A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4′-bpy)2.5(H2O)2(ClO 4)2-1.5(4,4′-bpy)-2H2O 1

Inorganic Chemistry

Volumn 36, Issue 20, 1997, Pages 4292-4293

  Yaghi, O M ^a   Li, Hailian ^a   Groy, Thomas L ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000122467     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970423a     Document Type: Article

References (28)

1. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
2. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
3. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
4. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
5. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
6. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
7. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
8. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
9. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
10. See, e.g.: (a) Lu, J.; Paliwala, T.; Lim, S. C.; Yu, C.; Niu, T.; Jacobson, A. J. Inorg. Chem. 1997, 36, 923. (b) Losier, P.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 2779. (c) Venkataraman, D.; Lee, S.; Moore, J. S.; Zhang, P.; Hirsch, K. A.; Gardner, G. B.; Covey, A. C.; Prentice, C. L. Chem. Mater. 1996, 8, 2030. (d) Yaghi, O. M. In Access in Nanoporous Materials; Pinnavaia, T. J., Thorpe, M. F., Eds.; Plenum: New York, 1995; p 111. (e) Robson, R.; Abrahams, B. F.; Batteen, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. In Supramolecular Architecture: Synthetic Control in Thin Films and Solids; Bein, T., Ed.; American Chemical Society: Washington, DC, 1992; Chapter 19. (f) Iwamoto, T. In Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Oxford: New York, 1991; Vol. 5, p 177. (g) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546. (h) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151. (i) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325. (j) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755.
11. See, e.g.: (a) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (b) Yaghi, O. M. In Metal Containing Polymeric Materials; Pittman, C. U., Carraher, C. E., Culbertson, B. M., Zeldin, M., Sheets, J. E., Eds.; Plenum: New York, 1996; p 219. (c) Zaworotko, M. J. Chem. Soc. Rev. 1994, 283.
12. See, e.g.: (a) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (b) Yaghi, O. M. In Metal Containing Polymeric Materials; Pittman, C. U., Carraher, C. E., Culbertson, B. M., Zeldin, M., Sheets, J. E., Eds.; Plenum: New York, 1996; p 219. (c) Zaworotko, M. J. Chem. Soc. Rev. 1994, 283.
13. See, e.g.: (a) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (b) Yaghi, O. M. In Metal Containing Polymeric Materials; Pittman, C. U., Carraher, C. E., Culbertson, B. M., Zeldin, M., Sheets, J. E., Eds.; Plenum: New York, 1996; p 219. (c) Zaworotko, M. J. Chem. Soc. Rev. 1994, 283.
14. In addition to crystallization methods involving the usual dissolution/ reprecipitation (a), hydrothermal (b) and aqueous (c) and nonaqueous (d) gel methods have been employed for the achievement of coordination solids in the form of single crystals. See e.g.: (a) Holden, A.; Morrison, P. Crystals and Crystal Growing, MIT Press: Cambridge, MA, 1982. (b) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401. (c) Yaghi, O. M.; Li, G; Groy, T. L. J. Solid State Chem. 1995, 777, 256. (d) Yaghi, O. M.; Li, G.; Li, H. Mater. Chem. 1997, 9, 1074.
15. In addition to crystallization methods involving the usual dissolution/ reprecipitation (a), hydrothermal (b) and aqueous (c) and nonaqueous (d) gel methods have been employed for the achievement of coordination solids in the form of single crystals. See e.g.: (a) Holden, A.; Morrison, P. Crystals and Crystal Growing, MIT Press: Cambridge, MA, 1982. (b) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401. (c) Yaghi, O. M.; Li, G; Groy, T. L. J. Solid State Chem. 1995, 777, 256. (d) Yaghi, O. M.; Li, G.; Li, H. Mater. Chem. 1997, 9, 1074.
16. In addition to crystallization methods involving the usual dissolution/ reprecipitation (a), hydrothermal (b) and aqueous (c) and nonaqueous (d) gel methods have been employed for the achievement of coordination solids in the form of single crystals. See e.g.: (a) Holden, A.; Morrison, P. Crystals and Crystal Growing, MIT Press: Cambridge, MA, 1982. (b) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401. (c) Yaghi, O. M.; Li, G; Groy, T. L. J. Solid State Chem. 1995, 777, 256. (d) Yaghi, O. M.; Li, G.; Li, H. Mater. Chem. 1997, 9, 1074.
17. In addition to crystallization methods involving the usual dissolution/ reprecipitation (a), hydrothermal (b) and aqueous (c) and nonaqueous (d) gel methods have been employed for the achievement of coordination solids in the form of single crystals. See e.g.: (a) Holden, A.; Morrison, P. Crystals and Crystal Growing, MIT Press: Cambridge, MA, 1982. (b) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401. (c) Yaghi, O. M.; Li, G; Groy, T. L. J. Solid State Chem. 1995, 777, 256. (d) Yaghi, O. M.; Li, G.; Li, H. Mater. Chem. 1997, 9, 1074.
18. (a) Yaghi, O. M.; Davis, C. E.; Li, G.; Li, H. J. Am. Chem. Soc. 1997, 119, 2861.
19. (b) Gardner, G. B.; Kiang, Y.-H.; Lee, S.; Asgaonkar, A.; Venkataraman, D. J. Am. Chem. Soc. 1996, 118, 6946.
20. (c) Yaghi, O. M.; Li, H.; Groy, T. L. J. Am. Chem. Soc. 1996, 118, 9096.
21. (d) Ramprasad, D.; Pez, G. P.; Toby, B. H.; Markley, T. J.; Pearlstein, R. M. J. Am. Chem. Soc. 1995, 117, 10694.
22. 2Ni: C, 50.34; H, 4.22; N, 11.74; Ni, 6.15. Found: C, 50.39; H, 4.15; N, 11.97; Ni, 6.07.
23. 3 axis with two preferred orientations for the oxygen atoms.
24. (a) Yaghi, O. M.; Richardson, D. A.; Li, G.; Davis, C. E.; Groy, T. L. Mater. Res. Soc. Symp. Proc. 1995, 371, 15.
25. (b) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1996, 118, 295.
26. (c) Robinson, F.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1995, 2413.
27. (d) Yaghi, O. M.; Li, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 207.
28. (e) Gable, R. W.; Hoskins, B. F.; Robson, R. J. Chem. Soc., Chem. Commun. 1990, 1677.