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Volumn , Issue 4, 2008, Pages 552-556

Synthesis and complexation properties of allenic bipyridines, a new class of axially chiral ligands for transition metal catalysis

Author keywords

Allenes; Axial chirality; Bipyridines; Catalysis; Transition metal complexes

Indexed keywords

CHELATION; HYDROCARBONS; LIGANDS; MASS SPECTROMETRY; METAL COMPLEXES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; SILVER COMPOUNDS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 53249109732     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701049     Document Type: Article
Times cited : (19)

References (44)
  • 1
    • 0003445429 scopus 로고    scopus 로고
    • Eds, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer, Berlin
    • a) Comprehensive Asymmetric Catalysis (Eds.: E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Berlin, 1999;
    • (1999) Comprehensive Asymmetric Catalysis
  • 2
    • 0003779363 scopus 로고    scopus 로고
    • Eds, M. Beller, C. Bolm, Wiley-VCH, Weinheim
    • b) Transition Metals for Organic Synthesis (Eds.: M. Beller, C. Bolm), Wiley-VCH, Weinheim, 2004;
    • (2004) Transition Metals for Organic Synthesis
  • 3
    • 0042881071 scopus 로고    scopus 로고
    • c) C. Bolm, Chem. Rev. 2003, 103, 2761-3400.
    • (2003) Chem. Rev , vol.103 , pp. 2761-3400
    • Bolm, C.1
  • 8
  • 10
    • 0001552544 scopus 로고    scopus 로고
    • a) R. Noyori, Angew. Chem. 2002, 114, 2108-2123;
    • (2002) Angew. Chem , vol.114 , pp. 2108-2123
    • Noyori, R.1
  • 11
    • 0037124885 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 2008-2022;
    • (2002) Angew. Chem. Int. Ed , vol.41 , pp. 2008-2022
  • 13
    • 4544320494 scopus 로고    scopus 로고
    • Eds, N. Krause, A. S. K. Hashmi, Wiley-VCH, Weinheim
    • a) Modern Allene Chemistry (Eds.: N. Krause, A. S. K. Hashmi), Wiley-VCH, Weinheim, 2004;
    • (2004) Modern Allene Chemistry
  • 15
  • 17
    • 4544276732 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 1196-1216;
    • (2004) Angew. Chem. Int. Ed , vol.43 , pp. 1196-1216
  • 19
    • 22944485617 scopus 로고    scopus 로고
    • f) S. Ma, Chem. Rev. 2005, 105, 2829-2871;
    • (2005) Chem. Rev , vol.105 , pp. 2829-2871
    • Ma, S.1
  • 20
  • 22
    • 85163238374 scopus 로고    scopus 로고
    • Recent examples: a F. Volz, N. Krause, Org. Biomol. Chem. 2007, 5, 1519-1521;
    • Recent examples: a) F. Volz, N. Krause, Org. Biomol. Chem. 2007, 5, 1519-1521;
  • 26
    • 34248146411 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 1650-1653;
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 1650-1653
  • 28
    • 33745652988 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 1897-1899;
    • (2006) Angew. Chem. Int. Ed , vol.45 , pp. 1897-1899
  • 31
    • 85163239987 scopus 로고    scopus 로고
    • In the absence of the methyl groups at the pyridine rings, undesired side reactions due to deprotonation of the acidic hydrogen atoms adjacent to the pyridine nitrogens are observed
    • In the absence of the methyl groups at the pyridine rings, undesired side reactions due to deprotonation of the acidic hydrogen atoms adjacent to the pyridine nitrogens are observed.
  • 38
    • 85163238343 scopus 로고    scopus 로고
    • The attempted enantioselective synthesis of the tertiary alcohol 1a by reaction of the titanium acetylide in the presence of (S)-BINOL (P. G. Cozzi, S. Alesi, Chem. Commun. 2004, 2248-2449) afforded only traces of the desired product.
    • The attempted enantioselective synthesis of the tertiary alcohol 1a by reaction of the titanium acetylide in the presence of (S)-BINOL (P. G. Cozzi, S. Alesi, Chem. Commun. 2004, 2248-2449) afforded only traces of the desired product.
  • 41
  • 42
    • 85163236586 scopus 로고    scopus 로고
    • Crystal structure analysis of a colorless crystal of [3b· AgBF4·CH2Cl2]2 (0.30×0.15×0.13 mm3) was performed on a Nonius-KappaCCD-Diffractometer at173(1) K. Crystal data for [3b· AgBF4·CH2Cl2]2: C 48H64Ag2B2Cl4F 8N4, M, 1228.19 gmol-1, orthorhombic, space group Fddd, a, 13.5824(8, b, 24.3346(8, c, 32.7072(16) Å, V, 10810.5(9) Å3, Z, 8, μ(Mo-Kα, 0.986 mm-1, 23363 independent reflections (θmin, 2.99, θmax, 27.48, 1961 with I≥2σ(I, R1, 0.0283, wR2 (all data, 0.0574; residual electron density max./min, 0.497/-0.274 e Å3. After merging symmetry-equivalent
    • 4) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 43
    • 85163238235 scopus 로고    scopus 로고
    • Initial experiments on the aziridination of styrene with [N-(p-toluolsulfonyl) imino]phenyliodinane show the high catalytic activity of a copper complex formed from allenic bipyridine 3b.
    • Initial experiments on the aziridination of styrene with [N-(p-toluolsulfonyl) imino]phenyliodinane show the high catalytic activity of a copper complex formed from allenic bipyridine 3b.


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