Sensitivity enhancement and dynamic behavior analysis by modulation excitation spectroscopy: Principle and application in heterogeneous catalysis

Chemical Engineering Science

Volumn 63, Issue 20, 2008, Pages 4902-4909

  Urakawa, Atsushi ^a   Bürgi, Thomas ^b   Baiker, Alfons ^a  

^a ETH ZURICH   (Switzerland)

^b UNIVERSITY OF NEUCHÂTEL   (Switzerland)

Author keywords

Catalysis; Chemical analysis; Kinetics; Transient response

Indexed keywords

CATALYSIS; CHLORINE COMPOUNDS; CONCENTRATION (PROCESS); DATA PROCESSING; DYNAMIC ANALYSIS; MODULATION; SENSITIVITY ANALYSIS;

CHEMICAL ANALYSIS; COMPLEX SYSTEMS; DYNAMIC BEHAVIOR ANALYSIS; DYNAMIC BEHAVIORS; ENANTIOSELECTIVE HYDROGENATION; EXCITATION SPECTROSCOPY; EXTERNAL-; HETEROGENEOUS CATALYSIS; HETEROGENEOUS CATALYTIC REACTIONS; IN-SITU SPECTROSCOPY; KINETICS; NOISY DATA; PERIODIC PERTURBATIONS; RESPONSE ANALYSIS; SELECTIVE DETECTION; SENSITIVITY ENHANCEMENTS; SOLID-GAS INTERFACES; SOLID-LIQUID; SOLID-LIQUID INTERFACES; TRANSIENT RESPONSE; WORKING CONDITIONS;

PHASE INTERFACES;

EID: 52949135858     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2007.06.009     Document Type: Article

References (27)

