Synthesis and molecular structure of the Cu4P8 cage compound [Cu4(P4Ph4)2(PCyp 3)3]

Angewandte Chemie - International Edition

Volumn 44, Issue 38, 2005, Pages 6241-6244

  Wolf, Robert ^a   Hey Hawkins, Evamarie ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

Author keywords

Cage compounds; Copper; P ligands; Phosphorus

Indexed keywords

MOLECULAR STRUCTURE; PHOSPHORUS; SYNTHESIS (CHEMICAL);

CAGE COMPOUNDS; P LIGANDS;

COPPER COMPOUNDS;

EID: 25844503687     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501607     Document Type: Article

References (65)

1. a) K. Issleib, K. Krech, Chem. Ber. 1965, 98, 2545;
2. b) K. Issleib, E. Fluck, Z. Anorg. Allg. Chem. 1965, 339, 274;
3. c) K. Issleib, K. Krech, Chem. Ber. 1966, 99, 1310;
4. d) K. Issleib, M. Hoffmann, Chem. Ber. 1966, 99, 1320;
5. e) K. Issleib, C. Rockstroh, I. Duchek, E. Fluck, Z. Anorg. Allg. Chem. 1968, 360, 77;
6. f) K. Issleib, K. Krech, J. Prakt. Chem. 1969, 311, 463.
7. M. Baudler, C. Gruner, G. Fürstenberg, B. Kloth, F. Saykowski, U. Özer, Z. Anorg. Allg. Chem. 1978, 446, 169.
8. a) M. Baudler, D. Koch, E. Tolls, K. M. Diederich, B. Kloth, Z. Anorg. Allg. Chem. 1976, 420, 146;
9. b) P. R. Hoffmann, K. G. Caulton, J. Am. Chem. Soc. 1975, 97, 6370.
10. M. Baudler, D. Koch, Z. Anorg. Allg. Chem. 1976, 425, 227.
11. A. Schmidpeter, G. Burget, Phosphorus Sulfur 1985, 22, 323.
12. G. Fritz, K. Stoll, Z. Anorg. Allg. Chem. 1986, 538, 782.
13. G. Fritz, R. Biastoch, K. Stoll, T. Vaahs, D. Hanke, H. W. Schneider, Phosphorus Sulfur 1987, 30, 385.
14. a) B. Riegel, A. Pfitzner, G. Heckmann, E. Fluck, H. Binder, Phosphorus Sulfur Silicon Relat Elem. 1994, 93, 173;
15. b) B. Riegel, A. Pfitzner, G. Heckmann, H. Binder, E. Fluck, Z. Anorg. Allg. Chem. 1994, 620, 8;
16. c) B. Riegel, A. Pfitzner, G. Heckmann, H. Binder, E. Fluck, Z. Anorg. Allg. Chem. 1995, 621, 1989;
17. d) D. Bongert, G. Heckmann, W. Schwarz, H. D. Hausen, H. Binder, Z. Anorg. Allg. Chem. 1995, 621, 1358;
18. e) D. Bongert, G. Heckmann, W. Schwarz, H. D. Hausen, H. Binder, Z. Anorg. Allg. Chem. 1996, 622, 1167;
19. f) D. Bongert, G. Heckmann, H. D. Hausen, W. Schwarz, H. Binder, Z. Anorg. Allg. Chem. 1996, 622, 1793;
20. g) H. Binder, B. Schuster, W. Schwarz, K. W. Klinkhammer, Z. Anorg. Allg. Chem. 1999, 625, 699.
21. H. Köpf, R. Voigtländer, Chem. Ber. 1981, 114, 2731.
22. R. A. Jones, M. H. Seeberger, B. R. Whittlesey, J. Am. Chem. Soc. 1985, 107, 6424.
23. a) M. Baudler, S. Klautke, Z. Naturforsch. 1981, 36, 527;
24. b) M. Baudler, S. Klautke, Z. Naturforsch. 1983, 38, 121.
25. M. Baudler, L. De Riese-Meyer, U. Schings, Z. Anorg. Allg. Chem. 1984, 519, 24.
26. a) A. H. Cowley, R. A. Jones, M. A. Maroones, J. L. Atwood, S. G. Bott, Angew. Chem. 1991, 103, 1163;
27. Angew. Chem. Int. Ed. Engl. 1991, 30, 1141;
28. b) G. Linti, R. Frey, W. Köstler, H. Schwenk, Chem. Ber./Recueil 1997, 130, 663;
29. c) W. Köstler, G. Linti, Eur. J. Inorg. Chem. 2001, 1841.
30. A. Schisler, Dissertation, Universität Leipzig, 2003.
31. a) A. Schisler, U. Huniar, P. Lönnecke, R. Ahlrichs, E. Hey-Hawkins, Angew. Chem. 2001, 113, 4345;
