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Crystal data for 5: [C50H54F 6N6OPRe, M, 1086.16, triclinic, P1 (No. 2, a, 12.515(2) Å, b, 14.369(2) Å, c, 16.693(3) Å, α, 83.00(2)°, β, 72.52(2)°, γ, 68.00(2)°, V, 2654.6(7) Å3, Z, 2, D c, 1.359 g cm-3, μ(Mo Kα, 2.379 mm -1, 15 754 reflections collected, 9873 were unique (R int, 0.0209, and 8122 were observed with I ≥ 2σ(I) in the ranges of -15 ≤ h ≤ 14, 17 ≤ k ≤ 17, 20 ≤ l ≤ 17 with 2θmax equal to 51.36°. F(000, 1096, T, 301 K. R1, 0.0447 and wR2, 0.1231 with a GOF on F2, 1.007. Data/restraints/parameters: 9873/3/517. The C atoms [C(30)-C37, on the dimethylphenyl groups in one of the dimethylphenyl-isocyanide ligands were refined is
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2 = 1.007. Data/restraints/parameters: 9873/3/517. The C atoms [C(30)-C(37)] on the dimethylphenyl groups in one of the dimethylphenyl-isocyanide ligands were refined isotropically because of their relatively high thermal parameters. For crystallographic data in CIF, see the Supporting Information.
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