Mechanism of the Stille reaction catalyzed by palladium ligated to arsine ligand: PhPdl(AsPh3)(DMF) is the species reacting with vinylstannane in DMF

Journal of the American Chemical Society

Volumn 125, Issue 14, 2003, Pages 4212-4222

  Amatore, Christian ^a   Bahsoun, Ali A ^a   Jutand, Anny ^a   Meyer, Gilbert ^a   Ndedi Ntepe, Alexandre ^a   Ricard, Louis ^b  

^a ECOLE NORMALE SUPÉRIEURE   (France)

^b LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; DIMERS; DISSOCIATION; ORGANOMETALLICS; OXIDATION; REACTION KINETICS; SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

TRANSMETALATION;

CATALYSIS;

ARSINE; LIGAND; PALLADIUM; STYRENE; TIN; VINYL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; DISSOCIATION; KINETICS; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 0037427269     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0204978     Document Type: Article

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14. 2
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18. -.
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22. 3.
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30. + complex,
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33. 2] in chloroform. However, because Stille reactions are never performed in chloroform, this investigation has not been undertaken.
34. 3 in THF, via the investigation of the kinetics of the catalytic reaction.
35. This is an application of the steady-state approximation for a reactive moiety involved in a fast equilibrium with a non reactive species.
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