32. Angew. Chem. Int. Ed. 2001, 40, 4217;
33. b) A. Schisler, P. Lönnecke, T. Gelbrich, E. Hey-Hawkins, Dalton Trans. 2004, 2895;
34. c) A. Schisler, P. Lönnecke, E. Hey-Hawkins, Inorg. Chem. 2005, 44, 461;
35. d) A. Schisler, P. Lönnecke, E. Hey-Hawkins, unpublished results.
36. R. Wolf, A. Schisler, P. Lönnecke, C. Jones, E. Hey-Hawkins, Eur. J. Inorg. Chem. 2004, 3277.
37. R. Wolf, Dissertation, Universität Leipzig, 2005.
38. J. Geier, H. Rüegger, M. Wörle, H. Grützmacher, Angew. Chem. 2003, 115, 4081;
39. Angew. Chem. Int. Ed. 2003, 42, 3951.
40. a) J. Geier, J. Harmer, H. Grützmacher, Angew. Chem. 2004, 116, 4185;
41. Angew. Chem. Int. Ed. 2004, 43, 4093;
42. b) J. Geier, Dissertation, ETH Zürich, 2004.
43. M. Kaupp, A. Patrakov, R. Reviakine, O. L. Malkina, Chem. Eur. J. 2005, 11, 2773.
44. R. Wolf, E. Hey-Hawkins, Chem. Commun. 2004, 2626.
45. -3. A numerical absorption correction was carried out with X-red (STOE & Cie GmbH, Darmstadt), and the structure solution with direct methods (G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, 1997).
46. Cu, P, and C atoms were refined anisotropically (G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, 1997).
47. The structure contains 3.5 molecules of toluene in the asymmetric unit, some of which are heavily disordered. One toluene molecule that could not be refined satisfactorily was eliminated by using the program SQUEEZE implemented in PLATON (P. V. D. Sluis, A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, 194). The positions of the H atoms were partially located on the Fourier difference map and partially calculated on idealized positions. CCDC 270972 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
48. For example, a) T. Greiser, E. Weiss, Chem. Ber. 1978, 111, 516;
49. b) G. van Koten, J. G. Noltes, A. L. Spek, J. Organomet. Chem. 1978, 159, 441;
50. c) A. H. Cowley, D. M. Giolando, R. A. Jones, C. M. Nunn, J. M. Power, J. Chem. Soc. Chem. Commun. 1988, 208;
51. d) T. A. Annan, R. Kumar, D. G. Tuck, J. Chem. Soc. Chem. Commun. 1988, 446;
52. e) D. J. Brauer, G. Hessler, P. C. Knüppel, O. Stelzer, Inorg. Chem. 1990, 29, 2370;
53. f) D. J. Brauer, P. C. Knüppel, O. Stelzer, Phosphorus Sulfur Silicon Relat. Elem. 1990, 49, 449;
54. g) T. A. Annan, R. Kumar, D. G. Tuck, J. Chem. Soc. Dalton Trans. 1991, 11;
55. h) A. Eichhöfer, D. Fenske, W. Holstein, Angew. Chem. 1993, 105, 257;
56. Angew. Chem. Int. Ed. Engl. 1993, 32, 242;
57. i) M. Faulhaber, M. Driess, K. Merz, Chem. Commun. 1998, 1887.
58. C. Meyer, H. Grützmacher, Angew. Chem. 1997, 109, 2576;
59. Angew. Chem. Int. Ed. Engl. 1997, 36, 2471.
60. a) O. Olofsson, Acta Chem. Scand. 1965, 18, 217;
61. b) H. Schlenger, H. Jacobs, R. Juza, Z. Anorg. Allg. Chem. 1971, 385, 177;
62. c) E. Amberger, P. A. Rauh, Acta Crystallogr. B 1974, 30, 2549;
63. d) M. H. Möller, W. Jeitschko, Z. Anorg. Allg. Chem. 1982, 491, 225.
64. 3 the Cu-P distances lie in the range 2.145-2.311 Å (av 2.236 Å).
65. R. Blom, A. Haaland, J. Mol. Struct. 1985, 128, 21.