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Volumn 21, Issue 25, 2002, Pages 5467-5469

Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(μ-SiC12H8)]3 from reaction of silafluorene with (Ph3P)2Pt(η2-C2H4)

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Indexed keywords

LIGANDS;

EID: 0038677670     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020565z     Document Type: Article
Times cited : (45)

References (27)
  • 19
    • 0037537606 scopus 로고    scopus 로고
    • note
    • PH (cis) = 21 Hz).
  • 20
    • 0001508917 scopus 로고    scopus 로고
    • 1H NMR spectrum exhibited two hydride signals at ca. -5 (t, with Pt satellites) and 2 ppm (d, Pt satellites not resolved). The data were obtained at 223 K and are consistent with an unsymmetrical environment about the two Pt centers in 2. Precedence for a directly related unsymmetrical palladium dimer has recently been published; see: Kim, Y.-J.; Lee, S.-C.; Park, J.-I.; Osakada, K.; Choi, J.-C.; Yamamoto, T. Organometallics 1998, 17, 4929.
    • (1998) Organometallics , vol.17 , pp. 4929
    • Kim, Y.-J.1    Lee, S.-C.2    Park, J.-I.3    Osakada, K.4    Choi, J.-C.5    Yamamoto, T.6
  • 22
    • 0037875441 scopus 로고    scopus 로고
    • note
    • 6: C, 59.21; H, 3.95. Pound: C, 59.32; H, 4.11.
  • 23
    • 0038551822 scopus 로고    scopus 로고
    • note
    • 2 = 21.6% for 13 184 reflections and 919 parameters. Crystallographic data for structure 3 have been be deposited with the Cambridge Structural Data Base dep #CCDC 196309.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.