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In the absence of the methyl groups at the pyridine rings, undesired side reactions due to deprotonation of the acidic hydrogen atoms adjacent to the pyridine nitrogens are observed
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In the absence of the methyl groups at the pyridine rings, undesired side reactions due to deprotonation of the acidic hydrogen atoms adjacent to the pyridine nitrogens are observed.
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33
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0000733886
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85163238343
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The attempted enantioselective synthesis of the tertiary alcohol 1a by reaction of the titanium acetylide in the presence of (S)-BINOL (P. G. Cozzi, S. Alesi, Chem. Commun. 2004, 2248-2449) afforded only traces of the desired product.
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The attempted enantioselective synthesis of the tertiary alcohol 1a by reaction of the titanium acetylide in the presence of (S)-BINOL (P. G. Cozzi, S. Alesi, Chem. Commun. 2004, 2248-2449) afforded only traces of the desired product.
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Günther, H.1
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42
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85163236586
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Crystal structure analysis of a colorless crystal of [3b· AgBF4·CH2Cl2]2 (0.30×0.15×0.13 mm3) was performed on a Nonius-KappaCCD-Diffractometer at173(1) K. Crystal data for [3b· AgBF4·CH2Cl2]2: C 48H64Ag2B2Cl4F 8N4, M, 1228.19 gmol-1, orthorhombic, space group Fddd, a, 13.5824(8, b, 24.3346(8, c, 32.7072(16) Å, V, 10810.5(9) Å3, Z, 8, μ(Mo-Kα, 0.986 mm-1, 23363 independent reflections (θmin, 2.99, θmax, 27.48, 1961 with I≥2σ(I, R1, 0.0283, wR2 (all data, 0.0574; residual electron density max./min, 0.497/-0.274 e Å3. After merging symmetry-equivalent
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4) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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43
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85163238235
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Initial experiments on the aziridination of styrene with [N-(p-toluolsulfonyl) imino]phenyliodinane show the high catalytic activity of a copper complex formed from allenic bipyridine 3b.
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Initial experiments on the aziridination of styrene with [N-(p-toluolsulfonyl) imino]phenyliodinane show the high catalytic activity of a copper complex formed from allenic bipyridine 3b.
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