2545;
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Issleib, K.1
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27
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0000989409
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b) W. A. Henderson, Jr., M. Epstein, F. S. Seichter, J. Am. Chem. Soc. 1963, 85, 2462.
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Henderson Jr., W.A.1
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28
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4544271458
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note
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-1 over the gauche isomer: J. Geier, unpublished results; see also ref. [12d].
-
-
-
-
30
-
-
4544262266
-
-
note
-
2- dianions with n > 4 have never been observed.
-
-
-
-
31
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0035913768
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-
a) S. L. Hinchley, C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. Voigt, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne, P. P. Power, J. Am. Chem. Soc. 2001, 123, 9045;
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Hinchley, S.L.1
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Cowley, A.H.7
Lappert, M.F.8
Gundersen, G.9
Clyburne, J.A.C.10
Power, P.P.11
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32
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0034699893
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b) S. L. Hinchley, C. A. Morrison, D. W. H. Rankin, C. L. B. Macdonald, R. J. Wiacek, A. H. Cowley, M. F. Lappert, G. Gundersen, J. A. C. Clyburne, P. P. Power, Chem. Commun. 2000, 2045.
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Chem. Commun.
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Hinchley, S.L.1
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Cowley, A.H.6
Lappert, M.F.7
Gundersen, G.8
Clyburne, J.A.C.9
Power, P.P.10
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33
-
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33845556264
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n (n = 3-6) in the 1960s. The first genuine diphosphene was prepared in 1981 and needed bulky substituents for kinetic stabilization: a) M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, T. Higushi, J. Am. Chem. Soc. 1981, 103, 4587;
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Yoshifuji, M.1
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Higushi, T.5
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34
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0001734139
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this reference also cites older work; PhP=PPh itself could only be stabilized by transition-metal complexation, see for example: b) J. Borm, L. Zolnai, G. Huttner, Angew. Chem. 1983, 95, 1018; Angew. Chem. Int. Ed. Engl. 1983, 22, 977.
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Borm, J.1
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Huttner, G.3
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35
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84984379287
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this reference also cites older work; PhP=PPh itself could only be stabilized by transition-metal complexation, see for example: b) J. Borm, L. Zolnai, G. Huttner, Angew. Chem. 1983, 95, 1018; Angew. Chem. Int. Ed. Engl. 1983, 22, 977.
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-
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36
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33847800348
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Chainlike tetraphosphanediides M-PPh-PPh-PPh-PPh-M (M = Li, K) in solution were proposed by: a) P. R. Hoffman, K. G. Caulton, J. Am. Chem. Soc. 1975, 97, 6370;
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Hoffman, P.R.1
Caulton, K.G.2
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37
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84957151209
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however, these results were differently interpreted by: b) M. Baudler, D. Koch, E. Tolls, K. M. Diedrich, B. Kloth, Z. Anorg. Allg. Chem. 1976, 420, 146;
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Baudler, M.1
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Kloth, B.5
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