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Details of the refinements: 1, 4: refinement of O, A(E, Sn and S atomic positions (A(E, K: 1, Rb: 2, Cs: 3, Ba: 4) employing anisotropic displacement parameters; H atoms not calculated. 5: refinement of Cs, Mn, S, Sn and 9 of 18 O atomic positions employing anisotropic displacement parameters; refinement of 9 of 10 O atomic positions employing isotropic displacement parameters; two O atomic positions twofold or threefold disordered; assignment of respective split positions; H atoms not calculated. The largest differential peak (4.275 e-·10 -6pm-3) is observed 195 pm apart from Cs6. Further details of the crystal structure investigation for compounds 1-5 can be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany, fax:, 49) 7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository numbers CSD 419010, 419011, 419012, 419013, and 419009
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