메뉴 건너뛰기




Volumn 10, Issue 10, 2008, Pages 1305-1308

An acentric parallel interpenetrated dual-ligand zinc coordination polymer from an in situ terminal-to-internal alkene rearrangement

Author keywords

[No Author keywords available]

Indexed keywords


EID: 52649166158     PISSN: 14668033     EISSN: 14668033     Source Type: Journal    
DOI: 10.1039/b809255a     Document Type: Article
Times cited : (32)

References (48)
  • 43
    • 52649143993 scopus 로고    scopus 로고
    • -1): 3250 w br, 1596 s, 1520 m, 1449 m, 1434 m, 1347 s, 1213 m, 1137 w, 1064 m, 1028 m, 953 w, 904 w, 857 w, 819 s, 765 w, 728 w, 678 m
    • 3, Z = 8. Refinement of 212 parameters on 3696 independent reflections out of 17297 measured reflections (Rint = 0.0327) led to R1 = 0.0604, wR2 = 0.1081 (all data) and S = 1.058. The hydrogen atom bound to the dpa ligand was found by Fourier difference map. See supporting data for more detailed crystallographic information, including bond lengths and angles and hydrogen bonding information. Attempts to solve the structure in the higher symmetry centrosymmetric space group Cmca with the zinc atom and mesaconate ligands on a crystallographic mirror plane and disordered dpa ligands were much less satisfactory (wR2 > 0.25). The low Flack parameter of 0.08(2) also corroborates the choice of the acentric Aba2 space group. The carbon atoms of the minor disordered component of the mesaconate ligand were modeled with equivalent anisotropic thermal parameters in order to permit acceptable refinement of these parameters


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.