The reactivity of cyclo-(P5tBu4) - towards group 13, 14 and 15 metal chlorides: Complexation and formation of cyclooligophosphanes, {cyclo-(P5tBu 4)}2 and {cyclo-(P4tBu 3)PtBu}2, by reductive elimination

Dalton Transactions

Volumn , Issue 18, 2004, Pages 2895-2898

  Schisler, Andrea ^a   Lönnecke, Peter ^a   Gelbrich, Thomas ^b   Hey Hawkins, Evamarie ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

^b UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; DIFFRACTOMETERS; FILTRATION; INERT GASES; INFRARED SPECTROSCOPY; ISOMERS; NUCLEAR MAGNETIC RESONANCE; REDUCTION; SOLVENTS; X RAY DIFFRACTION ANALYSIS;

CYCLOOLIGOPHOSPHANES; METAL CHLORIDES; REDUCTIVE ELIMINATION; STRUCTURE DETERMINATION;

PHOSPHORUS COMPOUNDS;

EID: 7044264965     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b407736a     Document Type: Article

References (52)

1. M. Baudler and K. Glinka, Chem. Rev., 1993, 93, 1623.
2. H. Köhler and A. Michaelis, Ber. Dtsch. Chem. Ges., 1877, 10, 807.
3. (a) M. Baudler, C. Wiaterek and K. Kazmierczak, Z. Anorg. Allg. Chem., 1989, 579, 7;
4. (b) M. Baudler, L. De Riese-Meyer and C. Wiaterek, Z. Naturforsch., Teil B, 1989, 44, 375;
5. (c) M. Baudler and L. De Riese-Meyer, Z. Naturforsch., Teil B, 1986, 41, 399;
6. (d) M. Baudler and B. Makowka, Angew. Chem., 1984, 96, 976; M. Baudler and B. Makowka, Angew. Chem., Int. Ed. Engl., 1984, 23, 987;
7. (d) M. Baudler and B. Makowka, Angew. Chem., 1984, 96, 976; M. Baudler and B. Makowka, Angew. Chem., Int. Ed. Engl., 1984, 23, 987;
8. (e) M. Baudler and V. Arndt, Z. Naturforsch., Teil B, 1984, 39, 275;
9. (f) M. Baudler and H. Tschaebunin, Z. Anorg. Allg. Chem., 1992, 617, 31;
10. (g) M. Baudler and M. Schnalke, Z. Anorg. Allg. Chem., 1990, 585, 18;
11. (h) M. Baudler, M. Schnalke, C. Wiaterek, S. Opiela and J. Hahn, Z. Anorg. Allg. Chem., 1989, 578, 7;
12. (i) M. Baudler, J. Hellmann, P. Bachmann, K. F. Tebbe, R. Fröhlich and M. Feher, Angew. Chem., 1981, 93, 415; M. Baudler, J. Hellmann, P. Bachmann, K. F. Tebbe, R. Fröhlich and M. Feher, Angew. Chem., Int. Ed. Engl., 1981, 20, 406;
13. (i) M. Baudler, J. Hellmann, P. Bachmann, K. F. Tebbe, R. Fröhlich and M. Feher, Angew. Chem., 1981, 93, 415; M. Baudler, J. Hellmann, P. Bachmann, K. F. Tebbe, R. Fröhlich and M. Feher, Angew. Chem., Int. Ed. Engl., 1981, 20, 406;
14. (j) M. Baudler and H. Jachow, Z. Naturforsch., Teil B, 1994, 49, 1755;
15. (k) M. Baudler, M. Michels, J. Hahn and M. Pieroth, Angew. Chem., 1985, 97, 514; M. Baudler, M. Michels, J. Hahn and M. Pieroth, Angew. Chem., Int. Ed. Engl., 1985, 24, 504.
16. (k) M. Baudler, M. Michels, J. Hahn and M. Pieroth, Angew. Chem., 1985, 97, 514; M. Baudler, M. Michels, J. Hahn and M. Pieroth, Angew. Chem., Int. Ed. Engl., 1985, 24, 504.
17. M. Baudler, M. Schnalke and Ch. Wiaterek, Z. Anorg. Allg. Chem., 1990, 585, 7.
18. N. Wiberg, A. Wörner, H.-W. Lerner, K. Karaghiosoff, D. Fenske, G. Baum, A. Dransfeld and P. von Rague Schleyer, Eur. J. Inorg. Chem., 1998, 6, 833.
19. M. Feher, R. Fröhlich and K. F. Tebbe, Z. Kristallogr., 1982, 158, 241.
20. (a) M. Häser and O. Treutler, J. Chem. Phys., 1995, 102, 3703;
21. (b) M. Marco, U. Schneider and R. Ahlrichs, J. Amer. Chem. Soc., 1992, 114, 9551.
22. M. Baudler, Ch. Gruner, G. Fürstenberg, B. Kloth, F. Saykowski and U. Özer, Z. Anorg. Allg. Chem., 1978, 446, 169.
23. M. Baudler and B. Makowka, Z. Anorg. Allg. Chem., 1985, 528, 7.
24. A. Schmidpeter and G. Burget, Phosphorus Sulfur, 1985, 22, 323.
25. G. Fritz and K. Stoll, Z. Anorg. Allg. Chem., 1986, 538, 78.
26. G. Fritz, R. Biastoch, K. Stoll, T. Vaahs, D. Hanke and H. W. Schneider, Phosphorus Sulfur, 1987, 30, 385.
