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Since the reversible transitions showed multiple endothermic peaks originated from mixtures of gold nanoparticles and byproducts (sulfides and disulfides, the highest peak maximum temperatures are selected in the second heating scan of DSC. The data for the reversible transitions temperatures of Au(I)-SC4 and Au(I)SC6 are not included in Figure 2c because any reversible transitions were not observed in the second heating scan of DSC. It seems likely that the reversible transition temperatures of Au(I)-SC4 and Au(I)-SC6 are below the range of detection for our DSC equipment. DSC curves of Au-SRs containing the irreversible and reversible transitions are shown in the Supporting Information
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Since the reversible transitions showed multiple endothermic peaks originated from mixtures of gold nanoparticles and byproducts (sulfides and disulfides), the highest peak maximum temperatures are selected in the second heating scan of DSC. The data for the reversible transitions temperatures of Au(I)-SC4 and Au(I)SC6 are not included in Figure 2c because any reversible transitions were not observed in the second heating scan of DSC. It seems likely that the reversible transition temperatures of Au(I)-SC4 and Au(I)-SC6 are below the range of detection for our DSC equipment. DSC curves of Au-SRs containing the irreversible and reversible transitions are shown in the Supporting Information.
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