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For selected recent examples involving primary and secondary hydrosilanes see: (a) Simons, R. S.; Sanow, L. M.; Galat, K. J.; Tessier, C. A.; Youngs, W. J. Organometallics 2000, 19, 3994. (b) Braddock-Wilking, J.; Levchinsky, Y.; Rath, N. P. Organometallics 2000, 19, 5500. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184. (d) Kim, Y.-J.; Park, J.-I.; Lee, S.- C.; Osakada, K.; Tanabe, M.; Choi, J.-C.; Koizumi, T.; Yamamoto, T. Organometallics 1999, 18, 1349. (e) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
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For selected recent examples involving primary and secondary hydrosilanes see: (a) Simons, R. S.; Sanow, L. M.; Galat, K. J.; Tessier, C. A.; Youngs, W. J. Organometallics 2000, 19, 3994. (b) Braddock-Wilking, J.; Levchinsky, Y.; Rath, N. P. Organometallics 2000, 19, 5500. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184. (d) Kim, Y.-J.; Park, J.-I.; Lee, S.- C.; Osakada, K.; Tanabe, M.; Choi, J.-C.; Koizumi, T.; Yamamoto, T. Organometallics 1999, 18, 1349. (e) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
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For selected recent examples involving primary and secondary hydrosilanes see: (a) Simons, R. S.; Sanow, L. M.; Galat, K. J.; Tessier, C. A.; Youngs, W. J. Organometallics 2000, 19, 3994. (b) Braddock-Wilking, J.; Levchinsky, Y.; Rath, N. P. Organometallics 2000, 19, 5500. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184. (d) Kim, Y.-J.; Park, J.-I.; Lee, S.- C.; Osakada, K.; Tanabe, M.; Choi, J.-C.; Koizumi, T.; Yamamoto, T. Organometallics 1999, 18, 1349. (e) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
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For selected recent examples involving primary and secondary hydrosilanes see: (a) Simons, R. S.; Sanow, L. M.; Galat, K. J.; Tessier, C. A.; Youngs, W. J. Organometallics 2000, 19, 3994. (b) Braddock-Wilking, J.; Levchinsky, Y.; Rath, N. P. Organometallics 2000, 19, 5500. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184. (d) Kim, Y.-J.; Park, J.-I.; Lee, S.- C.; Osakada, K.; Tanabe, M.; Choi, J.-C.; Koizumi, T.; Yamamoto, T. Organometallics 1999, 18, 1349. (e) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
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For selected recent examples involving primary and secondary hydrosilanes see: (a) Simons, R. S.; Sanow, L. M.; Galat, K. J.; Tessier, C. A.; Youngs, W. J. Organometallics 2000, 19, 3994. (b) Braddock-Wilking, J.; Levchinsky, Y.; Rath, N. P. Organometallics 2000, 19, 5500. (c) Feldman, J. D.; Mitchell, G. P.; Nolte, J.-O.; Tilley, T. D. J. Am. Chem. Soc. 1998, 120, 11184. (d) Kim, Y.-J.; Park, J.-I.; Lee, S.- C.; Osakada, K.; Tanabe, M.; Choi, J.-C.; Koizumi, T.; Yamamoto, T. Organometallics 1999, 18, 1349. (e) Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 1917.
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Attempts to confirm the position of this resonance by 2D NMR spectroscopy failed, due to the limited lifetime of 3.
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Variable-temperature reaction conditions are currently being examined with both the unsubstituted and substituted silafluorene systems 1 and 6 to monitor the sequence of steps.
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