27. A. Schisler, U. Huniar, P. Lönnecke, R. Ahlrichs and E. Hey-Hawkins, Angew. Chem., 2001, 113, 4345; A. Schisler, U. Huniar, P. Lönnecke, R. Ahlrichs and E. Hey-Hawkins, Angew. Chem., Int. Ed., 2001, 40, 4217.
28. A. Schisler, U. Huniar, P. Lönnecke, R. Ahlrichs and E. Hey-Hawkins, Angew. Chem., 2001, 113, 4345; A. Schisler, U. Huniar, P. Lönnecke, R. Ahlrichs and E. Hey-Hawkins, Angew. Chem., Int. Ed., 2001, 40, 4217.
29. (a) M. Baudler and H. Suchomel, Z. Anorg. Allg. Chem., 1983, 503, 7;
30. (b) H. Binder, B. Schuster, W. Schwarz and K. W. Klinkhammer, Z. Anorg. Allg. Chem., 1999, 625, 699;
31. (c) M. Baudler, L. Riese-Meyer and U. Schings, Z. Anorg. Allg. Chem., 1984, 519, 24.
32. (a) M. Baudler and H. Suchomel, Z. Anorg. Allg. Chem., 1983, 505, 39;
33. (b) D. Bongert, G. Heckmann, W. Schwarz, H.-D. Hausen and H. Binder, Z. Anorg. Allg. Chem., 1995, 621, 1358;
34. (c) D. Bongert, H.-D. Hausen, W. Schwarz, G. Heckmann and H. Binder, Z. Anorg. Allg. Chem., 1996, 622, 1167.
35. A. Schisler, Dissertation, Leipzig, 2003; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Dalton Trans.; to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Inorg. Chem., to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Chem. Eur. J., to be submitted.
36. A. Schisler, Dissertation, Leipzig, 2003; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Dalton Trans.; to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Inorg. Chem., to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Chem. Eur. J., to be submitted.
37. A. Schisler, Dissertation, Leipzig, 2003; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Dalton Trans.; to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Inorg. Chem., to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Chem. Eur. J., to be submitted.
38. A. Schisler, Dissertation, Leipzig, 2003; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Dalton Trans.; to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Inorg. Chem., to be submitted; A. Schisler, P. Lönnecke and E. Hey-Hawkins, Chem. Eur. J., to be submitted.
39. PP and the remaining signs and coupling constants were calculated with the program SPINWORKS (K. Marat, SPINWORKS, version 2000 05 10, University of Manitoba).
40. A. Schisler, Diplomarbeit, Leipzig, 1999.
41. K. Issleib and M. Hoffmann, Chem. Ber., 1966, 99, 1320.
42. M. Baudler, J. Hahn, H. Dietsch and G. Fürstenberg, Z. Naturforsch., Teil B, 1976, 31, 1305.
43. M. Baudler and H. Tschäbunin, Z. Anorg. Allg. Chem., 1984, 511, 77.
44. M. Baudler and Ch. Gruner, Chem. Ber., 1982, 115, 1739.
45. M. Baudler, J. Hellman and T. Schmidt, Z. Naturforsch., Teil B, 1983, 38, 537.
46. M. Karnop, W.-W. du Mont, P. G. Jones and J. Jeske, Chem. Ber., 1997, 130, 1611.
47. Data collection and cell refinement: D. Z. Otwinowski and W. Minor, Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, ed. C. W. Carter, Jr. and R. M. Sweet, Academic Press, 1997, p. 307. Absorption correction: SORTAV: R. H. Blessing, Acta Crystallogr., Sect. A, 1995, 51, 33; R. H. Blessing, J. Appl. Crystallogr., 1997, 30, 421.
48. Data collection and cell refinement: D. Z. Otwinowski and W. Minor, Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, ed. C. W. Carter, Jr. and R. M. Sweet, Academic Press, 1997, p. 307. Absorption correction: SORTAV: R. H. Blessing, Acta Crystallogr., Sect. A, 1995, 51, 33; R. H. Blessing, J. Appl. Crystallogr., 1997, 30, 421.
49. Structure solution and refinement: SHELXS and SHELXL97: G. M. Sheldrick 1997, University of Göttingen, Germany.
50. K. A. Jensen, Z. Anorg. Allg. Chem., 1936, 229, 265.
51. M. Baudler, G. Reuschenbach, J. Hellmann and J. Hahn, Z. Anorg. Allg. Chem., 1983, 499, 89.
52. D. E. C. Corbridge, The Structural Chemistry of Phosphorus, Elsevier, Amsterdam, 1974.