Activation of σ(C-H) Bonds in C6H5CH=NCH2CH2SEt Induced by Platinum(II). X-ray Crystal Structure of [Pt{C6H4CH=NCH2CH2SEt}Cl]

Organometallics

Volumn 19, Issue 7, 2000, Pages 1384-1390

  Riera, Xavier ^a   Caubet, Amparo ^a   López, Concepción ^a   Moreno, Virtudes ^a   Solans, Xavier ^a   Font Bardía, Mercè ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003371769     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990602v     Document Type: Article

References (61)

1. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
2. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
3. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
4. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
5. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
6. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
7. For recent applications of cyclometalated complexes see for instance: Omae, I. Applications of Organometallic Compounds; John Wiley: Chichester, U.K., 1998; Chapter 20. Klaus, A. J. Modern Colorants: Synthesis and Structure; London, U.K., 1995; Vol. 3, pp 1. Wild, S. B. Coord. Chem. Rev. 1997, 166, 291, and references therein. Pfeffer, M. Red. Trav. Chim. Pays-Bas 1990, 109, 567, and references therein. Ryabov, A. D. Synthesis 1985, 233, and references therein. Sokolov, V. I. Chirality and Optical Activity in Organometallic Chemistry; Gordon and Beach: London, United Kingdom, 1991. Buey, J.; Espinet, P.; Kitzerow, H. S.; Shours, J. Chem. Commun. 1999, 441, and references therein.
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52. The least-squares equation of the plane defined by the atoms Pt(1), S(1), N(1), and C(8) is (0.0991)XO + (0.9425)YO + (-0.3192)ZO. The deviations from the main plane are Pt(1), -0.057; S(1), 0.037; N(1), 0.086; and C(8), -0.066 Å.
53. The least-squares equation of the plane defined by the atoms Pt(2), S(2), N(2), and C(19) is (-0.1352)XO + (0.9763)YO + (0.1688)ZO = 6.0908. The deviations from the main plane are Pt(2), 0.0005; S(2), -0.0003; N(2), -0.0008; and C(19), 0.0006 Å.
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