1. Backus E.H.G., Eichler A., Kleyn A.W., and Bonn M. Real-time observation of molecular motion on a surface. Science 310 5755 (2005) 1790-1793
2. Bauer M., Lei C., Read K., Tobey R., Gland J., Murnane M.M., and Kapteyn H.C. Direct observation of surface chemistry using ultrafast soft-X-ray pulses. Physical Review Letters 87 2 (2001) 025501
3. Baurecht D., and Fringeli U.P. Quantitative modulated excitation Fourier transform infrared spectroscopy. Review of Scientific Instruments 72 10 (2001) 3782-3792
4. Baurecht D., Porth I., and Fringeli U.P. A new method of phase sensitive detection in modulation spectroscopy applied to temperature induced folding and unfolding of RNase A. Vibrational Spectroscopy 30 1 (2002) 85-92
5. Bieri M., and Bürgi T. Probing enantiospecific interactions between proline and an L-glutathione self-assembled monolayer by modulation excitation ATR-IR spectroscopy. Journal of Physical Chemistry B 109 20 (2005) 10243-10250
6. Bieri M., and Bürgi T. Enantiodiscrimination between an N-acetyl-L-cysteine SAM and proline: an in situ spectroscopic and computational study. ChemPhysChem 7 2 (2006) 514-523
7. Bieri M., Gautier C., and Bürgi T. Probing chiral interfaces by infrared spectroscopic methods. Physical Chemistry Chemical Physics 9 6 (2007) 671-685
8. 2. Journal of Physical Chemistry B 106 41 (2002) 10649-10658
9. Chenevarin S., and Thibault-Starzyk F. Two-dimensional IR pressure-jump spectroscopy of adsorbed species for zeolites. Angewandte Chemie-International Edition 43 9 (2004) 1155-1158
10. Desamero R., Rozovsky S., Zhadin N., McDermott A., and Callender R. Active site loop motion in triosephosphate isomerase: T-jump relaxation spectroscopy of thermal activation. Biochemistry 42 10 (2003) 2941-2951
11. Forster M., Loth K., Andrist M., Fringeli U.P., and Günthard H.H. Kinetic study of photooxidation of pyrocatechol by modulated electronic excitation IR and ESR spectroscopy (MEIR and MESR). Chemical Physics 17 1 (1976) 59-80
12. Fringeli, U.P., 1992. In situ infrared attenuated total reflection membrane spectroscopy. Internal Reflection Spectroscopy Theory and Applications. J. F. M. Mirabella. New York, Dekker, pp. 255-324.
13. Fringeli, U.P., Baurecht, D., Günthard, H.H., 2000. Infrared and Raman Spectroscopy of Biological Materials. Infrared and Raman Spectroscopy of Biological Materials. H. U. Gremlich and B. Yan. New York/Basel, Dekker, pp. 143-192.
14. Gisler A., Bürgi T., and Baiker A. Epoxidation on titania-silica aerogel catalysts studied by attenuated total reflection Fourier transform infrared and modulation spectroscopy. Physical Chemistry Chemical Physics 5 16 (2003) 3539-3548
15. Gisler A., Bürgi T., and Baiker A. Epoxidation of cyclic allylic alcohols on titania-silica aerogels studied by attenuated total reflection infrared and modulation spectroscopy. Journal of Catalysis 222 2 (2004) 461-469
16. Gleaves J.T., Ebner J.R., and Kuechler T.C. Temporal analysis of products (TAP)-a unique catalyst evaluation system with submillisecond time resolution. Catalysis Reviews-Science and Engineering 30 1 (1988) 49-116
17. Hunger M., and Weitkamp J. In situ IR, NMR, EPR, and UV/Vis spectroscopy: tools for new insight into the mechanisms of heterogeneous catalysis. Angewandte Chemie-International Edition 40 16 (2001) 2954-2971
18. Müller M., Buchet R., and Fringeli U.P. 2D-FTIR ATR spectroscopy of thermo-induced periodic secondary structural changes of poly-(L)-lysine: a cross-correlation analysis of phase-resolved temperature modulation spectra. Journal of Physical Chemistry 100 25 (1996) 10810-10825
19. Onyestyák G., Valyon J., and Rees L.V.C. A frequency-response study of the acidity of mordenite catalysts. Physical Chemistry Chemical Physics 2 13 (2000) 3077-3082
20. 2 complex in response to a temperature jump: a time-resolved structural investigation employing X-ray absorption spectroscopy. Biophysical Journal 84 2 (2003) 1370-1386
21. Urakawa A., Wirz R., Bürgi T., and Baiker A. ATR-IR flow-through cell for concentration modulation excitation spectroscopy: diffusion experiments and simulations. Journal of Physical Chemistry B 107 47 (2003) 13061-13068
22. Urakawa A., Bürgi T., and Baiker A. Kinetic analysis using square-wave stimulation in modulation excitation spectroscopy: mixing property of a flow-through PM-IRRAS Cell. Chemical Physics 324 2-3 (2006) 653
23. Urakawa A., Bürgi T., Schläpfer H.-P., and Baiker A. Simultaneous in situ monitoring of surface and gas species and surface properties by modulation excitation PM-IRRAS: CO oxidation over Pt film. Journal of Chemical Physics 124 (2006) 054717
24. Weckhuysen B.M. Snapshots of a working catalyst: possibilities and limitations of in situ spectroscopy in the field of heterogeneous catalysis. Chemical Communications 2 (2002) 97-110
25. Wirz R., Bürgi T., and Baiker A. Probing enantiospecific interactions at chiral solid-liquid interfaces by absolute configuration modulation infrared spectroscopy. Langmuir 19 3 (2003) 785-792
26. Wirz R., Bürgi T., Lindner W., and Baiker A. Absolute configuration modulation attenuated total reflection IR spectroscopy: an in situ method for probing chiral recognition in liquid chromatography. Analytical Chemistry 76 18 (2004) 5319-5330
27. Yablonsky G.S., Olea M., and Marin G.B. Temporal analysis of products: basic principles, applications, and theory. Journal of Catalysis 216 1-2 (2003) 120-134