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-1): 3250 w br, 1596 s, 1520 m, 1449 m, 1434 m, 1347 s, 1213 m, 1137 w, 1064 m, 1028 m, 953 w, 904 w, 857 w, 819 s, 765 w, 728 w, 678 m
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3, Z = 8. Refinement of 212 parameters on 3696 independent reflections out of 17297 measured reflections (Rint = 0.0327) led to R1 = 0.0604, wR2 = 0.1081 (all data) and S = 1.058. The hydrogen atom bound to the dpa ligand was found by Fourier difference map. See supporting data for more detailed crystallographic information, including bond lengths and angles and hydrogen bonding information. Attempts to solve the structure in the higher symmetry centrosymmetric space group Cmca with the zinc atom and mesaconate ligands on a crystallographic mirror plane and disordered dpa ligands were much less satisfactory (wR2 > 0.25). The low Flack parameter of 0.08(2) also corroborates the choice of the acentric Aba2 space group. The carbon atoms of the minor disordered component of the mesaconate ligand were modeled with equivalent anisotropic thermal parameters in order to permit acceptable refinement of these parameters
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