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NMR spectra of 2 and 4-8 in [D3]acetonitrile at 298 K indicate that these compounds are stable in this solvent. However, for 5, the presence of residual water in the solvent induces the cleavage of the ?́-(Pt-O) bond. Thus, for the electrochemical studies the use of HPLC-grade acetonitrile is strongly recommended
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NMR spectra of 2 and 4-8 in [D3]acetonitrile at 298 K indicate that these compounds are stable in this solvent. However, for 5, the presence of residual water in the solvent induces the cleavage of the ?́-(Pt-O) bond. Thus, for the electrochemical studies the use of HPLC-grade acetonitrile is strongly recommended.
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86
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85163236208
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For the cycle 6 → 8 → 6,The isosbestic points appear at λ = 405 and 374 nm.
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For the cycle 6 → 8 → 6,The isosbestic points appear at λ = 405 and 374 nm.
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33645674829
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85163238833
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The success of the preparations of compounds 2, 4-6 and 8 is strongly dependent on the quality of the methanol used. The presence of small amounts of water induces the formation of larger amounts of FcCHO and reduces the yields. Thus, the use of HPLC-grade MeOH is strongly recommended
-
The success of the preparations of compounds 2, 4-6 and 8 is strongly dependent on the quality of the methanol used. The presence of small amounts of water induces the formation of larger amounts of FcCHO and reduces the yields. Thus, the use of HPLC-grade MeOH is strongly recommended.
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91
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0004055425
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85163241030
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The labelling of the atoms refers to those shown in Scheme 1.
-
The labelling of the atoms refers to those shown in Scheme 1.
-
-
-
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93
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85163238635
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The labelling of the atoms refers to those shown in Scheme 2.
-
The labelling of the atoms refers to those shown in Scheme 2.
-
-
-
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96
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0003025996
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Kynoch Press, Birmingham, UK, 149
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