Involvement of a binuclear species with the Re-C(O)O-Re moiety in CO 2 reduction catalyzed by tricarbonyl rhenium(I) complexes with diimine ligands: Strikingly slow formation of the Re-Re and Re-C(O)O-re species from Re(dmb)(CO)3S (dmb = 4,4′-dimethyl-2,2′-bipyridine, S = solvent)

Journal of the American Chemical Society

Volumn 125, Issue 39, 2003, Pages 11976-11987

  Hayashi, Yukiko ^a   Kita, Shouichi ^b   Brunschwig, Bruce S ^c   Fujita, Etsuko ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b HIROSAKI UNIVERSITY   (Japan)

^c CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BRIDGED DIMERS;

CATALYSIS; ELECTRIC EXCITATION; GROUND STATE; OXIDATION; PHOTOLYSIS; REDUCTION;

COMPLEXATION;

2,2' BIPYRIDINE DERIVATIVE; 4,4' DIMETHYL 2,2' BIPYRIDINE; CARBOXYLIC ACID DERIVATIVE; DIIMINE; FORMIC ACID; IMINE; LIGAND; ORGANOMETALLIC COMPOUND; RADICAL; RHENIUM COMPLEX; TRICARBONYL RHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; DIMERIZATION; ELECTROCHEMICAL ANALYSIS; ELECTRON TRANSPORT; INFRARED SPECTROSCOPY; OXIDATION; PHOTOCHEMICAL QUENCHING; PHOTOLYSIS; PHOTOREACTIVITY; REACTION ANALYSIS; REDUCTION; ULTRAVIOLET SPECTROSCOPY;

EID: 0141732219     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja035960a     Document Type: Article

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