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Volumn 632, Issue 5, 2006, Pages 749-755

Influence of the counterions on the structures of ternary Zn/Sn/Se anions: Synthesis and properties of [Rb10(H2O)14.5] [Zn4(μ4-Se)2(SnSe4)4] and [Ba5(H2O)32] [Zn5Sn(μ3-Se)4(SnSe4) 4]

Author keywords

Barium; Crystal structure; Rubidium; Selenostannates; Ternary anions; Zinc

Indexed keywords


EID: 33646170986     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200500454     Document Type: Article
Times cited : (36)

References (23)
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    • H. Robson (ed.), Elsevier, Amsterdam
    • nd Rev. Ed., H. Robson (ed.), Elsevier, Amsterdam, 2001, p. 27;
    • (2001) nd Rev. Ed. , pp. 27
    • Wilson, S.T.1
  • 8
    • 33646173762 scopus 로고    scopus 로고
    • note
    • 4] unit to form four linked barrelane cages. Besides binary molecules, numerous ternary or even multinary clusters were reported that exhibit different atom types at the A or B positions; in general A is the more electronegative element whereas B represents metal and/or semi-metal atoms. For a detailed explanation see refs. [4b, 4c].
  • 12
    • 0004150157 scopus 로고    scopus 로고
    • Bruker AXS Inc., 6300 Enterprise Lane, Madison, WI 53719-1173, USA
    • -3 is observed close to Ba(6). Different coordination spheres, slight distortions and somewhat tilted relative positions, which can be gathered from figure 3, explain the occurrence of ever two crystallographically independent, ternary anions in 3 and 4. Further details of the crystal structure investigation for compounds 1-4 can be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany, (fax; (+49) 7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository numbers CSD 416008 (4), 416009 (2), 416010 (3), 416011 (1).
    • (1997) Shelxtl 5.1
    • Sheldrick, G.W.1
  • 15
    • 33646174775 scopus 로고    scopus 로고
    • c.f. ref[1]
    • c.f. ref[1], p. 1838-1841.
  • 17
    • 0003967634 scopus 로고
    • Ellis Horwood, Chichester, England
    • J. Burgess, Metal Ions in Solution, Ellis Horwood, Chichester, England 1978, pp, 182-183.
    • (1978) Metal Ions in Solution , pp. 182-183
    • Burgess, J.1
  • 19
    • 0037112579 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 4269-4272;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 4269-4272


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.