Syntheses and structures of solvated tetrasodiumtetrachalcogenostannates [Na4(en)4][SnE4] (en = 1,2-diaminoethane; e = Te, Se)

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 633, Issue 5-6, 2007, Pages 820-829

  Ruzin, Eugen ^a   Zimmermann, Christian ^a   Hillebrecht, Pierre ^a   Dehnen, Stefanie ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

Chalcogenostannate anions; Cluster anions (ternary); Crystal structures; En solvates; UV visible spectroscopy

Indexed keywords

EID: 34248217430     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700071     Document Type: Article

References (32)

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17. 12 to accord to the right model. 3: refinement of all atomic positions employing anisotropic displacement parameters; H atoms were calculated as riding groups. 4: refinement of Sn, Se, Mn, and most of the non-disordered Na and O atomic positions employing anisotropic displacement parameters; refinement of two non-disordered Na and 14 O atomic positions employing isotropic displacement parameters; two Na are disordered over two positions; refinement of respective split positions employing isotropic displacement parameters; H atoms not calculated. The reliability of this rare space groups has been further confirmed by means of the program PLATON [21]. Further details of the crystal structure investigation for compound 4 can be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany, (fax: (+49) 7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD 417801. CCDC 638021 -638023 contain the supplementary crystallographic data for compounds 1-3 in this paper. These data can be obtained free of charge via ww.ccdc.cam.ac.uk/datarequest/cif, or by emailing datarequest@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
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